CAS: 82-35-9; 1,5-Dinitroanthracene-9,10-Dione
该化合物是一种硝基替代炭疽衍生物,主要用作染料和颜料合成的中间体,其结构在1和5个位置上有两个硝基组,加强了其在电子生殖和核生殖替代反应中的回活动.该化合物因其在生产高性能色素方面的作用而受到重视,特别是在纺织和印刷工业中.在受控条件下和可预见的再活性下,其稳定性使它成为复杂的染色分子的可靠前体.此外,1,5-二硝基丙酮在有机溶剂中表现出有利的溶解性,促进了其在工业规模化学工艺中的使用.由于对热和摩擦的潜在敏感性,需要适当处理.
物理性质
- 熔点250°C
- 沸点439.64 °C at 760 mmHg
- 闪点294 °C
- 密度1.631g/cm3
- PSA:120.42
- LogP:2.2784
- 折射率1.714
- 蒸汽压1.02E-12 mmHg at 25 °C
- 溶解性Acetonitrile (Very Slightly), DMSO (Slightly), Methanol (Very Slightly)
- 敏感性常温常压下稳定有毒。可引起皮肤过敏性反应。应防止粉尘飞扬。生产设备应密闭，操作人员应穿戴防护用具。
- 外观形态淡黄色至黄色固体
- 储存条件2-8°C
- 产品应用该品经还原得1,5-二氨基蒽醌,用作蒽醌染料的中间体.
- 性质描述淡黄色针状晶体.熔点384-385°C(422°C).溶于热硝基苯,稍溶于热二甲苯,微溶于乙酸和浓硫酸,略微溶于乙醇,乙醚,苯.能升华.
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
CAS号84-66-2 邻苯二甲酸二乙酯 | CAS号84-65-1 蒽醌 | CAS号57875-61-3 dinitro-anthraq... | CAS号131-11-3 邻苯二甲酸二甲酯； 避蚊酯 | CAS号129-39-5 1,8-二硝基蒽醌 | CAS号82-34-8 1-硝基蒽醌 | CAS号6937-75-3 9,10-Anthracene... | CAS号117-14-6 蒽醌-1,5-二磺酸 | CAS号7664-93-9 硫酸 | CAS号7697-37-2 硝酸 | CAS号27573-16-6 1,4-dihydroxy-5... | CAS号82-46-2 1,5-二氯蒽醌 | CAS号82-21-3 1,5-二苯氧基蒽醌 | CAS号129-40-8 9,10-Anthracene... | CAS号10262-79-0 1,5-diamino-4,8... | CAS号117-12-4 蒽绛酚 | CAS号117-14-6 蒽醌-1,5-二磺酸 | CAS号145-49-3 1,5-二氨基-4,8-二羟基... | CAS号129-39-5 1,8-二硝基蒽醌 | CAS号129-44-2 1,5-二氨基蒽醌合成工艺路线路线简述
- 84-65-1 = 82-35-9
反应条件:1.1 Reagents: Sulfuric Acid,Nitric Acid
标题:Mononitration Of Anthraquinone With Nitric Acid/sulfuric Acid And Purification Of The Product With Aqueous Acetone Containing Sodium Hydroxide
作者:Kameo,Takashi; Et Al
参考文献:Kagaku To Kogyo (Osaka 日期:1988 卷标:62(3) 页码:98-103]
63934-06-5 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
713-36-0 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
84-65-1 = 82-35-9
反应条件:1.1 Reagents: Nitric Acid Solvents: 1,2-Dichloroethane
标题:Trends In Modern Dye-Chemistry. Viii
作者:Ayyangar,N. R.; Et Al
参考文献:Colourage 日期:1989 卷标:36(20) 页码:39-40]
84-65-1 = 82-35-9 + 129-39-5
反应条件:1.1 Reagents: Sulfuric Acid,Nitric Acid Solvents: Water1.2 Reagents: Fuming Sulfuric Acid
标题:Directed Nitration Of Organic Compounds. Iii. Potentiometric Study Of The Nitration Of Anthraquinone
作者:Kozorez,L. A.; Et Al
参考文献:Zhurnal Obshchei Khimii 日期:1989 卷标:59(9) 页码:2067-72]
= 82-35-9 + 84-65-1
反应条件:1.1 Reagents: Nitric Acid; 8 H,333 - 353 K
标题:Sub-4 Nm Nanodiamonds From Graphene-Oxide And Nitrated Polycyclic Aromatic Hydrocarbons At 423 K
作者:Shen,Yuting; Et Al
参考文献:Acs Nano 日期:2021 卷标:15(11) 页码:17392-17400]
84-65-1 + 82-34-8 = 82-35-9 + 129-39-5
反应条件:1.1 Reagents: Sulfuric Acid,Nitric Acid Solvents: Water; 4 H,30 °C
标题:Production Of Dye Using Waste Residue Of 1-Aminoanthraquinone Production
作者:Wang,Qingjun; Et Al
参考文献:Henan Huagong 日期:2008 卷标:25(3) 页码:20-22]
82-43-9 = 82-35-9 + 128-96-1 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
= 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
1468-95-7 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
28871-52-5 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
549-99-5 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
= 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
88-95-9 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
85-52-9 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
885-19-8 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
