CAS: 4645-32-3; Dimethyl Vinylphosphonate

该化合物是有机磷化合物,其特点是其乙烯基和二甲基酯功能组,一般看起来是无色的黄色液体,其气味略微甜;该化合物以其反应性而著称,特别是在聚合化学中,它可以参与各种聚合反应,包括涉及乙烯基体的聚合反应;二甲基乙烯基磷在阻燃剂合成中和作为生产其他含磷化合物的化学中间体中的潜在应用也得到承认;它溶于有机溶剂,但水溶性有限;在处理该物质时,安全考虑十分重要,因为如果吸入或摄入该物质,可能会对健康造成危害;应当采取适当的保护措施;

结构式图片

相似化合物

682-30-4 24630-67-9 128478-99-9

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

methanol vinyldichlorophosphine oxide dimethyl 2-chloroethylphosphonate ethylene dibromide(3-phenyl-4,5-dihydro-isoxazol-5-yl)-phosphonic acid dimethyl ester (2,3-diphenyl-isoxazolidin-5-yl)-phosphonic acid dimethyl ester 2-(Benzhydrylidene-amino)-4-(dimethoxy-phosphoryl)-butyric acid ethyl ester ethenylphosphine

合成工艺路线路线简述

    磷酸三甲酯 反应生成 二甲基-乙烯基磷酸酯
    参考文献:Process For The Preparation Of Vinylphosphonic Acid Diesters And
    标题:Process For The Preparation Of Vinylphosphonic Acid Diesters And
    摘要:通过在酸性或碱性催化剂存在下加热具有公式ch.Sub.3 Cooch.Sub.2 Ch.Sub.2 P(O)(Or).Sub.2的二烷基2-乙酰氧基乙磷酸酯,并将所得产物与具有公式r.Sup.1 C(Or).Sub.3的正酯反应,制备公式ch.Sub.2 .Dbd.Ch--P(O)(Or).Sub.2的乙烯磷酸二酯的方法.

    海关参考信息

    专利信息


    专利号:US-2012184653-A1
    优先权日:2011-01-18
    标 题:Synthesis of linear phosphorus-containing functional fluorocopolymer
    发明人:WANG LIANG; WANG VIKTORIA
    权利人:WANG LIANG; WANG VIKTORIA
    摘要:This invention relates to a synthesis of a linear fluorocopolymer having a plurality of pendant phosphorus-containing functional groups. The synthesized phosphorus-containing fluorocopolymer has chain linearity and narrow molecular weight distributions. It has applications as a lubricant additive that provides friction-reduction, anti-wear, and corrosion protection properties.

    专利号:US-8785629-B2
    优先权日:2009-06-18
    标题 :Phosphonates synthons for the synthesis of phosphonates derivatives showing better bioavailability
    发明人:AGROFOGLIO LUIGI A; ROY VINCENT; PRADERE UGO
    权利人:AGROFOGLIO LUIGI A; ROY VINCENT; PRADERE UGO; CENTRE NAT RECH SCIENT; UNIV ORLEANS
    摘要:Synthons for the synthesis of phosphonates prodrugs POM and POC, especially for direct Cross Metathesis.

    专利号:US-10465033-B2
    优先权日:2016-11-10
    标题:One step synthesis of ultrahigh molecular weight block copolymers
    发明人:URBAN MAREK W
    权利人:UNIV CLEMSON; UNIV CLEMSON RES FOUNDATION
    摘要:Single-step synthesis processes for production of ultrahigh molecular weight block copolymers are described. The ultrahigh molecular weight copolymers can have a molecular weight of about 10 6 or greater and can be formed within a few hours in a surfactant-free environment. The formation process is controlled by initiator-starvation conditions in a sequential polymerization of monomers exhibiting different solubility in the solvent.

    专利号:US-4198354-A
    优先权日:1977-04-09
    标 题:Manufacture of α-formylethanephosphonic acid esters
    发明人:SCHREPFER HANS J; SIEGEL HARDO; THEOBALD HANS
    权利人:BASF AG
    摘要:α-Formylethane-phosphonic acid esters are manufactured by reacting vinylphosphonic acid esters with carbon monoxide and hydrogen in the presence of conventional rhodium-containing hydroformylation catalysts. The reaction is carried out at from 50° to 180° C. and at pressures from 20 to 1,500 bars. The products are intermediates for the synthesis of insecticidally active phosphoric acid ester derivatives.

    专利号:RU-2205834-C2
    优先权日:1997-08-01
    标题 :Method of synthesis of [2-((8,9)-dioxo-2,6-diazobi-cyclo-[5,2,0]non-1(7)-en-2-yl)ethyl]phosphonic acid, method of synthesis of n-[3-(tertiary butyloxy- carbonylamino)propyl]-2-aminoethylphosphonic acid di-c1-c6-alkyl ester, compounds

    专利号:US-11866637-B2
    优先权日:2021-03-31
    标 题:Synthesis and use of grafted graphene in wellbore construction fluids for lubrication and corrosion inhibition
    发明人:SANTRA ASHOK; THAEMLITZ CARL
    权利人:ARAMCO SERVICES CO; SAUDI ARABIAN OIL CO
    摘要:A composition of matter including a mono-facial polymer-grafted graphene particle and an aqueous-based drilling fluid is provided. In the composition, a first side of the graphene particle has a grafted polymer. A method of lubricating a tool surface using the composition of matter is also provided. The method includes providing an aqueous-based drilling fluid, the aqueous-based drilling fluid having a mono-facial polymer-grafted graphene particle, and introducing the aqueous-based drilling fluid into a wellbore such that it contacts a tool surface to form a coated tool. A drilling tool having a mono-facial polymer-grafted graphene particle adhered to its surface is also provided.
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    合成参考文献


    摘要:Virieux, D.; Ayad, T.; Pirat, J.-L.; Volle, J.-N., Science of Synthesis Knowledge Updates, (2018) 1, 322.
    摘要:Jubault, P.; Poisson, T.; Pannecoucke, X., Science of Synthesis Knowledge Updates, (2017) 2, 343.
    摘要:Andersson, C.-M.; Andersson, M., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 64.
    摘要:Dornan, P. K.; Dong, V. M., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 163.
    摘要:Satoh, T.; Miura, M., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 208.
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