CAS: 5989-27-5; (4R)-Limonene

该化合物是无色液体碳氢化合物,被划为单极,主要见于柑橘水果的基本油,有助于其特性芳香;该化合物表现出一种愉快的柑橘香味,广泛用于香味和调味行业;化学,(+)-月球具有C10H16分子配方,具有循环结构,包括一个六人环;其性能为人所熟知,其性能为(+)表明其特定的光学活动;除了其芳香特性外,(+)-月内溶剂还具有溶剂特性,并经常用作清洁产品的天然溶剂;还具有潜在的生物活动,包括抗炎和抗氧化效应;由于其毒性和生物降解性较低,(+)-月球被视为合成溶剂的一种环境友好替代物;然而,它可引起某些个人的皮肤刺激,在各种处理过程中需要谨慎处理的化合物(+).

结构式图片

物理性质

欧盟法规

统一分类与标签压力设备指令-第1组危险流体欧盟化妆品法规附录三-限用物质清单REACH注册ECHA物质欧盟气雾剂指令-标签制度工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号86851-45-8 (R)-(+)-binapht... | CAS号7785-70-8 蒎烯 | CAS号25996-10-5 (Z)-1-bromo-3,7... | CAS号308363-12-4 (R)-香芹醇 | CAS号2102-58-1 香芹醇 | CAS号106-25-2 橙花醇 | CAS号203719-54-4 (+)-柠檬烯 1,2-环氧化物 | CAS号6485-40-1 左旋香芹酮 | CAS号121881-29-6 (R,E)-1-methyl-... | CAS号503-93-5 2,6,6-三甲基-2,4-环... | CAS号89-83-8 麝香草酚 | CAS号491-09-8 Piperitenone | CAS号16750-82-6 (S)-3-Methyl-6β... | CAS号99-49-0 L-香芹酮 | CAS号529-01-1 2-Cyclohexen-1-... | CAS号1195-92-2 (+)-柠檬烯氧化物,顺式和反式的混合物 | CAS号203719-54-4 (+)-柠檬烯 1,2-环氧化物 | CAS号1195-32-0 4-异丙烯基甲苯

合成工艺路线路线简述

  • 合成目标产物 (+)-Dipentene 主要起始原料 2,6-Octadiene, 1-Bromo-3,7-Dimethyl-, (2Z)-
  • (文献来源)合成步骤主要原料 2,6-Octadiene, 1-Bromo-3,7-Dimethyl-, (2Z)-
1-[2-((R)-4-Methyl-Cyclohex-3-Enyl)-Prop-2-Ene-1-Sulfonyl]-Propan-2-One置于aluminum Amalgam体系中,用 四氢呋喃,水 作为反应溶剂,化学反应 4.0H,以58%的收率获得产物甜橙提取物
参考文献:为c-C的新方法末端烯烃的耦合通过一个磺酰烷基化-Desulphinylation序列:合成ë-和ž-α-Bisabolenes
标题:为c-C的新方法末端烯烃的耦合通过一个磺酰烷基化-Desulphinylation序列:合成ë-和ž-α-Bisabolenes
摘要:描述了一种新的方法,该方法基于烯丙基亚磺酸介导的基于磺酰化-烷基化-脱磺酰化过程的末端烯烃的区域特异性cc偶联及其在柠檬烯转化为e-和z-α-双双硼烷中的应用.
DOI:10.1039/c39880000702

海关参考信息

专利信息


专利号:US-11926589-B2
优先权日:2019-07-09
标 题 :Process for the synthesis of non-racemic cyclohexenes
发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
权利人:BASF CORP; CALIFORNIA INST OF TECHN
摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

专利号:US-3676506-A
优先权日:1969-12-29
标题:Synthesis of novel compounds useful for production of juvabione
发明人:CRAWFORD ROBERT J
权利人:PROCTER & GAMBLE
摘要:Disclosed herein are processes for the production of 6-methyl-2(4-methylcyclohex-3-en-1-yl)hept-1-en-4-ol and 2-methyl-6-(4methylcyclohex-3-en-1-yl)heptan-4-ol using metalated limonene as the starting reactant. The novel compounds of the invention are useful in the synthesis of juvabione, a product having juvenile hormone activity.

