CAS: 88-64-2; 4-Acetamido-2-Aminobenzenesulfonic Acid

该化合物是一种芳香磺酸,其特征是磺酰胺功能组和乙酰胺替代体,看起来像白色的黄色晶晶状固体,在水中可以溶解,在各种应用中有用.化合物的分子配方反映了其复杂的结构,包括一个矿泉群,一个乙酰胺组和一个全氟辛烷磺酸组,这助长了其酸性.它通常用于染料,药物的合成,并用作分析化学的试剂.氨酸组的存在使其得以参与各种化学反应,包括电子替代和混合反应.此外,它显示出在生物系统中有用的特点,特别是在研究酶活动和药物开发的潜在中间作用方面.在处理该化合物时,应当采取安全防范措施,因为如果吸食或吸入,可能会对健康造成危害.

结构式图片

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2,4-Diaminobenzenesulfonic acid acetic anhydride 2-acetoxy-4-acetylamino-benzenesulfonic acid ; compound with pyridine

合成工艺路线路线简述

    Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于乙醇,铂体系中,化学反应生成 4-乙酰氨基-2-氨基苯磺酸
    参考文献:The Sulfonation Of M-Aminophenol
    标题:The Sulfonation Of M-Aminophenol
    摘要:
    DOI:10.1021/ja01178A524

    海关参考信息

    专利信息


    专利号:WO-9108265-A1
    优先权日:1989-12-02
    标 题:Azo compounds and their use as dyes, 1-sulpho-6-carboxyl-amino naphthaline, its use as a diazo component and process for the production of these compounds
    发明人:SPRINGER HARTMUT; HUSSONG KURT
    权利人:HOECHST AG
    摘要:The description relates to azo compounds corresponding to formula (1) below, having fibre-reactive properties and making valuable dyes. They can dye hydroxy and/or carbonamide group-containing synthetic and natural materials, especially fibre materials, like wool and especially cellulose fibre materials in bright colours. Formula (1) in which: M is hydrogen or a salt-forming metal like an alkaline metal; K is a residue of general formulae (2A) or (2B) in which: E is the residue of an intermediate component common in disazo dyes which can act as a coupling and as a diazo component, e.g. the residue of a 1-(aminophenyl) or -amino-naphthyl) pyrazolon, aminonaphthol, anilin or 1-amino naphthalin compound; v is the figure zero or 1; K is the residue of a water-soluble coupling component, preferably from the naphthol, aminonaphthol, anilin, pyrazolon, hydroxypyridon and acetoacetyl arylide series, whereby this coupling component contains 1 or 2 fibre-reactive groups of the vinyl sulphonate series; D is a benzol or naphthalin residue, whereby its substituents R?1 and R?2 are common ones in azo dyes, e.g. (besides hydrogen) lower alkyl, lower alkoxy, halogen, sulpho and carboxyl; the group -SO2?-Y is a fibre-reactive group of the vinyl sulphone series; a is the figure zero, 1 or 2; and k is the number 1 or 2. A description is also given of the compound 2-amino naphthaline-1-sulphonic acid-6-carboxylic acid which may be used as a pre-product in the production of dyes, e.g. as diazo component in the synthesis of dyes of general formula (1).

    专利号:US-4719053-A
    优先权日:1980-08-01
    标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates
    发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD
    权利人:HOECHST AG
    摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.

    专利号:US-6222067-B1
    优先权日:1999-11-04
    标 题:Alkylated diaminobenzene sulfonic acids
    发明人:CHEN KEH-LOONG; YIN TA-CHUNG
    权利人:EVERLIGHT USA INC
    摘要:A compound of the following formula (I):wherein R1 is hydrogen or C1-7 acyl, R2 is C1-3 alkylene, n is 0 or 1. Novel dyestuff intermediates of formula (I) compound of the present invention can be used to synthesis many kinds of dyestuffs. Also disclosed is a process for the preparation of compound of formula (I).
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    合成参考文献


    摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#00379
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