CAS: 1758-68-5; 1,2-Diamino-10-Anthracenedione

该化合物是炭疽杆菌家族的有机化合物,其特征为:在炭疽结构的1和2个位置上有两个氨基组(NH2),由三环系统组成,由结合苯环组成;该化合物的特点是其深色,经常显示红色或紫色的阴影,这归因于其可广泛迁移电子的同化系统. 1,2-二氨基丙酮因其在染料制造,特别是纺织工业中的强烈染色性能而已知.此外,该化合物在各个领域都有潜在用途,包括有机电子产品和其他化学合成材料的前体.氨基安基亚基安组的存在还带来某些再活性,适合进一步化学修改.然而,处理该化合物需要谨慎,因为它可能给健康带来风险,因此需要遵守适当的安全措施.

结构式图片

相似化合物

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    海关参考信息

    专利信息


    专利号:US-3983145-A
    优先权日:1973-11-01
    标 题:Use of alpha-di(lower alkoxy) anthraquinones in the synthesis of Alizarin Saphirols
    发明人:WHITE DAVID L; FITZPATRICK JOSEPH W
    权利人:TOMS RIVER CHEMICAL CORP
    摘要:Alpha-dihydroxyanthraquinones used as intermediates in the synthesis of many dyestuffs, such as the Alizarin Saphirols (e.g. Color Constitution No. 63000, 63005, 63010, 63011, 63315 and 63610) can be replaced on an equimolar basis by alpha-di(lower alkoxy)anthraquinones. The alpha-di(lower alkoxy) anthraquinones can be converted in a single step, by treatment with oleum, to the corresponding alpha-dihydroxyanthraquinone-beta-disulfonic acids in almost quantitative yield. The corresponding diamine is obtained by dinitrating followed by reduction of the nitro groups. The known intermediate, leuco 1,4,5,8-tetrahydroxyanthraquinone (see C.I. No. 62500) can be obtained either by reduction of the diamine or by reduction of the dinitro compound. In one embodiment, the alpha-di(lower alkoxy)anthraquinone is obtained from dinitroanthraquinone by treatment thereof with methanol and KOH.

    专利号:US-6596884-B2
    优先权日:1998-06-29
    标 题:Synthesis of hydrogen peroxide
    发明人:BECKMAN ERIC J; HANCU DAN
    权利人:UNIV PITTSBURGH
    摘要:A method for synthesizing hydrogen peroxide comprises the steps of: synthesizing an analog of anthraquinone that is miscible or soluble in carbon dioxide; reacting the analog of anthraquinone with hydrogen in carbon dioxide to produce a corresponding analog of tetrahydroquinone; and reacting the analog of tetrahydroquinone with oxygen to produce the hydrogen peroxide and regenerate the analog of anthraquinone. A chemical compound having the formula: n wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 are independently, the same or different, H, R C , or R S R C , wherein R S is a spacer group and R C is a fluoroalkyl group, a fluoroether group, a silicone group, an alkylene oxide group, a fluorinated acrylate group, or a phosphazine group, and wherein at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8 is not H.

    专利号:US-7772431-B1
    优先权日:1999-07-27
    标 题 :Performance of energy storage devices: potential areas for dendritic chemistry involvement
    发明人:NEWKOME GEORGE R
    权利人:NEWKOME GEORGE R
    摘要:A compound consists of a fractal-like, plain or organometallic array useful for energy storage devices. A dendrimer useful in the synthesis of the fractal-like compound includes a single ligating moiety bound to a surface of each quadrant of the dendrimer. A method of making metallo-based (macro) molecules includes the steps of combining monomers selected from the group consisting of bipyridal- and terpyridal-based ligands with connecting metals and self assembling macrocycles wherein the monomes are interconnected by the metals.

    专利号:US-4661292-A
    优先权日:1984-10-26
    标 题:Process for the preparation of 1,4-diamino-2,3-dicyanoanthraquinone
    发明人:SCHAULIN RUDOLF; GRELAT MAURICE
    权利人:CIBA GEIGY CORP
    摘要:The invention relates to a process for the preparation of 1,4-diamino-2,3-dicyanoanthraquinone, starting from 1,4-diaminoanthraquinones, or salts thereof, of the formula ##STR1## wherein n is 0, 1 or 2. To introduce the two cyanide radicals, the starting material is treated, in the presence of an oxidizing agent, with a compound which donates cyanide ions. The process comprises using as solvent a mixture of a carboxamide, an N-alkylated carboxamide or a lactam and water, which mixture contains more than 10% by weight of water. n 1,4-Diamino-2,3-dicyanoanthraquinone is an important intermediate for the synthesis of textile dyes.

