CAS: 1822-73-7; Phenyl(Vinyl)Sulfane

该化合物是含有硫磺的有机化合物,其特点是乙烯基和苯基功能组,这种反应中间体通常用于有机合成,特别是用于制备含有硫的聚合物和三环化合物,其主要优势包括激进和核循环添加反应中的高度回活动,使其对建造复杂的分子结构具有价值.该化合物在受控条件下的稳定性允许精确的功能化,而该化合物的硫溶能增强与金属催化的交叉组合反应的兼容性.Henyl 乙烯硫化物在材料科学中也被用于改变聚合物特性,例如提高热稳定性或粘附性.建议由于对氧化的敏感性,在惰性大气下进行适当处理.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号20451-53-0 苯基乙烯基亚砜 | CAS号762-55-0 2-chloroethenyl... | CAS号108-98-5 硫酚 | CAS号108-05-4 乙酸乙烯酯 | CAS号74-86-2 乙炔 | CAS号72610-21-0 2-chloro-1-(tri... | CAS号7486-35-3 三丁基乙烯基锡 | CAS号882-33-7 二苯二硫醚 | CAS号4837-01-8 2-溴乙基苯基硫醚 | CAS号622-38-8 苯乙硫醚 | CAS号3230-65-7 3,4-二氢异喹啉 | CAS号20451-53-0 苯基乙烯基亚砜 | CAS号141764-76-3 ethyl 5-methyl-... | CAS号38435-04-0 2,2-二氯环丙基苯砜 | CAS号19297-97-3 diphenyl(2-phen... | CAS号22103-05-5 Benzene,(1-prop... | CAS号75-73-0 四氟化碳 | CAS号76-16-4 六氟乙烷 | CAS号637-69-4 4-甲氧基苯乙烯 | CAS号613-37-6 4-甲氧基联苯

合成工艺路线路线简述

    苯乙硫醚置于manganese(Iv) Oxide,乙酰氯体系中,用 N,N-二甲基甲酰胺 用作溶剂,以66.4%的收率获得苯基乙烯基硫醚
    参考文献:Bellesia,Franco; Ghelfi,Franco; Pagnoni,Ugo Maria,Gazzetta Chimica Italiana,1993,Vol. 123,# 5,P. 289-291
    标题:Bellesia,Franco; Ghelfi,Franco; Pagnoni,Ugo Maria,Gazzetta Chimica Italiana,1993,Vol. 123,# 5,P. 289-291

    海关参考信息

    专利信息


    专利号:US-7098355-B2
    优先权日:2001-09-28
    标题 :Process for synthesis of organometallic compounds
    发明人:HIRAIKE HIROSHI; MORITA TAKEHARU; OZAWA FUMIYUKI; KATAYAMA HIROYUKI
    权利人:SEKISUI CHEMICAL CO LTD
    摘要:A method for synthesizing an organometallic compound, which is usefully utilized as a catalyst for manufacturing polyolefins by ring-opening metathesis polymerization of an olefin having strain in a molecule such as dicyclopentadiene or synthesizing epothilones by ring-dosing metathesis reaction, by an efficient and low cost synthesis method using a starting material which is easily available due to relatively simple chemical structure, and further without any possibility of coexistence of a vinylhetero compound or a vinyl compound exchanged which tends to accompany as an impurity in the system in conventional methods, characterized by reacting a starting material comprising a zero-valent transition metal complex (A) or a polyvalent transition metal complex (A′), a compound (B) or (B′) shown by the following general formula (1) or (4), respectively, and a neutral ligand (C) or (C′), in one step under non-reducing condition or reducing condition.n nR 1 Y 1 CR 2 X 1 2   (1)n nR 4 Y 2 CR 5 X 2 2   (4)

    专利号:WO-9515082-A1
    优先权日:1993-12-02
    标 题:Utilization of phenyl compounds for the control of phytoparasite nematodes
    发明人:GONZALEZ PEREZ JOSE ANTONIO; ESTEVEZ BRAUN ANA; GUTIERREZ RAVELO ANGEL; ESTEVEZ REYES RAFAEL
    权利人:UNIV LA LAGUNA; GONZALEZ PEREZ JOSE ANTONIO; ESTEVEZ BRAUN ANA; GUTIERREZ RAVELO ANGEL; ESTEVEZ REYES RAFAEL
    摘要:The invention relates to the utilization of phenyl compounds for controlling phytoparasites nematodes. It has been discovered that phenyl compounds with substituants which include a vinylic or acetylenic group conjugated with an oxygenated function or with sulfur have a potent nematicide action on phytoparasite nematodes. One object of the invention is to define substances which have not been previously disclosed and which can be used to control phytoparasite nematodes. Another object of the invention is to find new utilizations of mono- and bi-substituted phenyl compound derivatives which have not been described before as nematicides. Said utilizations are not evident when considering the state of the art. The object of this invention is to apply on an industrial scale the phenyl compounds since they may be obtained by means of simple chemical synthesis processes.

