CAS: 86-52-2; 1-(Chloromethyl)Naphthalene

• 英文名称1-(Chloromethyl)Naphthalene
• 中文名称1-(氯甲基)萘
• IUPAC名称1-(chloromethyl)naphthalene
• 其它别名1-Chloromethyl Naphthalene; Naphthalene, 1-Chloromethyl-; (1-Naphthyl)Methyl Chloride; 1-(Chloromethyl)Naphthalene, ; 1-Bromo-2-(Phenoxymethyl)Benzene97+%; Unii-Kd3Rz3R8C4; Naphthalene, (Chloromethyl)-; 1-(Chl
• CAS编号86-52-2
• MFCD编号:MFCD00004042
• EINECS号:201-678-2
• 分子式:C11H9Cl
• 分子量:176.64
• 产品CID: 1867542
• 产品分类有机原料→分子砌块→芳环类化合物→萘类化合物

• 相似结构搜索
• 产品信息参考;
• InChIKey: XMWGTKZEDLCVIG-UHFFFAOYSA-N
• InChI=1S/C11H9Cl/c12-8-10-6-3-5-9-4-1-2-7-11(9)10/h1-7H,8H2…
• 计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数1.0

相似化合物

物理性质

• 熔点32°C
• 沸点167-169°C at 760 mmHg
• 闪点113°C
• 密度1.2±0.1 g/cm3
• PSA:0.0
• LogP:3.5786
• 折射率1.631
• 蒸汽压0.0±0.5 mmHg at 25°C
• 溶解性Chloroform, Ethyl Acetate (Slightly), Methanol (Sparingly)
• 敏感性易受潮
• 外观形态深棕色熔融后为液体
• 储存条件置于阴暗处,密封, 常温干燥保存
• 产品应用农药,医药,助剂的中间体.
• 性质描述叶状体结晶.熔点47°C,沸点168-170°C(2.67kPa).溶于苯,乙醇.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07 & GHS05;
  注释: Exclamation mark & Corrosion
• 危险类别急性毒性 类别4(经皮)
  急性毒性 类别4(经口)
  皮肤腐蚀 类别1
  严重眼损伤 类别1
  皮肤腐蚀 类别1B
  金属腐蚀物 类别1
• 警示词Danger(危险)
• 危险描述H312 |皮肤接触有害.
  H302 |吞咽有害.
  H314 |造成严重皮肤灼伤和眼损伤.
  H318 |造成严重眼损伤.
  H290 |可能对金属造成腐蚀.
• 防范说明P260-P264-P270-P280-P301+P330+P331-P302+P352-P304+P340-P330-P362+P364-P363-P405-P501
• 危险等级8
• UN编号3261.0
• 危险品标志C,Xn
• 包装等级Ⅱ
• 安全声明26-36/37/39-45-60-20-27
• 危险类别码21/22-34-36/37/38-36-20/21/22
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 1-Chloromethyl Naphthalene 主要起始原料 Formaldehyde And Naphthalene
• 4780-79-4 = 86-52-2
  反应条件:1.1 Reagents: Pyridine,Thionyl Chloride Solvents: Diethyl Ether; Rt -> -5 °C; 20 Min,-5 °C; 4 H,-5 °C -> 25 °C; 8 H,25 °C1.2 Reagents: Water
  标题:Enantioselective,Lewis Base-Catalyzed Sulfenocyclization Of Polyenes
  作者:Tao,Zhonglin; Et Al
  参考文献:Journal Of The American Chemical Society 日期:2018 卷标:140(10) 页码:3569-3573]
  
  = 86-52-2
  反应条件:1.1 Reagents: Trifluoromethanesulfonyl Chloride Catalysts: Iron Chloride (Fecl3) Solvents: Acetonitrile; 12 H,25 - 28 °C1.2 Reagents: Sodium Chloride Solvents: Water
  标题:Light-Induced Fecl3-Catalyzed Selective Benzyl C-H Chlorination With Trifluoromethanesulfonyl Chloride
  作者:Yang,Chen-Xi; Et Al
  参考文献:Advanced Synthesis & Catalysis 日期:2023 卷标:365(23) 页码:4144-4149]
  
  = 86-52-2 [标题:Reaction Conditions
  标题:Reactions Of Allyl Arylmethyl Sulfides With Dichlorocarbene Under Conditions Of Phase-Transfer Catalysis
  作者:Al-Shura,A. M.; Et Al
  参考文献:Vestnik Moskovskogo Universiteta 日期:1990 卷标:31(4) 页码:392-7]
  