专利号:US-5399721-A
优先权日:1990-01-12
标题:Synthesis of optically pure 4-aryl-2-hydroxytetronic acids
发明人:HOPPER ALLEN T; WITIAK DONALD T
权利人:UNIV OHIO STATE RES FOUND
摘要:The present invention relates to a method for synthesis of optically pure stereogenically labile 4-aryl-2-hydroxytetronic acids from an optically pure aldehyde. The invention further relates to the use of such optically pure compounds as potent inhibitors of platelet aggregation by working at the level of cyclooxygenase. the invention further relates to the pharmaceutical use of such compounds in the treatment of coronary artery diseases, especially in the treatment and/or prevention of atherosclerosis.

专利号:WO-2024042405-A1
优先权日:2022-08-26
标 题:Compositions and methods for the synthesis of bio-based polymers
发明人:OLIVEIRA ANA; CAPÊTO ANA PAULA; PINTADO MANUELA
权利人:AMYRIS BIO PRODUCTS PORTUGAL UNIPESSOAL LTDA; UNIV CATOLICA PORTUGUESA
摘要:The present disclosure provides compositions and methods for the synthesis of bio-based polymers (e.g., polyurethanes and polyesters) from secondary materials produced during a fermentation process. The disclosure also features intermediates produced during these processes, as well as compositions containing the same.

专利号:US-12234203-B2
优先权日:2020-03-12
标 题:Process for the synthesis of cannabidiol and intermediates thereof
发明人:ANAND RADHIKA; SHARMA SUMIT; SINGH CHAM PANKAJ; GANNEDI VEERANJANEYULU; KUMAR MUKESH; PRATAP SINGH VARUN; PRAKASH RAHUL VISHAV; ASREY VISHWAKARMA RAM; PAL SINGH PARVINDER
权利人:COUNCIL OF SCIENT AND INDUSTRIAL RESEARCH AN INDIAN REGISTERED BODY INCORPORATED UNDER THE REGN OF T; COUNCIL OF SCIENT AND INDUSTRIAL RESEARCH AN INDIAN REGISTERED BODY INCORPORATED UNDER THE REGN OF S
摘要:The present invention relates to process for the preparation of cannabidiol (A) from the coupling of (D) and (E) through the intermediates (C) and (D) starting from compound (B). The invention further relates to the novel compounds (B), (C), (D) and (E) and reagents used in this process. More specifically, this invention provides the manufacturing of Cannabidiol (A) in milligram to gram or kilogram scale.

专利号:US-2024082118-A1
优先权日:2021-05-19
标 题:Topical compositions and methods of preparing the same
发明人:ABRAMOVICH SAGI; AVIDOR GAL; LANDA BENZION
权利人:LANDA LABS 2012 LTD
摘要:There is disclosed a composition comprising a water-insoluble thermoplastic compound capable of stimulating collagen synthesis (CSSC), the CSSC having a molecular weight of more than 0.6 kDa and being dispersed in a polar carrier as nano-elements having an average diameter of 200 nm or less and a viscosity of 107 mPa·s or less. The nano-elements of CSSC can be capable of stimulating the synthesis of skin proteins and/or enabling the delivery of active agents upon their application to a surface to be treated therewith. Methods for preparing the compositions and uses thereof are also provided.
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📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1136/thx.2010.156695
摘要:Ibrahim B, Basanta M, Cadden P, Singh D, Douce D, Woodcock A, Fowler SJ. Non-invasive phenotyping using exhaled volatile organic compounds in asthma. Thorax. 2011 Sep;66(9):804–9. doi: 10.1136/thx.2010.156695.
参考文献:10.2147/ijn.s20903
摘要:Shen Q, Wang Y, Zhang Y. Improvement of colchicine oral bioavailability by incorporating eugenol in the nanoemulsion as an oil excipient and enhancer. Int J Nanomedicine. 2011;6():1237–43.
参考文献:10.2147/ijn.s20353
摘要:Li X, Anton N, Ta TM, Zhao M, Messaddeq N, Vandamme TF. Microencapsulation of nanoemulsions: novel Trojan particles for bioactive lipid molecule delivery. Int J Nanomedicine. 2011;6():1313–25.
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