    专利号:US-2006030723-A1
    优先权日:2001-09-28
    标 题:Process for synthesis of organometallic compounds

    专利号:US-8034982-B2
    优先权日:2007-04-11
    标 题 :Isotopically tagged synons from 2 carbon precursors
    发明人:MARTINEZ RODOLFO A
    权利人:NEW MEXICO HIGHLANDS UNIVERSITY
    摘要:The use of vinyl sulfides, sulfoxides and sulfones in synthetic chemistry for the production of a wide variety of materials is well known. For example, phenyl vinyl sulfides, sulfoxides and sulfones have been used for the synthesis of important heterocycles, in combinatorial chemistry and as Diels-Alder adducts. Although these compounds have been used extensively for a variety of applications, the isotopically labeled versions have not been reported. A simple route for the isotopically labeled production of these important building blocks has been developed.

    专利号:US-7687635-B2
    优先权日:2002-01-22
    标 题:Metal complexes useful in metathesis and other reactions
    发明人:VERPOORT FRANCIS WALTER CORNELIUS; DE CLERCQ BOB
    权利人:TELENE S A S
    摘要:This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.

    专利号:US-11192908-B2
    优先权日:2018-08-17
    标题:Octamolybdate compounds exhibiting bright emission
    发明人:DANIELS STEVEN; PICKETT NIGEL; SAVJANI NICKY; GAVRILIUC VIRGIL
    权利人:NANOCO 2D MAT LIMITED; UNIV MANCHESTER
    摘要:Methods for the synthesis of a polyoxometalate compounds include heating a metal precursor in the presence of an organic salt. The polyoxometalate compounds produced herein display high photoluminescence quantum yields and photoluminescence maximums in the blue and/or violet regions of the electromagnetic spectrum.
    浙江扬帆新材料股份有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.shoufu.cn
    企业联系电话:0571-88902507;0571-88902517;0571-88902509👤
    📞浙江扬帆新材料股份有限公司 ⚠️参考联系方式
    联系人:唐小姐
    电话:0571-88902507;0571-88902517;0571-88902509

    传真:0571-88902500
    邮箱:shoufu@shoufuchem.com
    通信地址: 浙江省杭州市滨江区信诚路31号扬帆创业大厦
    邮编: 310051
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    地址:浙江省杭州市滨江区信诚路31号扬帆创业大厦
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
    ✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    扬帆新材料(浙江)股份有限公司
    ⚠️ 未注册 · 未认证企业
    ⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
    数据来源于公开网络搜索,平台未作核实,请自行辨别。
    🏢敬请 企业认领
    🏬开设公司展台
    📢获取免费会员权益
    🎖️点亮专属注册企业标签
    📇展现公司完整信息 样本查看立即注册认领 →
    网址: http://www.shoufu.cn
    电话:0571-88902507👤
    📞 扬帆新材料(浙江)股份有限公司⚠️参考联系方式

    电话: 0571-88902507
    邮件:shoufu@shoufuchem.com
    网址: http://www.shoufu.cn
    地址:浙江省上虞市杭州湾工业园区纬三路25号
    🆔 联系时候可告知是从"百琢研"平台获取的信息.
    ⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

    浙江省上虞市杭州湾工业园区纬三路25号
    ⚠️ 未注册 · 未认证企业
    注册入口 备注: 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别. 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
    第 1 / 1 页
    现货

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Laurent Debien, Et Al. Tri- And Tetrasubstituted Functionalized Vinyl Sulfides By Radical Allylation. Org Lett. 2013 Dec 20;15(24):6250-3.

    合成参考文献


    摘要:Fringuelli, F.; Piermatti, O.; Pizzo, F.; Vaccaro, L., Science of Synthesis, (2010) 47, 648.
    摘要:Michalak, M.; Gulajski, L.; Grela, K., Science of Synthesis, (2010) 47, 354.
    摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 47, 467.
    摘要:Wu, X.-F., Science of Synthesis Knowledge Updates, (2014) 1, 328.
    摘要:Wu, X.-F., Science of Synthesis Knowledge Updates, (2014) 1, 339.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知