CAS: 499-49-0; 5-Methylisophthalic Acid

该化合物是一种二碳基酸衍生物,其特点是在异硫酸结构的5位置存在一个甲基组,该化合物主要用作高性能聚合物合成的构件,如聚酯和聚酰胺,其硬性芳香核心和功能性碳基基组有助于提高热稳定性和机械性能;甲基替代物与非代用异硫酸相比,提高了有机溶液的溶性,有助于将其纳入专门的共聚物;还用于生产金属有机框架和作为精细化学合成的中间体;其定义明确的结构和再活性使其成为研究和工业应用中有价值的试剂.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

3,5-dimethylbenzoic acid 1-(3,5-dimethyl-phenyl)-2-methyl-propene 5-methyl-cyclohexa-1,3-diene-1,3,5-tricarboxylic acid 1,3,5-trimethyl-benzene diethyl 5-methylisophthalate benzene-1,3,5-tricarboxylic acid 5-Methylisophthalsaeure-dimethylester 5-methylisophthaloyl dichloride

合成工艺路线路线简述

    均三甲苯置于叔丁基过氧化氢体系中,用 水 作为反应溶剂,化学反应 24.0H,以38%的收率获得产物5-甲基间苯二酸
    参考文献:Surveying Iron-organic Framework Tal-1-Derived Materials In Ligandless Heterogeneous Oxidative Catalytic Transformations Of Alkylarenes
    标题:Surveying Iron-organic Framework Tal-1-Derived Materials In Ligandless Heterogeneous Oxidative Catalytic Transformations Of Alkylarenes
    摘要:从金属-有机框架(mofs)衍生的碳化材料在催化有机转化中的应用比mofs的应用少得多.在这里,我们调查了从多晶铁-有机框架tal-1衍生的异质催化剂材料的氧化性能.
    DOI:10.1055/s-0037-1611877

    海关参考信息

    专利信息


    专利号:US-9957355-B2
    优先权日:2013-06-12
    标 题 :Device and method for synthesis of a polymer under separation of a gaseous substance
    发明人:ZHU NING; STAMMER ACHIM; CLAUSS JOACHIM; KORY GAD
    权利人:BASF SE
    摘要:The invention relates to a device for synthesis of a polymer under separation of a gaseous substance. Said device comprises a reaction chamber ( 1 ), which has a top section ( 11 ), a middle section ( 12 ) and a bottom section ( 13 ), an inlet opening ( 2 ) which is arranged in the middle section ( 12 ), a first outlet opening ( 3 ) which is arranged in the bottom section ( 13 ), a second outlet opening ( 4 ) which is arranged in the top section ( 11 ), a first return opening ( 51 ), which is arranged in the bottom section ( 13 ), a second outlet opening ( 52 ), which is arranged under the top section ( 11 ), a distribution device ( 6 ), which is arranged between the top section ( 11 ) and the middle section ( 12 ), and a removal device ( 7 ) which is arranged to be movable along the top section ( 11 ). The invention further relates to a method for synthesis of a polymer which can be carried out in said device.

    专利号:US-9631051-B2
    优先权日:2013-06-12
    标 题:Device for the synthesis of a polymer with extraction of a gaseous substance comprising a reaction chamber having at least one circular-cylindrical section
    发明人:ZHU NING; STAMMER ACHIM; CLAUSS JOACHIM; KORY GAD
    权利人:BASF SE
    摘要:An apparatus for synthesis of a polymer with separation of a gaseous substance comprises a reaction space having an essentially circular cylindrical upper section which is bounded by two circular faces and one shell face and has a longitudinal cylinder axis, and a lower section, an inlet orifice disposed in a circular face or the shell face of the upper section, a first outlet orifice disposed in a wall of the lower section, a second outlet orifice disposed in the shell face of the upper section opposite the first outlet orifice, and a removal device which is disposed so as to be rotatable about the longitudinal cylinder axis and is in contact with both circular faces and the shell face. This apparatus can especially be used for performance of a process including the feeding of an oligomer melt into a reaction space through an inlet orifice, the polymerization of the oligomer melt to give a polymer melt, the removal of the polymer melt from the reaction space through a first outlet orifice of the reaction space, and the removal of a gaseous substance from the reaction space through a second outlet orifice of the reaction space, wherein deposits on at least one inner wall of the reaction space are removed by a removal device and transported into the oligomer melt.

    专利号:WO-2025052716-A1
    优先权日:2023-09-06
    标 题:Method for producing mof membrane composite, and mof membrane composite
    发明人:AKAHIRA TOMOYO; KAZAOKA DAIKI; MIYAHARA MAKOTO; NODA KENICHI
    权利人:NGK INSULATORS LTD
    摘要:This method for producing an MOF membrane composite involves: adhering a seed crystal of a CAU-10-type MOF onto a support (step S12); preparing an Al source solution, which is an aqueous solution containing an Al ion source (step S13a); preparing a ligand solution in which an organic ligand used for the synthesis of the CAU-10 type MOF is dissolved in a solvent (step S13b); preparing a raw material solution by mixing, at a speed at which turbidity is not generated, the ligand solution with the Al source solution (step S14); and forming an MOF film, that is, a CAU-10-type MOF, on the support through solvothermal synthesis by immersing the support in the raw material solution (step S15).

    专利号:EP-3007818-A1
    优先权日:2013-06-12
    标题 :Device and method for synthesis of a polymer under separation of a gaseous substance

    专利号:CA-2913498-A1
    优先权日:2013-06-12
    标 题 :Device for the synthesis of a polymer with extraction of a gaseous substance, comprising a reaction chamber having at least one circular-cylindrical section

    专利号:CA-2913501-A1
    优先权日:2013-06-12
    标 题 :Device and method for synthesis of a polymer under separation of a gaseous substance
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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1557/s43579-023-00351-4
    摘要:Sran BS, Hwang JW, Chitale SK, Kim J, Cho K, Jo D, Yoon JW, Lee S, Lee U-. Post-combustion CO2 capture of methyl and nitro mixed-linker CAU-10. MRS Communications. 2023 Mar 17;13(2):343–9. doi: 10.1557/s43579-023-00351-4.
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