90-44-8 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506]
1624-32-4 = 82-35-9 + 129-39-5 [标题:Reaction Conditions
标题:Product Class 5: Anthra-9,10-Quinones,Anthra-1,2-Quinones,Anthra-1,4-Quinones,Anthra-2,9-Quinones,And Their Higher Fused Analogues
作者:Krohn,K.; Et Al
参考文献:Science Of Synthesis 日期:2006 卷标:28 页码:367-506
邻苯二甲酸二甲酯 反应生成 1,5-二硝基蒽醌
参考文献:Process For Obtaining 1,5-Dinitro-Anthraquinone Of High Purity
标题:Process For Obtaining 1,5-Dinitro-Anthraquinone Of High Purity
摘要:该发明涉及一种从二硝基蒽醌的原混合物中高纯度获得1,5-二硝基蒽醌的方法.所述混合物在温度范围为150摄氏度至200摄氏度下,与一种沸点大于150摄氏度的酯反应,该酯来源于含有1至4个碳原子的脂肪醇和一元或二元羧酸或磷酸,然后,在可能的冷却后,但温度不低于150摄氏度的情况下,分离出基本上由1,5-二硝基蒽醌组成的不溶物质.
海关参考信息
- 2912110000-甲醛
2912210000-苯甲醛
2914610000-蒽醌
2914190090-其他无环酮 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-3983145-A
优先权日:1973-11-01
标 题:Use of alpha-di(lower alkoxy) anthraquinones in the synthesis of Alizarin Saphirols
发明人：WHITE DAVID L; FITZPATRICK JOSEPH W
权利人:TOMS RIVER CHEMICAL CORP
摘要:Alpha-dihydroxyanthraquinones used as intermediates in the synthesis of many dyestuffs, such as the Alizarin Saphirols (e.g. Color Constitution No. 63000, 63005, 63010, 63011, 63315 and 63610) can be replaced on an equimolar basis by alpha-di(lower alkoxy)anthraquinones. The alpha-di(lower alkoxy) anthraquinones can be converted in a single step, by treatment with oleum, to the corresponding alpha-dihydroxyanthraquinone-beta-disulfonic acids in almost quantitative yield. The corresponding diamine is obtained by dinitrating followed by reduction of the nitro groups. The known intermediate, leuco 1,4,5,8-tetrahydroxyanthraquinone (see C.I. No. 62500) can be obtained either by reduction of the diamine or by reduction of the dinitro compound. In one embodiment, the alpha-di(lower alkoxy)anthraquinone is obtained from dinitroanthraquinone by treatment thereof with methanol and KOH.
专利号:CN-101054681-A
优先权日:2007-02-14
标题:Method for one-step electrolytic synthesis of 1,5-diamino-4,8-dihydroxyanthraquinone
专利号:US-4543214-A
优先权日:1983-06-23
标 题 :Process for the preparation of bromoanthraquinones
发明人：SOMLO TIBOR; REGLI JOHANN
权利人:CIBA GEIGY AG
摘要:A process for the preparation of pure bromoanthraquinones by denitrobrominating corresponding nitroanthraquinones is described. The process comprises treating nitroanthraquinones of the formula I ##STR1## wherein X is hydroxy, mercapto, carboxy or halogen and m is 1, 2, 3 or 4 and n is 1 or 2, in the temperature range from 200° to 350° C. n Bromoanthraquinones of more than 95% purity are valuable starting materials for dye synthesis and can be used directly without further purification.
专利号:RO-104678-B1
优先权日:1989-06-28
标 题 :A process for the synthesis of polyether terranquinones
专利号:CN-111574844-B
优先权日:2020-05-14
标题 :Synthesis method of disperse blue 54
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📌 第三方产品分析报告
合成参考文献
摘要:Schafer, E. W., Jr., W. A. Bowles Jr., and J. Hurlbut. 1983. The acute oral toxicity and repellency and hazard potential of 998 chemicals to one or more species of wild and domestic birds. Archives of Environmental Contamination and Toxicology 12:355-382. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/Q_schafer832.pdf
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