CAS: 143-28-2; (Z)-Octadec-9-En-1-Ol

该化合物是分子式C18H36O的单饱和脂肪酒精. 这种化合物又称oleyl酒精, 其特征为9位置的双倍结合, 有助于室温的液体状态. 纯度为85%, 适合于需要中纯度的用途, 如表面活性剂,润滑剂和化妆品配方中的润滑剂. 其不饱和结构增加了化学改变的再活性, 包括酯化和环氧化. 该产品因其生物兼容性以及提高工业和个人护理产品的质质质和稳定性的能力而受到重视. 建议在惰性条件下进行适当的储存以防止氧化.

结构式图片

相似化合物

111-62-6 112-62-9 112-79-8

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号112-80-1 油酸 | CAS号111-62-6 油酸乙酯 | CAS号112-62-9 油酸甲酯 | CAS号73120-38-4 9-°Ctadecenyl iodide | CAS号6110-54-9 4-methylbenzene... | CAS号122-32-7 甘油三油酸酯 | CAS号142-77-8 油酸丁酯 | CAS号14101-91-8 methyl oleate | CAS号693-80-1 乙酸油烯基酯 | CAS号39836-21-0 顺-9-二十一碳烯 | CAS号40165-68-2 dioleylamine | CAS号35153-15-2 (Z)-9-十四碳烯-1-醇 | CAS号52957-16-1 9,10-tetradecenol | CAS号13019-22-2 9-十烯-1-醇 | CAS号50816-18-7 乙酸-9-癸烯基酯 | CAS号506-42-3 反-9-十八烯醇 | CAS号593-31-7 甘油1-油醚-d5 | CAS号3937-56-2 1,9-壬二醇 | CAS号5557-31-3 9-十八烯

合成工艺路线路线简述

    Oleyl Iodide置于氧气,三正丁基氢锡体系中,用 甲苯 用作溶剂,化学反应 24.0H,反应生成油醇
    参考文献:Aerobic Conversion Of Organic Halides To Alcohols. An Oxygenative Radical Cyclization
    标题:Aerobic Conversion Of Organic Halides To Alcohols. An Oxygenative Radical Cyclization
    摘要:
    Doi:10.1021/ja00023A076

    海关参考信息

    专利信息


    专利号:US-12252397-B2
    优先权日:2019-05-02
    标题:Process for the synthesis of nanoparticles of transition metal chalcogenides
    发明人:MONIKA MONIKA; PODDAR PANKAJ
    权利人:COUNCIL SCIENT IND RES
    摘要:A process for the synthesis of transition metal chalcogenides (TMC) having formula (I). More particularly, the present work relates to a one pot single phase process for the synthesis of a TMC system having formula (I) by wet chemistry. Formula (I) is represented as Ax-By.

    专利号:US-4922049-A
    优先权日:1989-01-13
    标 题:Synthesis of cis-olefins
    发明人:BYERS JIM D
    权利人:PHILLIPS PETROLEUM CO
    摘要:A process for the synthesis of cis-olefins from cis-olefinic alcohols consisting essentially of the following steps: n (a) reacting a cis-olefinic alcohol with a source of an alkali metal ion selected from the group consisting of lithium and sodium ions to form a first reaction product, n (b) then contacting said thus formed first reaction product with a sulfonyl halide compound to form a second reaction product, n (c) then containing said thus formed second reaction product with an alkyl magnesium compound and a cuprous salt to form a third reaction product comprising a cis-olefin wherein said steps are carried out in a suitable organic solvent.

    专利号:US-9096519-B2
    优先权日:2013-01-10
    标 题 :Process for the synthesis of ketones from internal alkenes
    发明人:MORANDI BILL; GRUBBS ROBERT H; WICKENS ZACHARY K; LERCH MICHAEL M
    权利人:CALIFORNIA INST OF TECHN
    摘要:The present invention is directed to methods for oxidizing internal olefins to ketones. In various embodiments, each method comprising contacting an organic substrate, having an initial internal olefin, with a mixture of (a) a biscationic palladium salt; and (b) an oxidizing agent; dissolved or dispersed in a solvent system to form a reaction mixture, said solvent system comprising at least one C 2-6 carbon nitrile and optionally at least one secondary alkyl amide, said method conducted under conditions sufficient to convert at least 50 mol % of the initial internal olefin to a ketone, said ketone positioned on a carbon of the initial internal olefin. The transformation occurs at room temperature and shows wide substrate scope. Applications to the oxidation of seed oil derivatives and a bioactive natural product are described.

