CAS: 16437-69-7; (Methylthio)Methyl Acetate

该化合物是一个有机化合物,其特征为酯功能组,其成分为乙酸和甲烷硫醇,该化合物一般是无色的,淡黄色的,有独特的气味,通常被称为甜味或果味,在乙醇和乙醚等有机溶剂中可溶解,但由于其水分恐惧甲基硫酸盐组,其溶解性有限.甲基甲基甲基乙酸酯因其在香味和口味工业中的用途而闻名,有助于各种气味特征.此外,该化合物可作为有机合成的中间体.该化合物一般在正常条件下稳定,但应小心处理,因为若吸入或摄入,可能会对健康造成危害.建议在与该物质合作时采取适当的安全措施,包括使用个人防护设备.

英文名称(Methylthio)Methyl Acetate
中文名称(甲硫基)乙酸甲酯
IUPAC名称methylsulfanylmethyl acetate
其它别名乙酸甲硫甲酯; Methylthiomethyl Acetate
CAS编号16437-69-7
MFCD编号:MFCD00075528
EINECS号:672-764-9
分子式:C4H8O2S
分子量:120.17
产品CID: 835236
产品分类有机原料→分子砌块→脂肪链类化合物

相似结构搜索
产品信息参考;;
InChIKey: LCUMNXCSNFGGGH-UHFFFAOYSA-N
InChI=1S/C4H8O2S/c1-4(5)6-3-7-2/h3H2,1-2H3…
计算化学: 氢键受体数3.0氢键供体数0.0可旋转键数2.0

相似化合物

74758-93-3 74758-91-1

MSDS等安全信息

GHS象形图
GHS符号GHS02 & GHS07;
注释: Flame & Exclamation mark
危险类别易燃液体类别3
特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
警示词Warning(警告)
危险描述H226 |易燃液体和蒸气.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P210-P233-P240-P241-P242-P243-P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P370+P378-P405-P501
危险等级3.2
UN编号3272.0
包装等级Ⅲ
安全声明16-37-26
危险类别码10-36/37/38

欧盟法规

ECHA物质C&L通报

上下游产品

Chloromethyl acetate sodium thiomethoxide chloroform acetic anhydride Dimethyl-acetoxymethyl-sulfonium (methylsulfanyl)methyl phenyl sulfone methylthiomethyl p-tolyl sulfone 2,4-dithiapentane

合成工艺路线路线简述

N-Acetyl Dimethylsulfimide置于乙酰氯体系中,化学反应生成乙酸甲硫甲酯
参考文献:Pummerer Reactions Of N-Acetyliminodialkylsulfuranes
标题:Pummerer Reactions Of N-Acetyliminodialkylsulfuranes
摘要:
Doi:10.1016/s0040-4039(01)97629-4

海关参考信息

2912110000-甲醛
2912120000-乙醛
2915110000-甲酸
2915211900-乙酸
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-8202985-B2
优先权日:2005-10-31
标题:Monomer compositions for the synthesis of polynucleotides, methods of synthesis, and methods of deprotection
发明人：DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINO; CARUTHERS MARVIN H
权利人:DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINO; CARUTHERS MARVIN H; AGILENT TECHNOLOGIES INC; UNIV COLORADO
摘要:Nucleotide monomers, polynucleotides, methods of making each, and methods of deprotecting each, are disclosed. An embodiment of the nucleotide monomer, among others, includes a nucleotide monomer having a heterobase protecting group selected from structures I through III as described herein. An embodiment of the polynucleotide, among others, includes a plurality of nucleotide moieties having a heterobase protecting group selected from one of structures I through III as described herein.

专利号:US-7759471-B2
优先权日:2005-10-31
标题 :Monomer compositions for the synthesis of RNA, methods of synthesis, and methods of deprotection
发明人：DELLINGER DOUGLAS J; TIMAR ZOLTAN; SIERZCHALA AGNIESZKA; DELLINGER GERALDINE; CARUTHERS MARVIN H
权利人:AGILENT TECHNOLOGIES INC; UNIV COLORADO
摘要:Nucleotide monomers, polynucleotides, methods of making each, methods of deprotecting each, and the like are disclosed herein.

专利号:US-2007100138-A1
优先权日:2005-10-31
标题:Monomer compositions for the synthesis of polynucleotides, methods of synthesis, and methods of deprotection

专利号:US-2007100136-A1
优先权日:2005-10-31
标题:Monomer compositions for the synthesis of RNA, methods of synthesis, and methods of deprotection

专利号:EP-2001896-A2
优先权日:2006-03-23
标题 :Monomer compositions for the synthesis of rna, methods of synthesis, and methods of deprotection

专利号:WO-2007112263-A2
优先权日:2006-03-23
标题:Monomer compositions for the synthesis of rna, methods of synthesis, and methods of deprotection