专利号:US-11180507-B2 优先权日:2016-07-08 标题:Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor 发明人:CUI XINYAN; CAO BIN 权利人:UNIV PITTSBURGH COMMONWEALTH SYS HIGHER EDUCATION; UNIV OF PITTSBURGH—OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION 摘要:A method of forming a compound having the formula (I′): (I′) includes the reaction: (II′) in the presence of a base, wherein X is a halo atom selected from the group consisting of Cl, Br and I.
专利号:US-7038828-B2 优先权日:2001-06-25 标 题 :Electrochromic organic polymer synthesis and devices utilizing electrochromic organic polymers 发明人:XU CHUNYE; TAYA MINORU 权利人:UNIV WASHINGTON 摘要:Large contrast ratio and rapid switching laminated electrochromic (EC) polymer device includes transparent electrode, cathodic EC polymer, gel electrolyte, and counter-electrode. Preferably the cathodic EC polymer is a poly(3,4-propylenedioxythiophene) derivative, PProDOT-Me 2 . Counter-electrode is a conductive coating deposited on transparent substrate, with preferred coatings including gold and highly conductive carbon. Lithography and sputtering can be employed to pattern a gold layer, while screen printing can be employed to similarly pattern graphite. Empirical studies of preferred device indicate a color change of high contrast ratio of transmittance (>50% T) is rapidly (0.5–1 s) obtained upon applied 2.5V, repeatable to at least 10,000 times, as estimated by electrochemistry. Dual layer EC devices including PProDOT-Me 2 are also disclosed, as are methods for synthesizing preferred EC polymers. Preferred synthesis method for obtaining PProDOT-Me 2 involves refluxing reagents in toluene in the presence of catalyst, while continually removing methanol byproduct from refluxing solution.
专利号:US-2023132381-A9 优先权日:2016-07-08 标 题 :Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor
专利号:US-2020181163-A1 优先权日:2016-07-08 标 题 :Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor
专利号:JP-2004531770-A 优先权日:2001-06-25 标题 :Synthesis of electrochromic organic polymer and device using electrochromic organic polymer
专利号:EP-1412812-A4 优先权日:2001-06-25 标题 :SYNTHESIS OF ELECTROCHROMIC ORGANIC POLYMERS AND EQUIPMENT WITH ELECTROCHROMIC ORGANIC POLYMERS