3,7,11-三甲基-1,3,6,10-十二碳-四烯置于palladium(II) Acetylacetonate,丙泊酚,三苯基膦,Palladium 10% On Activated Carbon,氢气体系中,用 甲苯 用作溶剂,85.0~115.0 °C,4.0 Mpa 条件下,反应 24.0H,反应生成角鲨烷 参考文献: Catalytic Process For Diene Dimerization[fr] Procédé Catalytique De Dimérisation Des Diènes 标题: Catalytic Process For Diene Dimerization[fr] Procédé Catalytique De Dimérisation Des Diènes 摘要:该发明涉及通过催化过程在无溶剂或含有碳氢化合物溶剂的反应介质中,在特定酚类添加剂的存在下,选择性地对共轭二烯化合物进行头对头二聚化.
专利信息
专利号:US-2024309024-A1 优先权日:2023-03-14 标题 :Direct synthesis of alkenylhalosilanes 发明人:LEWIS KENRICK MARTIN; ZHU YANJUN; BYRNE CHRISTOPHER M 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:A process for the direct synthesis of alkenylhalosilane monomers. Forming a slurry of liquid and copper-activated silicon from fresh silicon, cyclone fines and/or fine dust from silicon grinding, ultrafines and/or spent contact mass from the Direct Synthesis of alkylhalosilanes and arylhalosilanes, in a thermally stable solvent. Reacting the silanes by agitating the slurry with at least one unsaturated aliphatic or cycloaliphatic organohalide of the formula R1X, and optionally an organohalosilane and/or hydrogen halide, in the presence of a polymerization inhibiting Lewis base additive, at a reaction time, temperature and pressure effective to produce alkenylhalosilanes having the formulae, R1SiHX2, R12SiHX, R13SiX, R1SiX3, and R12SiX2 or mixtures thereof.
专利号:WO-2013057134-A1 优先权日:2011-10-19 标 题:Synthesis of semiconductor nanoparticles using metal precursors comprising non- or weakly coordinating anions 发明人:BAHNMUELLER STEFAN; TIAN SUSAN; TIAN SHIZHE; HOHEISEL WERNER 权利人:BAYER IP GMBH; BAYER SOUTH EAST ASIA PTE LTD 摘要:The present invention relates to a method for the synthesis of semiconductor nanoparticles comprising elements of the groups IB, IIB, IIIA, IVA, VA or VIA of the periodic classification wherein the composition of the core nanoparticle is selected from the group consisting of IB-VIA, IIB-VIA, IIIA-VIA, IB-IIIA-VIA or IB-IIB-TVA-VIA, IIB-IIIA-VIA, IIB-TVA-VA or mixtures thereof, and at least one shell comprises elements of the groups IIB and VIA,, wherein in case the core composition is IIB-VIA the shell comprises at least a further element selected from the groups IB, IIIA, IVA or VA, using metal precursors comprising non- or weakly coordinating anions. It further relates to the consecutive process for the synthesis that includes first the preparation of a binary nanoparticle system then modified to make a ternary system which again can be further modified to make a quaternary system.
专利号:US-8722852-B2 优先权日:2006-04-28 标 题 :Cosmetic composition for stimulating the synthesis of proteins of the basement membrane 发明人:ZIEGLER HUGO; IMFELD DOMINIK; STOCKLI MARTIN; HEIDL MARC 权利人:ZIEGLER HUGO; IMFELD DOMINIK; STOCKLI MARTIN; HEIDL MARC; DSM IP ASSETS BV 摘要:Cosmetic composition which can be applied topically, comprising at least one compound of the general formula (I) in which R 1 is H, C 1 -C 20 -alkyl, cycloalkyl or aryl-C 1 -C 4 -alkyl, n is 1-4, X is —O—, —NH— or —NR 2 — and R 2 H or C 1 -C 20 -alkyl; and at least one compound corresponding to the above formula (I) but in which XR 1 with X having the possible meaning of —NH— is the residue of an alpha-amino acid; use of these compounds and of the composition for stimulating the synthesis of the proteins of the basement membrane; and also both those compounds of the formula (I) in which X is —NR 2 — and both R 1 and R 2 are different from H, and the compounds corresponding to formula (I) but in which XR 1 with X having the possible meaning of —NH— is the residue of an alpha-amino acid, as such.
