CAS: 26523-78-4; Tris(2-Nonylphenyl) Phosphite

该化合物是一种受到发育障碍的有机磷化合物,通常用作聚合物中的次级抗氧化剂和稳定剂,其主要功能是通过分解氢氧化物来抑制氧化性降解,从而扩大塑料,弹性体和粘合剂等材料的热和加工稳定性;非苯组会提高有机基质中的溶解性,确保统一分散;该磷酸盐还与主要抗氧化剂协同作用,提高要求应用的总体性能;其水解稳定性和低挥发性使其适合高温处理;此外,它有助于在暴露于长期热或剪切压力的聚合物系统中保持颜色稳定性和机械特性.

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3050-88-2 2622-08-4 31570-04-4

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    专利信息


    专利号:US-7799944-B2
    优先权日:2003-09-05
    标题 :Process for the preparation of (meth)acrylate di-ammonium salts and their use as monomers for the synthesis of polymers
    发明人:VANNESTE PIET; LOENDERS RAF; VANDEN EYNDE IVAN; EECKHAOUDT SABINE
    权利人:TAMINCO N V
    摘要:The invention relates to the preparation of (meth)acrylate di-ammonium salts responding to formula (I) n nwherein R 1 represents hydrogen or methyl, each R 2 , independently, represents an alkyl comprising from 1 to 4 carbon atoms, each R 3 , independently, represents an alkyl or an aralkyl and each X − , independently, represents an anion;n nhaving a high purity and their use as monomers for the synthesis of polymers useful as cationic flocculants.

    专利号:EP-0062322-A1
    优先权日:1981-04-03
    标 题 :Improved process for synthesis of hindered amine stabilizers for polymeric materials
    发明人:LAI JOHN TA-YUAN
    权利人:GOODRICH CO B F
    摘要:Process for the synthesis of hindered polysubstituted α-amino acetamides by reaction of a secondary amine with an α-halo acetamide in a basic organic reaction medium and in the presence of a phase transfer catalyst. The product thus obtained can comprise a multifunctional compound having one or more hindered amino moieties. These compounds are highly effective as UV stabilizers in a variety of plastics, especially the alpha monoolefins.

    专利号:US-2009318592-A1
    优先权日:2005-10-11
    标 题 :Process for the Synthesis of Amine Ethers
    发明人:FREY MARKUS; BROENNIMANN VALERIE
    权利人:CIBA GEIGY CORP
    摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.

    专利号:US-2023047214-A1
    优先权日:2020-02-03
    标题:Methods for microwave synthesis of degradable polymers for drug delivery
    发明人:MURATOGLU ORHUN K; ORAL EBRU; GRINDY SCOTT
    权利人:MASSACHUSETTS GEN HOSPITAL
    摘要:Provided herein are methods of making degradable, additive-blended polymeric materials using microwave radiation and catalysts. The methods can include incorporation of therapeutic materials into the polymeric materials. There also are provided polymeric materials made by the methods and medical devices comprising the polymeric materials made by the methods.

    专利号:US-7402675-B2
    优先权日:2000-05-26
    标题 :Process for the synthesis of amine ethers from secondary amino oxides
    发明人:HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER
    权利人:CIBA SC HOLDING AG
    摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

    专利号:US-4473694-A
    优先权日:1981-04-03
    标 题:Process for the preparation of polysubstituted α-aminoacetamides
    发明人:LAI JOHN T
    权利人:GOODRICH CO B F
    摘要:Process for the synthesis of hindered polysubstituted alpha -amino acetamides which comprises first reacting an alpha -haloacetamide with a base to form an intermediate alpha -lactam which in turn is reacted with a primary or secondary amine. The product thus obtained can comprise a multifunctional compound having one or more hindered amino moieties. These compounds are highly effective as UV stabilizers in a variety of plastics, especially the alpha monoolefins.
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    合成参考文献


    摘要:European Commission; Opinion on Risk Assessment Report on Tris (nonylphenyl)phosphite (TNPP), CAS 26523-78-4, July 2006; Available from, as of Oct 14, 2015:
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    摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
    摘要:Kawamura Y; Kokuritsu Iyakuhin Shokuhin Eisei Kenkyusho Hokoku 128: 17-26 (2010).
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