专利号:US-4035350-A 优先权日:1975-01-30 标 题:Process for the preparation of water-soluble azo dyestuffs by reacting an aromatic amine and a coupling component with alkali metal nitrite or alkyl nitrite in the absence of acid 发明人:LANDLER JOSEF; WORFEL ERHARD 权利人:HOECHST AG 摘要:A new and very advantageous Process had been found for the preparation of azo dyestuffs by diazotation and coupling in which the synthesis is carried out without the hitherto usual addition of an acid, with the proviso that at least one of the diazo and coupling components contains at least one acid group. Besides the saving of reaction material and subsequently of alkali for neutralization of the reaction medium and isolation of the dyestuff, highly concentrated solutions of the dyestuff and salt-free or practically salt-free dyestuffs can be obtained, and waste-water is no longer charged with big amounts of salts.
专利号:CN-108863834-A 优先权日:2018-08-13 标题:A new method for the synthesis of 2-fluoro-1,3-dicarbonyl compounds
专利号:CN-108863834-B 优先权日:2018-08-13 标题:Novel synthesis method of 2-fluoro-1, 3-dicarbonyl compound
参考标题:Hfip-Mediated Strategy Towards β-Oxo Amides And Subsequent Friedel-Craft Type Cyclization To 2‑quinolinones Using Recyclable Catalyst 作者:Arup K. Kabi,Raghuram Gujjarappa,Nagaraju Vodnala,Dhananjaya Kaldhi,Ujjawal Tyagi,Kalisadhan Mukherjee,Chandi C. Malakar |发布日期:2020.11 摘要:A Simple And Cost-Effective 1,1,1,3,3,3-Hexafluoro-2-Propanol (Hfip)-Mediated Protocol For The Synthesis Of β-Oxo Amides Has Been Described By Using Amines And β-Keto Esters As Substrates. The Reaction Conditions Were Found To Be Highly Efficient Towards The Cleavage Of Co Bond And Consequent Formation Of The Products In Excellent Yields And Selectivity. The Obtained β-Oxo Amides Were Further Transformed
合成参考文献
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