    专利号:US-7060818-B2
    优先权日:2003-02-21
    标题:Synthesis of macrocyclic tetraamido compounds and new metal insertion process
    发明人:HORWITZ COLIN P; GHOSH ANINDYA
    权利人:UNIV CARNEGIE MELLON
    摘要:An improved method of synthesizing a macrocyclic tetraamido compound includes protecting the amino portion of an amino carboxylic acid to form a protected amino carboxylic acid; exposing the protected amino carboxylic acid to a first solvent, preferably a hydrocarbon solvent, such as toluene or 1,2-dichloroethane, dichloromethane, dibromomethane and 1,2-dibromoethane. The carboxylic acid portion of the protected amino carboxylic acid is then converted to an activated carboxylic acid by one of esterification or acid halide formation, to form a protected amino activated carboxylic acid derivative. The protected amino activated carboxylic acid derivative is reacted with a diamine in the presence of a second solvent, such as THF or ,2-dichloroethane, dichloromethane, dibromomethane and 1,2-dibromoethane, to form a protected diamide diamine intermediate. Following deprotection, the diamide diamine intermediate is reacted with an activated diacid, such as an activated malonate, oxalate or succinate derivative to form the macrocyclic tetraamido compound. The macrocyclic tetraamido compound may further be complexed with a transition metal.

    专利号:US-5955633-A
    优先权日:1997-03-20
    标题 :Synthesis of tertiary amine oxides
    发明人:PRABHU VAIKUNTH S
    权利人:GEN ELECTRIC
    摘要:A process is provided for the manufacture of free-flowing solid tertiary amine oxides having N-nitrosodimethylamine levels of less than about 250 ppb. The process comprises heating a mixture of a tertiary amine, a polar hydroxy alkyl solvent, an organic acid, and aqueous hydrogen peroxide, followed by removal of the solvent and water, preferably by azeotropic removal. The resultant tertiary amine oxides have good color without bleaching and are useful without further purification.
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    主要参考文献

    [参考文献]: Francisco Galindo, Et Al. Spectroscopic Studies Of 1,2-Diaminoanthraquinone (Daq) As A Fluorescent Probe For The Imaging Of Nitric Oxide In Living Cells. Photochem Photobiol Sci. 2008 Jan;7(1):126-30.
    [参考文献]: María J Marín, Et Al. Fluorescence Of 1,2-Diaminoanthraquinone And Its Nitric Oxide Reaction Product Within Macrophage Cells. Chembiochem. 2011 Nov 4;12(16):2471-7.
    [参考文献]: D R Iarullina, Et Al. [参考文献]: Mikrobiologiia. 2007 Jul-Aug;76(4):570-2.
    [参考文献]: Francisco Galindo, Et Al. Spectroscopic Studies Of 1,2-Diaminoanthraquinone (Daq) As A Fluorescent Probe For The Imaging Of Nitric Oxide In Living Cells. Photochem Photobiol Sci. 2008 Jan;7(1):126-30.
    [参考文献]: K Seligman, Et Al. Floral Transition And Nitric Oxide Emission During Flower Development In Arabidopsis Thaliana Is Affected In Nitrate Reductase-Deficient Plants. Plant Cell Physiol. 2008 Jul;49(7):1112-21.

    合成参考文献


    摘要:Irudayanathan, F. M.; Lee, S., Science of Synthesis Knowledge Updates, (2019) 2, 18.
    摘要:Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases., 21(12)(27), 1977
    摘要:Schafer, E. W., Jr., W. A. Bowles Jr., and J. Hurlbut. 1983. The acute oral toxicity and repellency and hazard potential of 998 chemicals to one or more species of wild and domestic birds. Archives of Environmental Contamination and Toxicology 12:355-382.
    参考文献:10.1093/pcp/pcn089
    摘要:Seligman K, Saviani EE, Oliveira HC, Pinto-Maglio CA, Salgado I. Floral transition and nitric oxide emission during flower development in Arabidopsis thaliana is affected in nitrate reductase-deficient plants. Plant Cell Physiol. 2008 Jul;49(7):1112–21. doi: 10.1093/pcp/pcn089.
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