溴乙烷,吡啶 反应生成1-乙基溴化吡啶 参考文献:Dual Functional Ionic Liquids As Plasticisers And Antimicrobial Agents For Medical Polymers 标题:Dual Functional Ionic Liquids As Plasticisers And Antimicrobial Agents For Medical Polymers 摘要:耐甲氧西林金黄色葡萄球菌(mrsa)等细菌对医疗器械的污染是临床上非常关注的问题.聚氯乙烯被广泛用于生产导管等医疗器械.导管管材的柔韧性来自于增塑剂的添加.在此,我们报告了两种双功能离子液体(1-乙基吡啶鎓多聚物酸酯和三丁基(2-羟乙基)鏻多聚物酸酯)的设计,它们不仅具有独特的增塑作用,而且对一系列抗生素耐药菌具有抗菌和抗生物膜形成活性.聚氯乙烯的塑化是离子液体浓度的函数.这两种离子液体的有效抗菌性能源于阴离子或阳离子的化学结构,并不局限于阴离子/阳离子上烷基链的长度.所采用的设计方法将有助于开发作为聚合物多功能添加剂的离子液体. Doi:10.1039/c1Gc15132K
专利号:US-2010191010-A1 优先权日:2007-07-02 标题 :Process for the synthesis of carbamates using co2 发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY 权利人:HUNTSMAN INT LLC 摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.
专利号:US-5104944-A 优先权日:1989-07-18 标题:Process for nucleophilic derivatization of materials having an imide group conjugated to an aromatic moiety 发明人:GOLDBERG MARTIN J; MORRIS DANIEL P; VIEHBECK ALFRED 权利人:IBM 摘要:A process for the synthesis of derivatives of materials containing an imide group conjugated to an aromatic moiety to form an ester, a thioester, an amide, a ketone, and silylesters. Electrons are supplied to redox sites to form a reduced imide material. The reduced imide material is contacted with a nucleophile which opens the imide ring of the reduced imide and chemically combines with a carbonyl carbon atom of the open imide ring to form an imide derivative.
专利号:US-4481177-A 优先权日:1982-12-09 标 题 :Synthesis of zeolite ZSM-22 with a heterocyclic organic compound 发明人:VALYOCSIK ERNEST W 权利人:MOBIL OIL CORP 摘要:An improved process for preparing ZSM-22 zeolite is disclosed and claimed. The process comprises preparing a reaction mixture comprised of sources of an alkali or alkaline earth metal, alumina, silica, organic promoter and water, and having the following composition, in terms of mole ratios of oxides: n SiO 2 /Al 2 O 3 =20 to ∞ n H 2 O/SiO 2 =10 to 100 n OH - /SiO 2 =0 to 1.0 n M + /SiO 2 =0 to 2.0 n RN/SiO 2 =0.01 to 2.0 n wherein RN is a functional group of a heterocyclic organic compound containing one or more four (4) to ten (10) member, saturated or unsaturated, non-fused rings, wherein the hetero atoms are the same or different, and they are oxygen, phosphorus or nitrogen, an alkyl and/or alkene derivative of the heterocyclic organic compound, wherein the alkyl and/or alkene groups contain one (1) to ten (10) carbon atoms, or an organic or inorganic salt of the heterocyclic organic compound or its alkyl or alkene derivative, and M is an alkali or alkaline earth metal, e.g., Na, K, Cs, Li, Ca or Sr, and maintaining the reaction mixture at crystallization conditions until crystals of the ZSM-22 zeolite are formed.
专利号:US-10864507-B2 优先权日:2016-05-11 标题:Method for the synthesis of a ZSM-22 zeolite, a metal containing zeolite and its application in hydromerization of long chain n-paraffins 发明人:SONTYANA ANANTH KISHORE KUMAR; MUNUSAMY KUPPUSAMY; GHOSH SAYANTI; PAI SHIVANAND MUKUND; KUMAR LALIT; KASTURE MAHESH WAMANRAO; NEWALKAR BHARAT LAKSHMAN 权利人:BHARAT PETROLEUM CORPORATION LTD 摘要:The present invention provides a process for preparing a zeolite by hydrothermal heating of silica precursor and alumina precursor along with a combination of two structure-directing organic templates, N,N-dimethyl formamide and 1,6-diaminohexane in the presence of an alkali. The use of two structure-directing organic templates, not only reduces the crystallization time but also enables the preparation of more catalytically active ZSM-22 of submicron crystallite size. The present invention also provides a process of preparing a noble metal containing zeolite catalyst for hydroisomerization of long chain n-paraffins.
专利号:US-2019176137-A1 优先权日:2016-05-11 标 题:Method for the synthesis of a zsm-22 zeolite, a metal containing zeolite and its application in hydromerization of long chain n-paraffins
专利号:US-11964875-B2 优先权日:2022-03-24 标 题 :Synthesis of *MRE framework type molecular sieves 发明人:XIE DAN; JENSEN KURT OWEN; OJO ADEOLA FLORENCE 权利人:CHEVRON USA INC 摘要:A method is provided for synthesizing *MRE molecular sieves using an organic structure directing agent which comprises a 1-ethylpyridinium cation.
参考标题:A Convenient Synthesis Of Triflate Anion Ionic Liquids And Their Properties 作者:Nikolai V. Ignat'Ev,Peter Barthen,Andryi Kucheryna,Helge Willner,Peter Sartori 摘要:Synthesis Of High Purity Triflate Ionic Liquids Via Direct Alkylation Of Organic Bases (Amines, Phosphines Or Heterocyclic Compounds) With Methyl And Ethyl Trifluoromethanesulfonate (Methyl And Ethyl Triflate) Has Been Developed. Cheap And Non-Toxic Dimethyl And Diethyl Carbonate Serve As Source For The Methyl And Ethyl Groups In The Preparation Of Methyl And Ethyl Triflate By This Invented Process. The Properties
合成参考文献
摘要:Krohn, K.; Böker, N., Science of Synthesis, (2006) 28, 371.