专利号:US-5876587-A 优先权日:1995-12-29 标题 :Electrochemical synthesis of transition metal/phosphine catalysts 发明人:HORBEZ DOMINIQUE; HUSER MARC; PERRON ROBERT 权利人:RHONE POULENC CHIMIE 摘要:Catalyst compounds comprising at least one transition metal in an oxidation state of 0 to 1, and at least one monodentate or bidentate water-soluble phosphine, well suited for the hydrocyanation of ethylenically unsaturated compounds, are electrochemically synthesized, by electrolyzing an aqueous solution catholyte (contained in the cathode compartment of any suitable electrolytic cell) comprising at least one transition metal compound and at least one monodentate or bidentate water-soluble phosphine, advantageously at least one phosphine having the following formulae (I) and/or (II): P(Ar1)a(Ar2)b(Ar3)c(D1)d(D2)e(D3)f(I) (Ar1)a(Ar2)b(D1)d(D2)eP-L-P(Ar1)g(Ar2)h(D1)i(D2)j(II).
专利号:US-12312250-B1 优先权日:2024-10-30 标 题 :Synthesis of zinc oxide nanoparticles using L-tryptophan as a fuel 发明人:AHMED EHAB ABDELHAMED ABDELRAHMAN; ABDULKHAIR BABIKER YAGOUB ELHADI 权利人:IMAM MOHAMMAD IBN SAUD ISLAMIC UNIV 摘要:A method of synthesizing zinc oxide nanoparticles includes mixing an aqueous solution of a zinc precursor and an aqueous solution of L-tryptophan to form a reaction mixture and heating the reaction mixture to a temperature of at least 100° C. to produce a dry powder. The method further includes calcining the dry powder to obtain the zinc oxide nanoparticles. The zinc oxide nanoparticles have an average particle size of 155 nm or less. Further, the zinc oxide nanoparticles are substantially spherical and include mesopores with a total pore volume of 0.1 to 0.5 cm3/g.
专利号:WO-2016005892-A1 优先权日:2014-07-08 标题 :Process for the preparation of substituted polyazamacrocycles 发明人:SANTARELLI SAMUELE; CHIABERGE STEFANO 权利人:ENI SPA 摘要:Process for the preparation of a polyazamacrocycle substituted with at least one aryl or heteroaryl group comprising reacting at least one unsubstituted polyazamacrocycle with at least one halogenated aryl or heteroaryl compound. Said polyazamacrocycle substituted with at least one aryl or heteroaryl group may advantageously be used in the synthesis of anionic or cationic complexes and/or of supramolecular adducts useful in the construction of luminescent solar concentrators (LSCs), which in their turn may advantageously be used together, for example, with photovoltaic cells (or solar cells), or with photoelectrolytic cells, in solar devices (i.e. devices for exploiting solar energy). Moreover, said polyazamacrocycle may be used in other fields such as, for example, the analytical field, the medical or biomedical field, the biological field, the field of detergents (both for household use and for personal care use). Formula I
专利号:US-5679237-A 优先权日:1994-12-06 标题:Electrochemical synthesis of transition metal/phosphine catalyst compounds 发明人:CHAMARD ALEX; HORBEZ DOMINIQUE; HUSER MARC; PERRON ROBERT 权利人:RHONE POULENC FIBRES 摘要:Catalyst compounds comprising at least one transition metal having an oxidation number of 0 or 1 and at least one sulfonated phosphine are electrochemically synthesized, by electrolyzing an aqueous solution catholyte (contained in the cathode compartment of any suitable electrolytic cell) comprising at least one transition metal compound and at least one sulfonated phosphine.
专利号:WO-2020124467-A1 优先权日:2018-12-20 标 题:Oxalate material, preparation method, use, lithium-ion battery cathode material and lithium-ion battery 发明人:TANG YONGBING; YAO WENJIAO; ZHOU XIAOLONG 权利人:SHENZHEN INST ADV TECH 摘要:The present application relates to the technical field of batteries, and relates to an oxalate material, a preparation method, a use, a lithium-ion battery cathode material and a lithium-ion battery. The oxalate material of the present application comprises the following chemical compositions: Li2TMC4O8, wherein TM is a transition metal having charge of plus two. The oxalate material is a polyanionic-based cathode material having dual electrochemical activities and can be used as a lithium-ion battery cathode active material in a lithium-ion battery. With respect to existing lithium-ion battery cathode materials, the present application provides a designing and preparation method for a cathode material having a good safety and high capability. Besides, the synthesis method for the cathode active material is convenient, rapid and safe and all materials are cheap and easily obtained; and the cathode active material is important for optimizing battery material synthesis technique and reducing electrode material preparation cost.