CAS: 1120-36-1; Tetradec-1-Ene

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CAS号21129-09-9 1,2-十四碳二醇 | CAS号10157-76-3 对甲苯磺酸十二酯 | CAS号1826-67-1 乙烯基溴化镁 | CAS号17049-49-9 正辛基镁溴盐 | CAS号2695-47-8 6-溴-1-己烯 | CAS号629-76-5 十五烷醇 | CAS号1002-84-2 十五烷酸 | CAS号54509-73-8 ethene | CAS号928-89-2 6-氯-1-己烯 | CAS号74036-95-6 2-溴十四烷 | CAS号10580-24-2 Undecanoic acid... | CAS号106-18-3 月桂酸丁酯 | CAS号28267-31-4 butyl tridecanoate | CAS号110-36-1 肉豆蔻酸丁酯 | CAS号111-06-8 棕榈酸丁酯 | CAS号35996-97-5 butyl pentadecanoate | CAS号111860-76-5 2-chlorotetrade... | CAS号131156-33-7 ethyl 2-methylt... | CAS号41114-00-5 十五酸乙酯 | CAS号629-59-4 正十四烷

反-7-十四(碳)烯置于(Iprdi)Co(η3-C3H5),Potassium Tert-Butylate,碘,Potassium Hydride体系中,用 四氢呋喃,甲醇,甲基叔丁基醚 用作溶剂,化学反应 44.25H,反应生成1-十四烯
参考文献:链式硼氢化和脱硼氢化反热力学烯烃异构化
标题:链式硼氢化和脱硼氢化反热力学烯烃异构化
摘要:我们报道了一种脱硼氢反应工艺,该工艺可以与链式硼氢化反应相结合,产生内烯烃到末端烯烃的一锅,反热力学,短程或长程异构化.该脱硼氢反应通过包含亲核试剂活化,碘化和碱促进消除的序列发生.异构化在室温下进行,不需要氟化物碱,并且这种异构化的底物范围比我们之前报道的硅烷异构化的底物范围扩大了.
Doi:10.1021/acs.Orglett.1C03124

专利信息

专利号:US-11866398-B2
优先权日:2018-05-15
标 题:Total synthesis of prostaglandin J natural products by stereoretentive metathesis
发明人：LI JIAMING; CHEN XU; AHMED TONIA S; STOLTZ BRIAN M; GRUBBS ROBERT H
权利人:CALIFORNIA INST OF TECHN
摘要:This invention relates generally to the synthesis of Δ12-Prostaglandin J product using stereoretentive ruthenium olefin metathesis catalysts supported by dithiolate ligands. Δ12-Prostaglandin J products were generated with excellent selectivity (>99% Z) and in moderate to high/good yields (47% to 80% yield; 58% to 80% yield).

专利号:US-8314015-B2
优先权日:2010-07-14
标题 :Silicon surface modification for the electrochemical synthesis of silicon particles in suspension
发明人：TU CHANG-CHING; TANG LIANG; VOUTSAS APOSTOLOS T
权利人:TU CHANG-CHING; TANG LIANG; VOUTSAS APOSTOLOS T; SHARP LAB OF AMERICA INC
摘要:A process of silicon (Si) surface modification is provided for the electrochemical synthesis of Si particles in suspension. The process begins with a Si first substrate with a surface, and forms Si particles attached to the surface. Hydrogen-terminated Si particles are created and the first substrate is immersed in a hexane/1-octene (1/1 volume ratio) solution with a catalytic amount of chloroplatinic acid (H 2 PtCl 6 ). 1-octene is bonded with the hydrogen-terminated Si particles, creating modified Si particles, with octane capping ligands, attached to the substrate surface. The first substrate is then exposed to ultrasonication, separating the modified Si particles from the first substrate. After removing the first substrate, a suspension is created of modified Si particles suspended in excess hexane/1-octene.

专利号:US-7247752-B2
优先权日:2004-10-01
标 题 :Methods for the synthesis of astaxanthin
发明人：LOCKWOOD SAMUEL F; TANG PENG CHO; NADOLSKI GEOFF; JACKSON HENRY L; FANG ZHIQIANG; DU YISHU; YANG MIN; GEISS WILLIAM; WILLIAMS RICHARD; BURDICK DAVID
权利人:CARDAX PHARMACEUTICALS INC
摘要:A method used for synthesizing intermediates for use in the synthesis of carotenoids and carotenoid analogs, and/or carotenoid derivatives. In some embodiments, the invention includes methods for synthesizing optically active intermediates useful for the synthesis of optically active carotenoids. Synthesis of optically active carotenoids, in one embodiment, may be accomplished by forming an optically active dihydroxy intermediate from ketoisopherone. The optically active dihydroxy intermediate may be converted into optically active astaxanthin derivatives.

专利号:US-2024051918-A1
优先权日:2022-08-10
标 题 :Sequential and independent synthesis of mercaptans and asymmetrical sulfides in a single reactor
发明人：LASSEN KENNETH M; NWAGWU UGOCHUKWU; HASENBERG DANIEL M
权利人:CHEVRON PHILLIPS CHEMICAL CO LP
摘要:The present disclosure generally relates to processes to produce a mercaptan and an asymmetrical sulfide utilize stacked bed catalyst systems containing CoMo and NiMo, and these processes demonstrate a synergistic reduction in the amount of ethylene, methyl mercaptan, ethyl mercaptan, and H2S in product mixtures. In aspects, the conversion of limiting reactants in the synthesis of asymmetrical sulfides unexpectedly remain high under increased flow rates through the catalyst bed, and under reduced temperatures and pressures. In further aspects, reactor systems configured for the independent synthesis of mercaptans and asymmetrical sulfides in a single fixed bed catalyst vessel are also disclosed as a simplification of existing reactor systems employing separate reactors for separate mercaptan and sulfide syntheses.

专利号:US-7615169-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人：STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-7230101-B1
优先权日:2002-08-28
标 题:Synthesis of methotrexate-containing heterodimeric molecules
发明人：MURTHI KRISHNA K; SMITH CHASE C
权利人:GPC BIOTECH INC
摘要:The present invention relates to novel compositions of methotrexate-containing heterodimeric probe molecules, also known as chemical inducers of dimerization (CID), useful in three-hybrid assays. The invention further relates to synthesis of said compositions and their intermediates. Another aspect of the invention is a method for using the heterodimeric probe molecules described herein in drug screens to identify potential protein targets to a given ligand, optimize protein-ligand interactions, or identify potential ligands for a given protein target. In certain embodiments, the invention contemplates the synthesis of the following methotrexate-containing heterodimeric probe: