CAS: 4342-61-4; 1 2-Dichlorotetramethyldisilane

该化合物是一种有机硅化合物,其独特结构包括两个硅原子,结为4个甲基组和两个氯原子.该化合物一般没有色素,可粉黄,具有独特的气味;以其活性闻名,特别是水分含量,导致水解和硅醇组的形成;氯原子的存在有助于其在各种化学反应中的潜在用途,包括作为合成含硅材料的前体.此外,它显示出硅的典型特性,如低挥发性以及形成硅氧链的能力.安全考虑很重要,因为吸入或摄入会有害,而且应当采取适当的处理措施以避免接触.

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CAS号1450-14-2 六甲基二硅烷 | CAS号13528-88-6 1,1,2-三氯-1,2,2-... | CAS号100-44-7 氯化苄 | CAS号4098-30-0 十二甲基环己硅烷 | CAS号18419-84-6 1,2-二乙氧基-1,1,2,... | CAS号1145-98-8 二苯基四甲基二硅烷 | CAS号75-78-5 二甲基二氯硅烷 | CAS号56-23-5 四氯化碳 | CAS号6376-86-9 (5Z)-2-amino-5-... | CAS号1078-97-3 1,4-亚苯基双(氯二甲基硅烷) | CAS号105410-04-6 3-[chloro(dimet... | CAS号332343-84-7 1,2-双(2-甲氧基苯基)-... | CAS号4098-30-0 十二甲基环己硅烷 | CAS号4518-98-3 1,1,2,2-四氯-1,2-... | CAS号26980-40-5 methylpentachlo... | CAS号18080-91-6 [dimethyl(prop-... | CAS号18419-84-6 1,2-二乙氧基-1,1,2,... | CAS号75-78-5 二甲基二氯硅烷 | CAS号1066-35-9 二甲基一氯硅烷

合成工艺路线路线简述

    十二甲基环己硅烷置于氯体系中,化学反应生成 1,2-二氯四甲基二硅烷
    参考文献:Cyclic Polysilanes
    标题:Cyclic Polysilanes
    摘要:
    DOI:10.1016/s0022-328X(00)92591-9

    专利信息


    专利号:US-5877337-A
    优先权日:1997-03-20
    标 题 :Process for preparing alkylchlorosilanes from the residues of direct synthesis of alkylchlorosilanes
    发明人:MAUTNER KONRAD; SCHINABECK ANTON; STRAUSSBERGER HERBERT
    权利人:WACKER CHEMIE GMBH
    摘要:Alkylchlorosilanes are prepared continuously from the residue of direct synthesis of alkylchlorosilanes containing liquid constituents with a boiling point of at least 70 DEG C. at 1013 hPa and solid constituents, by heating the residue with hydrogen chloride at temperatures of from 300 DEG C. to 800 DEG C. in a tubular reactor with internals which can be rotated.

    专利号:US-8637695-B2
    优先权日:2011-12-30
    标 题:Synthesis of organohalosilane monomers from conventionally uncleavable Direct Process Residue
    发明人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID
    权利人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID; MOMENTIVE PERFORMANCE MAT INC
    摘要:Disclosed herein is a catalytic process for the synthesis of organohalosilane monomers from tetraorganodihalodisilanes and other compounds that are not cleaved during the conventional hydrochlorination of Direct Process Residue. The process is characterized by the use of a catalyst containing (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.

    专利号:US-8207366-B2
    优先权日:2008-02-26
    标题:Method for producing alkyl chlorosilanes from the residues of the direct synthesis of alkyl chlorosilanes
    发明人:BOECK MANFRED; FUCHS PAUL; MAUTNER KONRAD
    权利人:BOECK MANFRED; FUCHS PAUL; MAUTNER KONRAD; WACKER CHEMIE AG
    摘要:High boiling residue from the direct synthesis of alkylchlorosilanes are converted in large part to monosilanes by heating the residue by passage of alternating current in a pressurized reactor.

    专利号:US-6344578-B1
    优先权日:2000-08-10
    标题 :Process for working up residues from the direct synthesis of organochlorosilanes
    发明人:MAUTNER KONRAD; KOEHLER BERND; TAMME GUDRUN
    权利人:WACKER CHEMIE GMBH
    摘要:The invention relates to a process for preparing alkylchlorosilanes from the liquid constituents of the residues from the direct synthesis of alkylchlorosilanes which have a boiling point of above 70° C. at 1013 hPa and comprise disilanes, in which the residues are heated with hydrogen chloride and silicon at temperatures of at least 300° C., with at least 10% by weight of trichlorosilane and/or tetrachlorosilane, based on the weight of the alkylchlorosilanes formed, being formed at the same time.

    专利号:US-4289890-A
    优先权日:1979-02-12
    标 题:Synthesis of chloromethyldisilanes
    发明人:GORDON ROY G
    权利人:GORDON ROY G
    摘要:1,2 Dichloro-1,1,2,2-tetramethyldisilane is synthesized in high yield and good purity starting from a crude mixture of chloromethyldisilanes formed as by-products in the manufacture of silicones. The new method uses less than half as much Grignard reagent as previous methods required. The synthesis can also be used to produce other haloalkyldisilanes such as chloropentamethyldisilane or 1,1,2 trichloro-1,2,2-trimethyldisilane.

    专利号:US-11691883-B2
    优先权日:2018-09-10
    标题:Synthesis of trichlorosilane from tetrachlorosilane and hydridosilanes
    发明人:AUNER NORBERT; STURM ALEXANDER G
    权利人:MOMENTIVE PERFORMANCE MAT INC
    摘要:The invention relates to a process for the preparation of trichlorosilane (HSiCl3) which comprises the reaction of tetrachlorosilane (SiCU) with hydridosilanes in the presence of a catalyst.
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    合成参考文献


    摘要:Marschner, C.; Baumgartner, J., Science of Synthesis Knowledge Updates, (2013) 2, 121.
    摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 103.
    摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 115.
    摘要:Marschner, C.; Baumgartner, J., Science of Synthesis Knowledge Updates, (2013) 2, 110.
    摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 76.
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