二苯基二氯化锡 以 四氢呋喃,氯仿 作为反应溶剂,化学反应生成 三苯基氯化锡 参考文献:Vinyl Derivatives Of The Metals. Ii. The Cleavage Of Vinyltin Compounds By The Halogens And By Protonic Acids1 标题:Vinyl Derivatives Of The Metals. Ii. The Cleavage Of Vinyltin Compounds By The Halogens And By Protonic Acids1 摘要: DOI:10.1021/ja01566A027
专利号:US-4762935-A 优先权日:1986-10-06 标题:Precursors and synthesis of methyl-9-oxo-11α,16-dihydroxy-16-vinyl-5-cis-13-trans-prostadienoates 发明人:WISSNER ALLAN; GREEN KENNETH E; HAMANN PHILIP R; LEVIN JEREMY 权利人:AMERICAN CYANAMID CO 摘要:This disclosure describes novel compounds which are useful as precursors in the synthesis of 9-oxo-11α,16-dihydroxy-16-vinyl-5-cis-13-trans-prostadienoate esters which possess activity as hypotensive agents and/or as vasodilators.
专利号:US-12102991-B2 优先权日:2019-07-17 标题:Ligand-directed reticular synthesis of metal-organic frameworks having edge-transitive ALB network topologies 发明人:FARHA OMAR K; CHEN ZHIJIE; LI PENGHAO; STODDART J FRASER 权利人:UNIV NORTHWESTERN 摘要:A series of isoreticular metal-organic frameworks composed of metal nodes connected by rigid trigonal prismatic organic linkers and having a 6,12-coordinatled alb network topology are provided. Also provided are methods of synthesizing the metal-organic frameworks and methods of using the metal-organic frameworks to catalyze the hydrolysis of organic molecules, such as nerve agents, having hydrolysable bonds.
专利号:WO-2025056767-A1 优先权日:2023-09-15 标题 :Process for the preparation of enantiomerically enriched aliphatic amines 发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS 权利人:SYNGENTA CROP PROTECTION AG 摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.
专利号:US-4705866-A 优先权日:1985-12-26 标 题 :Synthesis of N-halogenated phenyl maleimide compounds with tin containing catalysts 发明人:GASTINGER ROBERT G 权利人:ATLANTIC RICHFIELD CO 摘要:A process for the preparation of N-brominated or N-chlorinated phenylmaleimide by reacting maleic anhydride and a brominated or chlorinated aniline compound at temperatures of from about 100 DEG C. to about 210 DEG C. in the presence of tin containing catalyst compound and optionally an inert solvent.
专利号:US-11384044-B2 优先权日:2017-08-03 标 题 :Method for introducing substituent into α,β-unsaturated ketone and method for synthesizing prostaglandin using the same 发明人:SUZUKI MASAAKI; KOYAMA HIROKO 权利人:NAT CT GERIATRICS & GERONTOLOGY 摘要:The present invention provides a method for introducing substituents into the α-position and the β-position of an α,β-unsaturated ketone, which not only can be used for the synthesis of a prostaglandin by a three-component coupling process, but also enables synthesis of a prostaglandin in a high yield by one-pot operation without requiring the use of a large excess amount of any of the three components required for the synthesis or using a highly toxic heavy metal as a catalyst or a solvent that is highly toxic to living bodies, and a method for synthesizing a prostaglandin using the same technical means. n The method for introducing substituents into an α,β-unsaturated ketone according to the present invention is a method for introducing substituents into the carbon at the α-position and the carbon at the β-position of an α,β-unsaturated ketone, including: a first step of mixing alkyllithium and trialkylalkenyl tin in which tin atom binds to the vinyl position of the alkenyl group; a second step of mixing the mixture of the first step and dialkylzinc; a third step of mixing the mixture of the second step and an α,β-unsaturated ketone; and a fourth step of mixing the mixture of the third step and a trifluoromethanesulfonate compound.
专利号:US-9968097-B2 优先权日:2012-05-30 标题:Composition comprising a biological control agent and a fungicide selected from inhibitors of the lipid membrane synthesis, the melanine biosynthesis, the nucleic acid synthesis or the signal transduction 发明人:WACHENDORFF-NEUMANN ULRIKE; ANDERSCH WOLFRAM; STENZEL KLAUS; SPRINGER BERND 权利人:BAYER CROPSCIENCE AG 摘要:The present invention relates to a composition comprising at least one biological control agent. Furthermore, the present invention relates to the use of this composition as well as a method for reducing overall damage of plants and plant parts.
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合成参考文献
参考文献:10.1007/s10646-011-0739-5 摘要:Antizar-Ladislao B, Sarkar SK, Anderson P, Peshkur T, Bhattacharya BD, Chatterjee M, Satpathy KK. Baseline of butyltin contamination in sediments of Sundarban mangrove wetland and adjacent coastal regions, India. Ecotoxicology. 2011 Nov;20(8):1975–83. doi: 10.1007/s10646-011-0739-5.