5,5-二甲基环戊烷-1,3-二酮置于alkaline Hypochlorite体系中,化学反应生成 2,2-二甲基琥珀酸 参考文献:Farmer; Ingold; Thorpe,Journal Of The Chemical Society,1922,Vol. 121,P. 157,158 标题:Farmer; Ingold; Thorpe,Journal Of The Chemical Society,1922,Vol. 121,P. 157,158
专利号:US-2010055750-A1 优先权日:2008-09-03 标 题:Polyester synthesis 发明人:WOSNICK JORDAN H 权利人:XEROX CORP 摘要:The present disclosure provides for enzymatic polymerization to produce polyester resins suitable for use in manufacturing toners. In embodiments, crystalline copolymers, which are polyesters, may be synthesized from lactones, cyclic anhydrides, cyclic carbonates, and combinations thereof. These crystalline copolymers, in turn, may be utilized in the synthesis of toner particles.
专利号:US-2024254395-A1 优先权日:2021-06-02 标题 :Pyrolysis of polyurethane compound-containing material in order to recover raw materials 发明人:EIDEN STEFANIE; BELLINGHAUSEN RAINER; WOLF AUREL; HAHN CHRISTIAN; LODDENKEMPER TIM; JENDRZOK CAROLA 权利人:COVESTRO DEUTSCHLAND AG 摘要:The invention relates to a process according to claim 1 and pyrolysis devices used therein for the pyrolysis of pyrolysis stock comprising polyurethane-containing material, allowing carrying out pyrolysis on an industrial scale. According to the invention, even with higher amounts of pyrolysis stock an amount of pyrolysis product is obtained that contains cleavage products which can be reused for the synthesis of polyurethane-containing material.
专利号:US-2024352216-A1 优先权日:2021-08-20 标 题:Pyrolysis of a polymeric polyurethane compound in order to recover raw materials 发明人:EIDEN STEFANIE; BELLINGHAUSEN RAINER; WOLF AUREL; ALBACH ROLF 权利人:COVESTRO DEUTSCHLAND AG 摘要:The invention relates to a method according to claim 1 for the commercial implementation of a pyrolysis, and to pyrolysis devices for the pyrolysis of pyrolysis stock used in this method. The pyrolysis stock contains a polymeric compound having at least one structural polyurethane unit of the formula (I), wherein Q is a hydrocarbon group with 2 to 8 carbon atoms, preferably 3 to 8 carbon atoms, and n represents a number from 2 to 4, most preferably 2, and -* represents a covalent bond to the polymer backbone. The method and the pyrolysis device according to the invention allow, even with higher compounds of pyrolysis stock an amount of pyrolysis product to be obtained that contains cleavage products which can be reused for the synthesis of polyurethane-containing material.
专利号:US-2021370210-A1 优先权日:2018-10-19 标题 :Filter medium, materials and methods for the removal of contaminants 发明人:GOTTSCHALL KLAUS; GOTTSCHALL EVELYN; PFEUFFER PETER 权利人:GOTTSCHALL KLAUS 摘要:Filter media, filter elements, and arrangements of filters, wherein at least one polymeric mesh adsorbent is comprising at least one functional polymer or derivative of a functional polymer, capable of binding contaminants from a gas mixture, preferably proteins, peptides, glycoproteins, lipoproteins, nucleic acids, carbohydrates, and lipids. These contaminants may exhibit allergenic or toxic properties. These contaminants are preferably embedded in aerosols or attached to small particles. Processes for the synthesis of a polymeric mesh, whereas at least one functional polymer is immobilized via generation of amide or ester bonds, whereas all reactants are not activated and not comprising active groups.
专利号:EP-0536083-B1 优先权日:1991-09-30 标题 :Process for the synthesis of dialkyl succinylsuccinate esters and their conversion to dialkyl 2,5-diarylamino-3,6-dihydroterephthalate esters 发明人:CAMPBELL COLIN D DR; JAFFE EDWARD E DR 权利人:CIBA GEIGY AG 摘要:A process for the preparation of dialkyl succinylsuccinate esters from mixtures of dialkyl succinates, formed by separate or in situ transesterification of dimethyl succinate with C<6> to C1/4 alkanols and their conversion to dialkyl 2,5-diarylamino-3,6-dihydroterephthalate esters having high solubility in organic solvents.
专利号:WO-2025124564-A1 优先权日:2023-12-15 标题:Polyester synthesis based on aspartic acid modification 发明人:ZHANG KECHUN; CHEN XI; LEI TENGFEI; LIU SHENGYANG 权利人:MINT BIOTECHNOLOGIES CO LTD 摘要:Provided in the present invention is polyester synthesis based on aspartic acid modification. A monomer of a unique structure of an imide ring is obtained based on aspartic acid and a dibasic acid likely to be cyclized, the monomer is based on the aspartic acid, can be derived from biomass, is low in cost and renewable, meets the requirement of sustainable development, and the unique structure of the monomer can regulate and control various properties of polyester materials, such as the mechanics, temperature resistance, hydrophilicity and hydrophobicity, and crystallization.
[参考文献]: Toney Jh, Et Al. Succinic Acids As Potent Inhibitors Of Plasmid-Borne Imp-1 Metallo-Beta-Lactamase. J Biol Chem. 2001 Aug 24;276(34):31913-8. [参考文献]: Birgitta C Burckhardt, Et Al. The Renal Na(+)-Dependent Dicarboxylate Transporter, Nadc-3, Translocates Dimethyl- And Disulfhydryl-Compounds And Contributes To Renal Heavy Metal Detoxification. J Am Soc Nephrol. 2002 Nov;13(11):2628-38. [参考文献]: Leena Hamberg, Et Al. Breeding Increases The Efficacy Of Chondrostereum Purpureum In The Sprout Control Of Birch. Plos One. 2015 Feb 12;10(2):E0117381. [参考文献]: María C Bernini, Et Al. Thermodynamic And Kinetic Control On The Formation Of Two Novel Metal-Organic Frameworks Based On The Er(Iii) Ion And The Asymmetric Dimethylsuccinate Ligand. Inorg Chem. 2010 Jun 7;49(11):5063-71. [参考文献]: R I Kelley, Et Al. Octenylsuccinic Aciduria In Children Fed Protein-Hydrolysate Formulas Containing Modified Cornstarch. Pediatr Res. 1991 Dec;30(6):564-9.
合成参考文献
摘要:Sawamura, M.; Shimizu, Y., Science of Synthesis: Knowledge Updates, (2024) 2, 231. 参考文献:10.1016/s0304-3835(02)00302-6 摘要:Tamura S, Fukamiya N, Okano M, Tokuda H, Aoi W, Mukainaka T, Nishino H, Tagahara K, Koike K. Cancer chemopreventive effect of quassinoid derivatives. Introduction of side chain to shinjulactone C for enhancement of inhibitory effect on Epstein-Barr virus activation. Cancer Lett. 2002 Nov 08;185(1):47–51. doi: 10.1016/s0304-3835(02)00302-6. 参考文献:10.1385/abab:76:3:161 摘要:Kaluskar VM, Kapadnis BP, Jaspers C, Penninckx MJ. Production of laccase by immobilized cells of Agaricus sp.: induction effect of xylan and lignin derivatives. Appl Biochem Biotechnol. 1999 Mar;76(3):161–70. doi: 10.1385/abab:76:3:161.