CAS: 4707-71-5; 9-Phenanthrenecarboxaldehyde

该化合物是有机化合物,其特征是苯丙胺脊柱,其形态为9级,该化合物一般为黄色至浅褐色固体,因其芳香性特性而闻名,该化合物由三根结合的苯乙烯环组成,在乙醇和二氯甲烷等有机溶剂中溶解,但在水中溶解性有限. 9-Phenanthreneboxalhyde,在有机合成中被使用,特别是用于制作各种衍生物和作为合成更复杂的有机分子的中间体.该化合物的再活动主要归因于甲醚功能组,该组可以参与各种化学反应,包括核细胞添加和凝聚反应.此外,该化合物可能表现出荧光性,从而引起对材料科学和光化学的兴趣.在处理该物质时,应当采取安全防范措施,因为如果该物质对健康构成风险,则可能对其构成风险.

结构式图片

相似化合物

837-45-6 2510-55-6 2039-77-2

上下游产品

CAS号4707-72-6 菲-9-甲醇 | CAS号573-17-1 9-溴菲 | CAS号68-12-2 N,N-二甲基甲酰胺 | CAS号51873-96-2 (E)-9-Phenanthr... | CAS号883-20-5 9-甲基菲 | CAS号4885-02-3 1,1-二氯甲醚 | CAS号85-01-8 菲 | CAS号132556-01-5 Phenanthrene-9-... | CAS号16331-54-7 Phenanthrene-9-... | CAS号32870-98-7 9-乙炔菲 | CAS号4707-72-6 菲-9-甲醇 | CAS号951-05-3 Phenanthrene,9-... | CAS号484-17-3 9-菲酚 | CAS号837-45-6 菲-9-甲酸 | CAS号21461-45-0 Phenanthrene,9-... | CAS号19893-74-4 9-Phenanthrenep... | CAS号19893-69-7 9-[(Z)-2-nitrop... | CAS号19889-62-4 [(Z)-4-nitro-5-...

合成工艺路线路线简述

    菲置于三氯化铝,氢氰酸,氯苯体系中,化学反应生成 9-甲醛菲
    参考文献:78.关于氰化氢的研究.第七部分 芳香烃中的醛
    标题:78.关于氰化氢的研究.第七部分 芳香烃中的醛
    摘要:
    DOI:10.1039/jr9360000339

    海关参考信息

    专利信息


    专利号:US-10266565-B2
    优先权日:2011-04-12
    标 题 :Peptide mimetic ligands of polo-like kinase 1 polo box domain and methods of use
    发明人:BURKE JR TERRENCE R; LIU FA; LEE KYUNG S; PARK JUNG-EUN
    权利人:BURKE JR TERRENCE R; LIU FA; LEE KYUNG S; PARK JUNG EUN; THE US SECRETARY DEPARTMENT OF HEALTH & HUMAN SERVICES
    摘要:Novel compounds are provided that bind to polo-like kinases through the polo-box domain. In certain embodiments, the novel compounds are PEGylated peptides. The PEGylated peptides in accordance with the invention demonstrate high PBD-binding affinity. In certain embodiments, the PEGylated peptides have also achieved activities in whole cell systems. The invention also provides compounds that bind polo-like kinases through the polo-box domain and possess reduced anionic charge. Further provided are methods of design and/or synthesis of the PEGylated peptides and methods of use thereof. The invention provides methods of use of the compounds and methods of synthesis of the compounds.

    专利号:US-5175302-A
    优先权日:1987-07-13
    标 题 :Nucleophilic fluoroalkylation of aldehydes
    发明人:STAHLY G PATRICK
    权利人:ETHYL CORP
    摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

    专利号:US-4837327-A
    优先权日:1987-07-13
    标 题 :Process for nucleophilic fluoroalkylation of aldehydes
    发明人:STAHLY G PATRICK
    权利人:ETHYL CORP
    摘要:Aryl difluoromethyl sulfone adds to alkehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

    专利号:US-4999429-A
    优先权日:1989-01-09
    标 题 :Process for the preparation of α,α,β-1-trifluoro-1-olefinic derivatives
    发明人:STAHLY G PATRICK
    权利人:ETHYL CORP
    摘要:Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formula n n RCH(OH)CF.sub.2 SO.sub.2 Ar (I) n n wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.

    专利号:US-11117893-B2
    优先权日:2018-09-24
    标题 :Methods for preparation of substituted pyridines and related novel compounds
    发明人:WATKINS EDMOND BLAKE; UREDI DILIPKUMAR; MOTATI DAMODER REDDY
    权利人:WATKINS EDMOND BLAKE; UREDI DILIPKUMAR; MOTATI DAMODER REDDY; UNION UNIV
    摘要:The present invention relates to novel methods of preparation of substituted pyridines and the compounds produced therefrom. In particular, the present invention provides efficient methods for the construction of diversely substituted pyridines, with varying substitution patterns under simple and metal-free conditions with high atom- and pot-economy and excellent functional group tolerance, and which are useful for the synthesis of natural products.

    专利号:CN-118725333-A
    优先权日:2024-07-19
    标 题 :Keggin type polyacid-based metal organic framework molecular material, synthesis method and application of Keggin type polyacid-based metal organic framework molecular material as photocatalyst
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    主要参考文献

    [参考文献]: Paulo Cicero Nascimento, Et Al. Determination Of Oxygen And Nitrogen Derivatives Of Polycyclic Aromatic Hydrocarbons In Fractions Of Asphalt Mixtures Using Liquid Chromatography Coupled To Mass Spectrometry With Atmospheric Pressure Chemical Ionization. J Sep Sci. 2015 Dec;38(23):4055-62.

    合成参考文献


    摘要:Liu, L.; Wang, D.; Li, C.-J., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 585.
    摘要:G. Culbertson and R. Pettit. J. Am. Chem. Soc. 85, 741 (1963).
    摘要:Cui, H.; An, B.; Zhang, X., Science of Synthesis: Dearomatizations, (2026) .
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