CAS: 1119-86-4; Decane-1,2-Diol

相似化合物

5393-81-7 1117-86-8 6920-24-7

上下游产品

CAS号872-05-9 正癸烯 | CAS号15138-49-5 4-°Ctyl-1,3-dio... | CAS号2404-44-6 1,2-环氧癸烷 | CAS号28114-20-7 2-Heptyloxirane | CAS号5393-81-7 2-羟基癸酸(2-羟基癸酸) | CAS号110-83-8 环己烯 | CAS号153750-36-8 (1,2-Epoxydecyl... | CAS号15138-49-5 4-°Ctyl-1,3-dio... | CAS号872-05-9 正癸烯 | CAS号124-19-6 正壬醛 | CAS号112-05-0 正壬酸 | CAS号333-60-8 2-oxodecanoic acid | CAS号87827-60-9 (R)-1,2-癸二醇 | CAS号2404-44-6 1,2-环氧癸烷 | CAS号84276-14-2 (S)-1,2-癸二醇 | CAS号74649-87-9 2-°Ctyl-1,4,7,1... | CAS号65678-02-6 1-hydroxydecan-2-one

正癸烯置于四氧化锇,N-甲基吗啉氧化物体系中,用 水,丙酮,叔丁醇 用作溶剂,化学反应生成1,2-癸二醇
参考文献:通过环硫酸酯的c(sp 3)-c(sp 3)kumada型偶联催化多元醇的化学和区域选择性官能化
标题:通过环硫酸酯的c(sp 3)-c(sp 3)kumada型偶联催化多元醇的化学和区域选择性官能化
摘要:该贡献描述了铜硫酸酯,环状硫酸酯(多元醇的独特亲电衍生物)与烷基格氏试剂的铜催化c(sp 3)-C(sp 3)交叉偶联反应,可提供高收率的官能化醇产品.该方法操作简单,突出了环硫酸酯作为催化,化学选择性多元醇转化中高反应性底物的潜力.
Doi:10.1021/acs.Orglett.6B01745

专利信息

专利号:US-5321143-A
优先权日:1988-05-26
标题 :Ruthenium-catalyzed production of cyclic sulfates
发明人：SHARPLESS K BARRY; GAO YUN
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:A ruthenium catalyzed method to synthesize cyclic sulfate compounds from the corresponding cyclic sulfites, and the cyclic sulfate reaction products obtained by this method. These cyclic sulfates further react with selected nucleophiles to give various substituted products. The method is an efficient means for the synthesis of chiral building blocks from tartaric acid enantiomers in high yields using an overall two-stage, one-pot reaction procedure. The chiral compounds can be transformed by nucleophilic reactions into chiral building blocks useful for the synthesis of natural biologically active products, such as antibiotics and pheromones.

专利号:US-5112990-A
优先权日:1988-05-26
标 题 :Ruthenium-catalyzed production of cyclic sulfates
发明人：SHARPLESS K BARRY; GAO YUN
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:A ruthenium catalyzed method to synthesize cyclic sulfate compounds from the corresponding cyclic sulfites, and the cyclic sulfate reaction products obtained by this method. These cyclic sulfates further react with selected nucleophiles to give various substituted products. The method is an efficient means for the synthesis of chiral building blocks from tartaric acid enantiomers in high yields using an overall two-stage, one-pot reaction procedure. The chiral compounds can be transformed by nucleophilic reactions into chiral building blocks useful for the synthesis of natural biologically active products, such as antibiotics and pheromones.

专利号:US-8877977-B2
优先权日:2011-11-25
标题 :Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
发明人：STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
权利人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO; BASF SE
摘要:Process for the preparation of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, in which aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst and in the presence of hydrogen gas. Polyalkylenepolyamines obtainable by such processes and polyalkylenepolyamines comprising hydroxy groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.

专利号:WO-2013076053-A1
优先权日:2011-11-25
标题:Synthesis of polyalkylene polyamines with low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
发明人：STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
权利人:BASF SE; STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
摘要:The invention relates to a method for the production of polyalkylene polyamines by homogeneously catalyzed alcohol amination, wherein aliphatic alkanolamines are reacted with each other or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols in the presence of a homogeneous catalyst while eliminating water and in the presence of hydrogen gas. The invention further relates to polyalkylene polyamines, which can be obtained by said methods, and to polyalkylene polyamines which contain hydroxyl groups, secondary amines or tertiary amines. The invention finally relates to uses of said polyalkylene polyamines as adhesion promoters in inks, adhesion promoters in composite films, cohesion promoters in adhesives, cross-linkers/hardeners for resins, primers for paints, wet adhesion promoters for dispersion paints, complexing agents and flocculants, penetration auxiliaries for use in wood preservation, corrosion inhibitors, and immobilization agents of proteins and enzymes.

专利号:US-8115002-B2
优先权日:2006-09-20
标 题:Preparation of substituted morphinan-6-ones and salts and intermediates thereof
发明人：WANG PETER X; MOSER FRANK W; CANTRELL GARY L; GROTE CHRISTOPHER W
权利人:WANG PETER X; MOSER FRANK W; CANTRELL GARY L; GROTE CHRISTOPHER W; MALLINCKRODT LLC
摘要:The present invention is directed to processes for the synthesis of morphinan-6-ones and salts, intermediates, and analogs thereof.

专利号:US-11414365-B2
优先权日:2018-01-30
标题:Natural 1,2-alkanediols, compositions having natural 1,2-alkanediols and processes for making the same
发明人：BURGO ROCCO V; WRIGHT MICHAEL E; MOSSER GARY B; FEVOLA MICHAEL J
权利人:INOLEX INVESTMENT CORP
摘要:A process is incorporated herein for the synthesis of bio-1,2-alkanediols, comprising: providing a bio-alkene having a carbon chain of about 5 to about 20 carbon atoms and a bio-1-alkene regioselectivity of at least about 80%, at least about 92% and/or at least about 95%; and converting the bio-alkene to a bio-1,2-alkanediol having a carbon chain length of about 5 to about 20 carbon atoms. Methods for treating catalysts which may be incorporated in the process for the synthesis of bio-1,2-alkanediols are also included herein. Such bio-1,2-alkanediols are used in compositions and products alone as antimicrobial materials, or with existing bio-compounds and/or antimicrobials, preservatives, alternative preservation systems and/or hurdle technology components. The bio-1,2-alkanediols incorporate a natural and bio-based pathway for antimicrobial effects in various compositions such as cosmetic, pharmaceutical, industrial and household products.