CAS: 58656-04-5; Tricyclohexylphosphonium Tetrafluoroborate

上下游产品

tetrafluoroboric acid diethyl ether carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II)[(η6-benzene)IrH2(P(Cy)3)]BF4 tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride

[rucl(=chch3)(Co)(P(Cy)3)2]Bf4 以 二氯甲烷 作为反应溶剂,以90%的收率获得产物[(Cy)3Pch=ch2]Bf4
参考文献:氢化钌(II)前体的乙烯基和卡宾钌(II)配合物.
标题:氢化钌(II)前体的乙烯基和卡宾钌(II)配合物.
摘要:氢化物[ruhcl(co)(l)2] [l = Pipr3(1),Pcy3(2)]与hc(三键)cr(r = H,Ph,Tbu)的反应通过插入炔烃进入相应的乙烯基络合物[rucl(chchr)(co)(l)2,3-8)形成ru-H键,在用hbf4质子化后得到阳离子五配位钌碳烯[rucl(chch2R)(co) (l)2] Bf4,9-14.卡宾配合物与pr3(r = Me,Ipr)和ch3Cn的后续反应导致乙烯基化合物的去质子化和再生或钌-卡宾键的裂解和六配位配合物[rucl(Co)(ch3Cn)2(pipr3)2] Bf4,17和[ruh(co)(ch3Cn)2(pipr3)2] X,18A,B.乙酰基衍生物[ruh(2-O2Cch3)(co)(pcy3)2],19,也通过插入与乙炔和苯乙炔反应反应生成相关的乙烯基络合物[ru(chchr)(kappa2-O2Cch3)(co)(pcy3)2],20,21,其中r
DOI:10.1039/b314425A

专利信息

专利号:US-11718584-B2
优先权日:2019-02-22
标题 :Process for the synthesis anthranilic diamide compounds and intermediates thereof
发明人：KARRI PHANEENDRASAI; PABBA JAGADISH; SHINDE BHARAT UTTAMRAO; KALWAGHE AMOL DNYANESHWAR; MADHAVRAO KAMBLE MARUTI; KLAUSENER ALEXANDER G M; PANMAND DEEPAK SHANKAR
权利人:PI INDUSTRIES LTD
摘要:The present invention disclosed a process for the synthesis of anthranilic diamide compound of formula (I), n n n n n n n n n n wherein, R 1 , R 2 , R 3a , R 3b , R 3c , R 4 , R 5 , R 6 and Z are as defined in the detailed description. The process comprising the step of obtaining a mono- or dicyano substituted aniline compound of formula (IV) which is then converted to an anthranilic acid compound of formula (V) or an anthranilic amide compound of formula (Va). Further, the compound of formula (VI) can be optionally synthesized from compound of formula (IV or V or Va)

专利号:US-9000170-B2
优先权日:2012-03-19
标 题:Process for the preparation of tetracarboxynaphthalenediimide compounds disubstituted with heteroaryl groups
发明人：SCHIMPERNA GIULIANA; PELLEGRINO ANDREA; CHIABERGE STEFANO; BIANCHI GABRIELE
权利人:ENI SPA
摘要:A process for the preparation of a tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups having general formula (I), comprising the reaction of at least one disubstituted N,N′-dialkyl-1,5,8-tetracarboxynaphthalenediimide with at least one heteroaryl compound. Said tetracarboxynaphthalenediimide compound disubstituted with heteroaryl groups can be advantageously used as monomer in the synthesis of semiconductor polymers which can be advantageously used in the construction of organic field effect transistors (OFET) or of organic thin film transistors (OTFT).

专利号:US-2021074930-A1
优先权日:2019-09-06
标题 :Synthesis of ft4-based organic semiconducting small molecules by pd-catalyzed direct (hetero)arylation or direct alkenylation
发明人：HE MINGQIAN; LI YANG; SUN JING; WANG HONGXIANG; ZHOU MONG-DONG
权利人:CORNING INC; UNIV LIAONING SHIHUA
摘要:A method for forming organic semiconducting materials, including: providing a mixture having: a tetrathienoacene (FT4)-based monomer, and one of a thiophene-containing compound or an alkene-containing compound; and reacting the FT4-based monomer with the thiophene-containing compound or the alkene-containing compound in a one-step direct arylation reaction mechanism to form a final FT4-based organic semiconducting compound.

专利号:US-9006491-B2
优先权日:2009-10-22
标题 :Structure and method for synthesizing and using dialkyl(2,4,6- or 2,6-alkoxyphenyl)phosphine and its tetrafluoroborate
发明人：MA SHENGMING; LÃœ BO; FU CHUNLING
权利人:MA SHENGMING; LÃœ BO; FU CHUNLING; UNIV ZHEJIANG
摘要:The current invention relates to the structure, synthesis of dialkyl(2,4,6- or 2,6-alkoxyphenyl)phosphine or its tetrafluoroborate, as well as its applications in the palladium catalyzed carbon-chlorine bond activation for Suzuki coupling reactions and carbon-nitrogen bond formation reactions. The dialkyl(2,4,6- or 2,6-alkoxyphenyl)phosphine or its tetrafluoroborate could coordinate with the palladium catalyst to activate the inert carbon-chlorine bond highly selectively and catalyze Suzuki coupling reaction with arylboronic acid or carbon-nitrogen bond formation reaction with organic amines. The current invention uses only one step to synthesize dialkyl(2,4,6- or 2,6-alkoxyphenyl)phosphine and its tetrafluoroborate is stable in the air. Compared with known synthetic routes of ligands used in activating carbon-chlorine bonds, the method of current invention is short, easy to operate. Moreover, with this type of ligands, the Suzuki coupling products of optically active chlorolactones and arylboronic acids would maintain their configuration and optical purity.

专利号:WO-2023183905-A2
优先权日:2022-03-24
标 题 :Deuterated analogs of pyrrole inhibitors of erk, synthesis thereof and intermediates thereto

专利号:CN-119212985-A
优先权日:2022-03-24
标题:Deuterated analogs of pyrrole inhibitors of ERK, synthesis thereof and intermediates thereof