  61767-59-7 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of 1H-Cyclobuta[de]Naphthalene By Organometallic Methodology
  作者:Yang,Lau S.; Et Al
  参考文献:Journal Of The Chemical Society 日期:1983 卷标:(16) 页码:866-8]
  
  119-64-2 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  447-53-0 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  67-71-0 + 529-34-0 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  530-93-8 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  573-57-9 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  612-17-9 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  4780-79-4 = 86-52-2
  反应条件:1.1 Reagents: Thionyl Chloride Solvents: Chloroform; < 10 °C; 30 Min,30 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water; Ph 8
  标题:Studies On Novel 2-Imidazolidinones And Tetrahydropyrimidin-2(1H)-Ones As Potential Tace Inhibitors: Design,Synthesis,Molecular Modeling,And Preliminary Biological Evaluation
  作者:Dasgupta,Shirshendu; Et Al
  参考文献:Bioorganic & Medicinal Chemistry 日期:2009 卷标:17(10) 页码:3604-3617]
  
  4780-79-4 = 86-52-2
  反应条件:1.1 Reagents: Thionyl Chloride Solvents: Toluene,Perfluorohexane; 12 H,Rt
  标题:Fluorous Solvent As A New Phase-Screen Medium Between Reagents And Reactants In The Bromination And Chlorination Of Alcohols
  作者:Nakamura,Hiroyuki; Et Al
  参考文献:Organic Letters 日期:2003 卷标:5(8) 页码:1167-1169]
  
  5121-00-6 = 86-52-2
  反应条件:1.1 Catalysts: Bis[tris(2-Methylphenyl)Phosphine]Palladium,Dicyclohexyl[3,6-Dimethoxy-2′,4′,6′-Tris(1-Methylethyl)[1,1′-Biphenyl]-2-Yl]Phos... Solvents: Toluene; 20 H,130 °C
  标题:Pd-Catalyzed Decarbonylative Cross-Couplings Of Aroyl Chlorides
  作者:Malapit,Christian A.; Et Al
  参考文献:Organic Letters 日期:2017 卷标:19(15) 页码:4142-4145]
  
  = 86-52-2
  反应条件:1.1 Reagents: N-Chloro-N-Cyclohexylbenzenesulfonamide Catalysts: Benzil Solvents: Benzene; Heated
  标题:N-Chloro-N-Cyclohexylbenzene Sulfonamide
  作者:Maynard,George D.
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1]
  
  = 86-52-2
  反应条件:1.1 Reagents: Chlorosuccinimide Catalysts: 2,3-Dichloro-5,6-Dicyano-1,4-Benzoquinone,N-Hydroxyphthalimide Solvents: Acetonitrile; 3 H,80 °C
  标题:N-Hydroxyphthalimide/benzoquinone-Catalyzed Chlorination Of Hydrocarbon C-H Bond Using N-Chlorosuccinimide
  作者:Li,Zi-Hao; Et Al
  参考文献:Organic & Biomolecular Chemistry 日期:2019 卷标:17(13) 页码:3403-3408]
  
  = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis By Substitution Of Carbonyl Oxygen
  作者:Pfeiffer,W. D.
  参考文献:Science Of Synthesis 日期:2007 卷标:35 页码:155-165]
  
  7093-91-6 = 86-52-2
  反应条件:1.1 Reagents: Iron Chloride (Fecl3)
  标题:Arylmethyl Isocyanates
  作者:Kozhushko,B. N.; Et Al
  参考文献:Zhurnal Organicheskoi Khimii 日期:1984 卷标:20(4) 页码:721-7]
  
  = 86-52-2
  反应条件:1.1 Reagents: Hydrochloric Acid,Phosphoric Acid
  标题:Antimicrobial Activity Of Nitrogen-Containing Compounds Synthesized From Chloromethylated Naphthalene
  作者:Babakhanov,R. A.; Et Al
  参考文献:Azerbaidzhanskii Khimicheskii Zhurnal 日期:1985 卷标:(5) 页码:100-2]
  
  21792-52-9 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  2461-35-0 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  529-34-0 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854]
  
  53597-17-4 = 86-52-2 [标题:Reaction Conditions
  标题:Synthesis Of Naphthalenes,Anthracenes,9H-Fluorenes,And Other Acenes
  作者:Toyota,S.; Et Al
  参考文献:Science Of Synthesis 日期:2010 卷标:45 页码:745-854

海关参考信息

• 2902300000-甲苯
  2902902000-精萘
  2903110000-一氯甲烷及氯乙烷
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管