CAS: 1992-48-9; Tetraisopropyl Orthosilicate

该化合物是有机硅质化合物,其特征为四类异丙氧化合物,附在硅原子上;该化合物通常是无色,粘结液液体,在有机溶剂中溶解,但在水中溶解较少,以其作为合成硅酸和硅酸盐材料的前体的能力而著称;该物质在包括涂层,粘合剂和密封剂在内的各种应用中具有价值;Tetraiso proxylsilane在水中可以进行水解,导致硅醇组形成,最终在进一步凝结后产生硅酸凝胶;其再活性和形成硅氧烷联系的能力使它成为材料科学和纳米技术领域的一个重要复合物;此外,必须谨慎处理该物质,因为它可能是易燃的,在与皮肤或眼睛接触时可能引起刺激;在实验室或实验室与四丙基氨基化合物接触时,应当注意适当的安全措施.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

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CAS号67-63-0 异丙醇 | CAS号18145-76-1 dichloro-di(pro... | CAS号541-42-4 亚硝酸异丙酯 | CAS号10026-04-7 四氯化硅 | CAS号681-84-5 原硅酸四甲酯 | CAS号107-44-8 sarin | CAS号638-11-9 丁酸异丙基酯

合成工艺路线路线简述

  • 合成目标产物 Tetraisopropyl Orthosilicate 主要起始原料 Isopropyl Alcohol
  • (文献来源)合成步骤主要原料 Isopropyl Alcohol
Dichlorodiisopropoxysilane置于sodium体系中,用 甲苯 用作溶剂,化学反应 0.5H,反应生成正硅酸四异丙酯
参考文献:The Phenylation And Methylation Of Alkoxychlorosilanes1
标题:The Phenylation And Methylation Of Alkoxychlorosilanes1
摘要:
Doi:10.1021/jo01073A033

海关参考信息

专利信息


专利号:US-2010119736-A1
优先权日:2008-10-07
标题 :Ambient pressure synthesis of zeolite films and their application as corrosion resistant coatings
发明人:YAN YUSHAN; CAI RUI; SUN MINWEI
权利人:UNIV CALIFORNIA
摘要:A method for producing zeolite films or membranes at essentially ambient pressure, which includes preparing a synthesis mixture comprising an ionic liquid solvent and an aluminum and/or silicon and/or phosphate source and converting the synthesis mixture to form a continuous zeolite layer. In addition, a method of synthesizing zeolite nanocrystals, which includes preparing a synthesis mixture, the synthesis mixture having a silica or a silica and alumina source, and a template; and synthesizing the synthesis mixture to form zeolite nanocrystals.

专利号:US-2019070597-A1
优先权日:2015-10-13
标题:Synthesis of plate-like sapo-34 crystals
发明人:FICKEL DUSTIN; KULKARNI NEETA
权利人:SABIC GLOBAL TECHNOLOGIES BV
摘要:Disclosed is a SAPO-34 molecular sieve having platelet morphology with the smallest dimension on the order of a few nanometers. Also disclosed are methods and systems of using said molecular sieve for catalyzing the reaction of alkyl halides to light olefins. These methods and systems have been shown to have maximum combined selectivity of ethylene and propylene of at least 90% or ranging from 90% to 98%.

专利号:US-2019046964-A1
优先权日:2016-03-16
标 题 :Synthesis of sapo-34 and use in chloromethane to olefins reactions
发明人:FICKEL DUSTIN; KULKARNI NEETA; SABNIS KAIWALYA
权利人:SABIC GLOBAL TECHNOLOGIES BV
摘要:Disclosed are methods of producing SAPO-34 and MeAPSO-34 molecular sieves having nano-crystal morphology and optionally a hierarchical structure. Also disclosed are methods and systems of using said molecular sieve for catalyzing the reaction of alkyl halides to light olefins.

专利号:US-7309799-B2
优先权日:2004-06-01
标 题:Methods for the synthesis of milnacipran and congeners thereof
发明人:BUCHWALD STEPHEN L; SWAGER TIMOTHY M; RARIY ROMAN V
权利人:COLLEGIUM PHARMACEUTICAL INC
摘要:One aspect of the present invention relates to methods for synthesizing milnacipran or congeners thereof. Another aspect of the present invention relates to asymmetric methods for synthesizing enantiomerically enriched milnacipran or congeners thereof. The present invention also relates to methods for synthesizing intermediates useful in the non-asymmetric or asymmetric methods for synthesizing enantiomerically enriched milnacipran or congeners thereof.

专利号:US-2024228309-A1
优先权日:2023-01-06
标题:Porous ammonia synthesis catalyst, its preparation method and use
发明人:WU CHUANDE; YE JIJIE
权利人:UNIV ZHEJIANG
摘要:The present disclosure discloses a porous ammonia synthesis catalyst, its preparation method and use, which are suitable for catalyzing ammonia synthesis reaction by using nitrogen and hydrogen as raw materials. The porous ammonia synthesis catalyst is a novel ammonia synthesis catalyst material prepared by taking metal coordination compound as template, uniformly dispersing the metal coordination compound in silica gel through a sol-gel method, then carrying out hydrothermal aging, and finally controlling calcination conditions. Compared with traditional synthetic ammonia catalysts, the porous ammonia synthesis catalyst has uniform pore distribution, easily regulated pore size, large specific surface area, easily regulated aggregation degree of metal active centers, particle size, distribution, structure and composition, high ammonia synthesis catalytic efficiency, ammonia synthesis catalysis under mild reaction conditions, high stability, low catalyst preparation cost, which can completely replace existing ammonia synthesis industrial catalysts.

专利号:US-5629394-A
优先权日:1992-12-17
标 题 :Direct synthesis by living cationic polymerization of nitrogen-containing polymers
发明人:CHERADAME HERVE M; CHEN FRANK J; STANAT JON E R; NGUYEN HUNG A; TABAR BEHROOZ R
权利人:EXXON CHEMICAL PATENTS INC
摘要:A method is provided for the direct synthesis by living cationic polymerization of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino, cyanato, thiocyanato or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.
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主要参考文献

参考标题:Synthesis Of Aryl Ethers From Aromatic Carboxylic Acids
作者:Lukas Gooßen,Sukalyan Bhadra,Wojciech Dzik
摘要:Meta-Substituted Carboxylates Are Converted Into Para-Substituted Alkoxyarenes And Vice Versa. The Combined Processes Provide A Convenient Synthetic Entry To The Important Class Of Aromatic Ethers From Widely Available Carboxylic Acids. A Silver/copper Bimetallic Catalyst System Promotes The Decarboxylative Chan-Evans-Lam Alkoxylation Of Ortho-Substituted Aromatic Carboxylate Salts With Tetraalkyl Orthosilicates

合成参考文献


参考文献:10.1007/978-3-642-87538-0_9
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