专利号:WO-0142331-A1 优先权日:1999-12-09 标题:Fluorene-perylene copolymers and uses thereof 发明人:BECKER STEFAN; FRIEND RICHARD; MUELLEN KLAUS; MACKENZIE DEVIN; MARSITZKY DIRK; SETAYESH SEPAS 权利人:CAMBRIDGE DISPLAY TECH LTD; MAX PLANCK INST FUER POLYMERFO; BECKER STEFAN; FRIEND RICHARD; MUELLEN KLAUS; MACKENZIE DEVIN; MARSITZKY DIRK; SETAYESH SEPAS 摘要:A statistical copolymer of formula (I) is provided wherein: A represents an end-capping unit; B is a moiety of formula (II) or (III), wherein each of R?1 and R2¿ is hydrogen, alkyl, haloalkyl, alkoxy, alkoxyalkyl, aryl and aralkyl; C is a perylene-containing moiety of formula (IV), wherein each of a1, a2, a3 and a4 is 0 or 1, each of b3, b4, b5 and b6 is 0, 1 or 2, each of X?1, X2, X3 and X4¿ is a single bond or a linking unit, and each of R?3, R4, R5 and R6¿ is hydrogen, alkyl, haloalkyl, alkoxy, alkoxyalkyl, aryl, aryloxy or aralkyl; and the ratio x:y is from 80:20 to 99.9:0.1. A kit for the synthesis of the copolymers of the invention and electroluminescent devices incorporating said copolymers are also provided.
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专利号:US-4436858-A 优先权日:1982-05-14 标题:Plasticized polydicyclopentadiene and a method for making the same 发明人:KLOSIEWICZ DANIEL W 权利人:HERCULES INC 摘要:Incorporation of an ester plasticizer having a solubility parameter from about 7.8 to about 10.2 (cal/cc)1/2 increases the flexibility and impact strength of poly(dicyclopentadiene). In a preferred embodiment of the method for poly(dicyclopentadiene) synthesis, the plasticizer is incorporated into at least one or two parts of a metathesis-catalyst system: a catalyst/monomer solution or an activator/monomer solution. The two parts are then combined in the mixing head of a reaction injection molding machine and injected into a mold where the reaction mixture rapidly sets up into a thermoset polymer with greater flexibility and impact strength than is found in the corresponding unplasticized poly(dicyclopentadiene).
参考文献:10.1007/s00216-008-2005-0 摘要:Stoichev T, Baptista MS, Basto MCP, Carvalho PN, Vasconcelos MTSD. Application of SPME to the determination of alkylphenols and bisphenol A in cyanobacteria culture media. Analytical and Bioanalytical Chemistry. 2008 Apr 01;391(1):425–32. doi: 10.1007/s00216-008-2005-0.