    专利号:US-9517945-B2
    优先权日:2012-11-28
    标 题:Low-temperature route for precision synthesis of metal oxide nanoparticles
    发明人:ITO DAISUKE; HUTCHISON JAMES E
    权利人:UNIV OREGON
    摘要:Methods for making metal oxide nanoparticles, including mixed metal oxides and core-shell metal oxide nanoparticles, are disclosed. A solution comprising a metal carboxylate and a carboxylic acid is combined with a solvent comprising an alcohol heated to a temperature ≦250° C. for an effective period of time to form metal oxide nanoparticles. The metal may be a group IIIA metal, a group IVA metal, a transition metal, or a combination thereof. A metal oxide shell may be deposited onto metal oxide nanoparticles by dispersing the metal oxide nanoparticles in an alcohol, adding a metal carboxylate, and maintaining the reaction at a temperature ≦200° C. for an effective period of time to form core-shell nanoparticles. The nanoparticles may have a relative size dispersity of ≦20%, and may further comprise a plurality of carboxylic acid, carboxylate, and/or alcohol ligands coordinated to the nanoparticles' outer surfaces.

    专利号:US-2006074259-A1
    优先权日:2004-10-01
    标 题:Process for the enzymatic synthesis of pyroglutamic esters
    发明人:PASCALY MATTHIAS; THUM OLIVER
    权利人:GOLDSCHMIDT GMBH
    摘要:A process for the preparation of compounds according to the general formula (I), n nin which R is a hydrocarbon radical of an alcohol, wherein one or more alcohols of the general formula (II) n nR—OH  (II)n nin which R is as defined above, are esterified and/or transesterified without using significant amounts of solvents, preferably without solvents, preferably under reduced pressure at temperatures below 100° C. in the presence of enzymes from the class of hydrolases with a compound according to the general formula (III), n n nin which R 1 is either hydrogen or a linear or branched alkyl or alkenyl group having 1 to 3 carbon atoms is provided.

    专利号:US-4749818-A
    优先权日:1987-09-30
    标 题:Synthesis of cis-9-tricosene
    发明人:BYERS JIM D; DRAKE CHARLES A
    权利人:PHILLIPS PETROLEUM CO
    摘要:A process for the preparation of cis-9-tricosene is disclosed. Cis-1,9-octadecadiene, which may be obtained by the dehydration of oleyl alcohol, is metallated with an organomagnesium halide, producing cis-9-octadecenylmagnesium halide, which in turn is alkylated with n-pentyl halide to form the desired cis-9-tricosene.
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    主要参考文献


    1: Teke GM, Pott RWM. Design and evaluation of a continuous semipartition bioreactor for in situ liquid-liquid extractive fermentation. Biotechnol Bioeng. 2020 Sep 2. doi: 10.1002/bit.27550. Epub ahead of print. 10(1):11367. doi: 10.1038/s41598-020-68399-z.
    4: Cordova LT, Butler J, Alper HS. Direct production of fatty alcohols from glucose using engineered strains of Yarrowia lipolytica. Metab Eng Commun. 2019 Oct 31;10:e00105. doi: 10.1016/j.mec.2019.e00105.
    5: Jiang Y, Murnane KS, Blough BE, Banga AK. Transdermal Delivery of the Free Base of 3-Fluoroamphetamine: In Vitro Skin Permeation and Irritation Potential. AAPS PharmSciTech. 2020 Mar 25;21(3):109. doi: 10.1208/s12249-020-01649-5. 80(11):2027-2036. doi: 10.2166/wst.2020.015. 9(3):468-474. doi: 10.1021/acssynbio.9b00402. Epub 2020 Mar 9. 55(4):438-447. doi: 10.1080/10934529.2019.1706334. Epub 2020 Mar 9.

    合成参考文献


    摘要:Vasseur, A.; Bruffaerts, J., Science of Synthesis Knowledge Updates, (2016) 2, 133.
    摘要:Kashemirov, B. A.; Błażewska, K.; Justyna, K.; Lyu, J.; McKenna, C. E., Science of Synthesis Knowledge Updates, (2021) 1, 345.
    摘要:Kashemirov, B. A.; Błażewska, K.; Justyna, K.; Lyu, J.; McKenna, C. E., Science of Synthesis Knowledge Updates, (2021) 1, 388.
    摘要:Besson, M.; Pinel, C., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 2, 262.
    摘要:Shi, Y.; Cole-Hamilton, D. J.; Kamer, P. C. J., Science of Synthesis: Catalytic Reduction in Organic Synthesis, (2017) 2, 204.
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