专利号:WO-2024246574-A1 优先权日:2023-06-02 标题:METHOD OF SYNTHESIS OF COLLOIDAL InSb QUANTUM DOTS 发明人:REISS PETER; KWON YONGJU 权利人:COMMISSARIAT A LENERGIE ATOMATIQUE ET AUX ENERGIES ALTERNATIVES; CENTRE NAT RECH SCIENT; UNIV GRENOBLE ALPES 摘要:The present invention relates to a method of synthesis of colloidal InSb quantum dots (InSb QDs) comprising a premixing step of In and Sb precursors at a temperature of less than 100°C, under stirring.
专利号:US-8450456-B2 优先权日:2007-12-21 标题:Activating peptide of the synthesis of aquaporins and cosmetic and/or pharmaceutical composition containing it 发明人:DAL FARRA CLAUDE; DOMLOGE NOUHA; BOTTO JEAN-MARIE 权利人:DAL FARRA CLAUDE; DOMLOGE NOUHA; BOTTO JEAN-MARIE; ISP INVESTMENTS INC 摘要:The present invention concerns a peptide of the general formula (I): n R 1 -(AA) n -X 1 —X 2 —X 3 -Pro-X 4 —X 5 —X 7 -(AA) p -R 2 , capable of activating the synthesis of proteins of the family of aquaporins. n The present invention also concerns a cosmetic, nutraceutical or pharmaceutical composition, comprising a peptide of general formula (I) as active principle. The invention also relates to the use of this new active principle in a cosmetic or nutraceutical composition, intended to improve the moisturizing and the barrier function of the epidermis and intended to stimulate cutaneous regeneration. The invention also relates to the use of this new active principle to realize a pharmaceutical composition, and in particular a dermatological composition, intended to regulate and/or stimulate the activity of the aquaporins and to thus treat the pathological dryness of the skin or mucosa. The invention also relates to a method of cosmetic treatment intended to prevent or combat against dryness of the skin and mucosa, and the manifestations of cutaneous ageing.
专利号:US-2014255328-A1 优先权日:2013-03-11 标 题:Hydrothermal Synthesis of Zinc Phlogopite 发明人:MCGUIRE MEAGHAN CLARK; BULL IVOR; JOHNSON GEOFFREY MARK 权利人:BASF SE 摘要:This invention relates to a synthetically derived zinc phlogopite platelets, of superior platelet diameter, effect pigments comprising such synthetically derived platelets and methods of forming said substrates. More specifically the disclosure describes an improved hydrothermal synthesis of zinc phlogopite suitable as a platelets for interference pigments, barrier and flame retardant applications.
1: Kim L, Czyszczon-Burton TM, Nguyen KM, Stukey S, Lazar S, Prana J, Miao Z, Park S, Chen SF, Inkpen MS. Low Vapor Pressure Solvents for Single-Molecule Junction Measurements. Nano Lett. 2024 Aug 14;24(32):9998-10005. doi: 10.1021/acs.nanolett.4c02786. Epub 2024 Aug 2. 2: van Elburg F, Grunert F, Aurisicchio C, di Consiglio M, di Ronza R, Talma A, Bernal-Ortega P, Blume A. Exploring the Impact of Bio-Based Plasticizers on the Curing Behavior and Material Properties of a Simplified Tire-Tread Compound. Polymers (Basel). 2024 Jul 1;16(13):1880. doi: 10.3390/polym16131880. 3: Roman MJ, Knight AG, Moon DR, Lane PD, Costen ML, McKendrick KG. Distinguishing Mechanisms for Reactive Uptake at Liquid Surfaces via Angular Distributions of Inelastically Scattered Molecules. J Phys Chem A. 2024 Jul 4;128(26):5166-5174. doi: 10.1021/acs.jpca.4c02917. Epub 2024 Jun 24.
合成参考文献
参考文献:10.1007/s00792-010-0301-z 摘要:Tapilatu YH, Grossi V, Acquaviva M, Militon C, Bertrand JC, Cuny P. Isolation of hydrocarbon-degrading extremely halophilic archaea from an uncontaminated hypersaline pond (Camargue, France). Extremophiles. 2010 Mar;14(2):225–31. doi: 10.1007/s00792-010-0301-z. 参考文献:10.1021/la2020868 摘要:Barrett CA, Singh A, Murphy JA, O'Sullivan C, Buckley DN, Ryan KM. Complete synthesis of germanium nanocrystal encrusted carbon colloids in supercritical CO2 and their superhydrophobic properties. Langmuir. 2011 Sep 06;27(17):11166–73. doi: 10.1021/la2020868.