CAS: 932-32-1; 2-Chloro-N-Methylaniline

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CAS号95-51-2 2-氯苯胺 | CAS号74-88-4 碘甲烷 | CAS号50-00-0 甲醛 | CAS号88-73-3 邻氯硝基苯 | CAS号100-61-8 N-甲基苯胺 | CAS号694-80-4 2-溴氯苯 | CAS号74-89-5 氨基甲烷 | CAS号13506-15-5 ethyl N-(2-chlo... | CAS号14924-76-6 N-(2-chlorophen... | CAS号51584-17-9 1-甲基吲哚-3-乙腈 | CAS号875-30-9 1,3-二甲基-1H-吲哚 | CAS号1484-12-4 N-甲基咔唑 | CAS号140669-65-4 2-diphenylphosp... | CAS号16136-58-6 1-甲基吲哚-2-甲酸 | CAS号20200-86-6 1,3,3-三甲基-2,3-二... | CAS号1821-38-1 (2-Ethylphenyl)... | CAS号24438-17-3 1,3-DIMETHYLIND...

甲亚胺酸,N-(2-氯苯基)-,乙基酯置于sodium Acetoxyborohydride体系中,用 四氢呋喃 作为反应溶剂,化学反应 3.0H,反应生成 2-氯-N-甲基苯胺
参考文献:通过甲亚胺酸酯中间体合成单-N-甲基苯胺的简便方法
标题:通过甲亚胺酸酯中间体合成单-N-甲基苯胺的简便方法
摘要:已经开发了具有优异产率的制备单-N-甲基苯胺的通用方法.该方案依赖于nabh 3(oac)还原的亚甲酸酯中间体,该中间体是通过在mcm-41-So 3 H中孔沸石的催化下用原甲酸三乙酯处理一级取代苯胺来定量反应生成的.新开发的程序简便,高效且对环境无害.
DOI:10.1016/j.Tet.2010.06.091

专利信息

专利号:US-6479668-B1
优先权日:1998-09-08
标 题 :Method of producing pyrrolidine derivatives
发明人：MURAOKA HIDEO; SATO HARUYO
权利人:TORAY INDUSTRIES
摘要:A method for producing pyrrolidine derivatives such as 3,4-epoxypyrrolodines, 3-pyrrolidols and the like, by oxidizing 3-pyrrolines with at least one peroxide in the presence of at least one acid is disclosed. The 3-pyrrolines are produced by deriving cis-2-butene compounds from cis-2-butene-1,4-diols and performing a cyclization between the cis-2-butene derivatives and at least one primary amine. The method may be performed as a one-pot synthesis and may be performed as a continuous reaction.

专利号:US-4046757-A
优先权日:1968-10-18
标 题 :2-Optionally substituted alkyl-and phenylsulfonylphenyl-azo-phenyl dyes and a process for their synthesis
发明人：MEYBECK JACQUES; MUELLER CURT; MUELLER FRED
权利人:SANDOZ LTD
摘要:Compounds of the formula ##STR1## wherein R 1 is optionally substituted hydrocarbyl (alkyl or phenyl), n R 2 is hydrogen, alkyl or acylamino, n R 3 is hydrogen, alkyl, substituted alkyl, alkoxy or substituted alkoxy, n Each of R 4 and R 5 is independently hydrogen, alkyl or substituted alkyl, n T is halo, nitro, cyano, alkyl, alkoxy, alkylsulfonyl, sulfamoyl or alkylsulfamoyl, and n n is 0 to 3. These compounds are suitable for the dyeing and printing of textile materials. The dyeings obtained are extremely fast to thermofixation, sublimation, pleating, gas fumes, cross dyeing, rubbing, dry cleaning, chlorine, and wet treatments, such as water, washing and perspiration. The compounds of this invention and other phenylazo-phenyl compounds with an optionally substituted hydrocarbylsulfonyl group (R 1-- SO 2 --) on the diazo component radical in a position ortho to the azo group can be synthesized from the corresponding compounds having a halo atom or nitro group in this position by reaction with a compound of the formula H--SO 2 --R 1 or a salt thereof.

专利号:EP-1334111-A2
优先权日:2000-10-17
标题 :Phosphinoamidite carboxylates and analogs thereof in the synthesis of oligonucleotides having reduced internucleotide charge

专利号:WO-0050406-A1
优先权日:1999-02-22
标 题 :Isoquinoline derivatives and isoquinoline combinatorial libraries
发明人：LEBL MICHAEL
权利人:TREGA BIOSCIENCES INC
摘要:The present invention provides the synthesis of heterocyclic compounds based on the isoquinoline ring. More specifically, the invention provides novel isoquinoline derivatives as well as novel libraries comprised of such compouds.

专利号:WO-0232912-A2
优先权日:2000-10-17
标题 :Phosphinoamidite carboxylates and analogs thereof in the synthesis of oligonucleotides having reduced internucleotide charge

专利号:EP-1334111-A4
优先权日:2000-10-17
标题:PHOSPHINOAMIDITE CARBOXYLATES AND ANALOGUES THEREOF IN THE SYNTHESIS OF OLIGONUCLEOTIDES HAVING REDUCED INTERNUCLEOTIDE LOAD