111-83-1 = 870-08-6 反应条件:1.1 Reagents: Tin Catalysts: Tetrabutylammonium Bromide,Iodine; Rt -> 160 °C; 2 H,160 °C; 160 °C -> 180 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; Rt -> 80 °C; 1 H,80 °C1.3 Reagents: Ethanol; 0.5 H 标题:Synthesis Of Dioctyltin Bis(Isooctyl Thioglycolate) As Thermal Stabilizer For Polyvinyl Chloride 作者:Shi,Tianbing; Et Al 参考文献:Jingxi Shiyou Huagong 日期:2010 卷标:27(2) 页码:58-61
辛基氧代锡烷 以96%的收率获得产物氧化二辛基锡 参考文献:Process For The Fractional Production Of Organotin Compounds 标题:Process For The Fractional Production Of Organotin Compounds 摘要:一种用于分级生产单,二或三有机锡氧化物的方法,包括将有机锡卤化物进行水解,将水解反应混合物分离成三层,从而获得所需的含有三有机锡氧化物的层,该层基本上不含有单和/或二有机锡氧化物,含有单有机锡氧化物的水层,或基本上不含有单和/或三有机锡氧化物的含有二有机锡氧化物的层,然后从所需的有机锡氧化物层中回收三,单或二有机锡氧化物.
专利号:US-12338202-B2 优先权日:2021-09-10 标 题 :One pot synthesis of urea (meth)acrylates 发明人:BESTGEN SEBASTIAN; BEYER SILVIA 权利人:EVONIK OPERATIONS GMBH 摘要:A one-pot synthesis of polymerizable and acyclic urea (meth)acrylates, preferably mono(meth)acrylates, can be performed via in-situ synthesis of urea alcohols or amines followed by direct reaction with a (meth)acrylate reactive diluent. The urea alcohol/amine is obtained from isocyanates and alcohols, amines, or hydroxyamines. Subsequently, the reaction with the (meth)acrylate reactive diluent takes place and the urea (meth)acrylate is directly obtained either in solution with the reactive diluent, or as a pure material after removal of the reactive diluent.
专利号:US-2009105470-A1 优先权日:2005-02-22 标题 :Tin Mediated Regioselective Synthesis of Sucrose-6-Esters 发明人:RATNAM RAKESH; MOFIZUDDIN MOHAMMED; AURORA SUNDEEP 权利人:PHARMED MEDICARE PRIVATE LTD A 摘要:A method is disclosed for regioselective synthesis of sucrose-6-acetate via formation of a novel sucrose-tin adduct using sucrose and DBTO. The novel tin adduct can be represented by a formula (6-O-sucrose)-O—Snbutyl.sub.2-O-(6-O-sucrose) or as 1,3.(di O-sucrose) dibutyl stannylene. The adduct is acylated to yield sucrose-6-acetate or sucrose-6-benzoate as major product.
专利号:US-2024383928-A1 优先权日:2021-07-30 标 题:Production of diorganotin dihalides 发明人:VINCENT ROBERT; ZIMMERMANN JARROD C 权利人:MERCK PATENT GMBH 摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.
专利号:US-7351781-B2 优先权日:2001-04-24 标题 :Synthesis of vinyl polymers by controlled radical polymerization 发明人:WHITE DANIELA; O'DWYER JAMES B 权利人:PPG IND OHIO INC 摘要:A controlled free radical polymerization process, which includes the steps of: adding a monofunctional iniferter compound to an oxygen-free solvent; heating the solution to a temperature sufficient to allow the iniferter compound to form two carbon centered radical residues; adding a first monomer composition comprising one or more monomers to the solution containing the radical containing residues; polymerizing the first monomer composition to form a quasi-living polymer; and optionally polymerizing a second monomer composition comprising one or more monomers, which are different than the first monomer composition. The resulting non-random copolymer having the general formula:n nφ-[-A p -B s -] t -φn nwhere A and B are different compositions of ethylenically unsaturated monomers; p is an integer from 1 to 1,000; s is an integer from 0 to 1,000; t is an integer from 1 to 100; and φ is a residue from the iniferter.
专利号:US-6479696-B1 优先权日:1999-07-05 标题:Method for synthesis and process inhibition of isobornyl (meth)acrylate 发明人:KNEBEL JOACHIM; SAAL DORIS 权利人:ROEHM GMBH 摘要:Isobornyl (meth)acrylate is synthesized by a two-stage one-pot process, wherein isobornyl acetate is converted to isoborneol followed by transesterification with (meth)acrylic acid methyl ester, without isolation of the intermediates or purification of the product.
专利号:US-2003018151-A1 优先权日:2001-04-24 标题 :Synthesis of vinyl polymers by controlled radical polymerization
摘要:Arzneimittel-Forschung. Drug Research., 19(934), 1969 [] 摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198 摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/S_schafer851.pdf