CAS: 15555-77-8; Ruthenium, Dichlorotetrakis(Triphenylphosphine)-

该化合物是的协调综合体,其特点是一种中央离子,与4个三苯磷和2个氯化离子相协调;该化合物通常具有平平平面几何学,这是许多 d6金属复合体的特点;其存在有助于其稳定性和有机溶剂溶解性;该产品经常用于催解,特别是在有机合成和各种反应中,如氢化和单质元体;该中心可以进行氧化和减少,使其在红氧化反应中具有多种功能;此外,该化合物的电子特性可能受离子性质的影响,允许金枪鱼再活动;其应用范围包括材料科学和光化学等领域,可以作为合成其他复合体的前体;在处理该化合物时,应注意安全防范措施,许多过渡性金属复合物,因为潜在的毒性和环境问题.

结构式图片

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ruthenium(III) chloride trihydrate triphenylphosphine6H3(CH2NMe2)2-2,6-N,C,N')(PPh3)][RuCl(C6H3(CH2NMe2)2-2,6-N,C,N')(PPh3)] cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

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    专利信息


    专利号:US-9150423-B2
    优先权日:2010-12-07
    标 题:Ammonia synthesis catalyst and ammonia synthesis method
    发明人:HOSONO HIDEO; HARA MICHIKAZU; KITANO MASAAKI; KIM SUNG WNG; MATSUISHI SATORU; TODA YOSHITAKE; YOKOYAMA TOSHIHARU; HAYASHI FUMITAKA
    权利人:HOSONO HIDEO; HARA MICHIKAZU; KITANO MASAAKI; KIM SUNG WNG; MATSUISHI SATORU; TODA YOSHITAKE; YOKOYAMA TOSHIHARU; HAYASHI FUMITAKA; TOKYO INST TECH
    摘要:The present invention provides a catalyst substance that is stable and performs well in the synthesis of ammonia, one of the most important chemical substances for fertilizer ingredients and the like. The catalyst substance exhibits catalytic activity under mild synthesis conditions not requiring high pressure, and is also advantageous from a resource perspective. Further provided is a method for producing the same. This catalyst comprises a supported metal catalyst that is supported on a mayenite type compound including conduction electrons of 10 15 cm −3 or more and serving as a support for the ammonia synthesis catalyst. The mayenite type compound used as the support may take any form, including that of powder, a porous material, a sintered body, a thin-film, or a single crystal. Use of this catalyst makes it possible to increase the electron donating ability toward a transition metal.

    专利号:US-3597510-A
    优先权日:1968-05-15
    标题:Preparation of allylphosphonic acid and esters and salts thereof
    发明人:POLLAK PETER I; SLATES HARRY L
    权利人:MERCK & CO INC
    摘要:PROPENYLPHOSPHONIC ACID AND ESTERS AND SALTS THEREOF ARE PREPARED BY TRANSITIONAL METAL CATALYIZED DOUBLE BOND ISOMERIZATION OF THE CORRESPONDING ALKYLPHOSPHONIC ACID OR ALLYLPHOSPHONATE. THESE COMPOUNDS ARE USEFUL INTERMEDIATES IN THE SYNTHESIS OF ANTIBIOTICALLY ACTIVE ($)(CIS-1,2-EPOXYPROPYL) PHOSPHONIC ACID AND ITS SALTS.

    专利号:US-9688611-B2
    优先权日:2015-10-21
    标 题:Synthesis of (S)-2-acetamido-3-(4-hydroxy-3-(3-methylbut-2-enyl) phenyl) propanoic acid derivatives
    发明人:MANSHA Muhammad; ABBAS YASIR; ULLAH NISAR
    权利人:UNIV KING FAHD PET & MINERALS
    摘要:A method for producing a compound of formula (I) or a pharmaceutically acceptable salt, solvate, tautomer or stereoisomer, such as compound 1 and compound 2 is disclosed. The method proceeds through an O-allylated tyrosine-based compound, such as compound 3 and preferably comprises [3,3] sigmatropic Claisen rearrangement and olefin cross metathesis reactions. In addition, a pharmaceutical composition comprising a compound of formula (I) a tumor necrosis factor (TNF) related apoptosis inducing ligand (TRAIL) and a pharmaceutically acceptable carrier or excipient is disclosed.

    专利号:US-11964260-B2
    优先权日:2016-08-08
    标题:Method for manufacturing ammonia synthesis catalyst, and method for manufacturing ammonia
    发明人:HOSONO HIDEO; KITANO MASAAKI; YOKOYAMA TOSHIHARU; LI JIANG; KAWAMURA SHIGEKI; KISHIDA Kazuhisa
    权利人:TOKYO INST TECH; TSUBAME BHB CO LTD
    摘要:Provided is a method for manufacturing a catalyst with which it is possible to obtain a supported metal ammonia synthesis catalyst, in which there are restrictions in terms of producing method and producing facility, and particularly large restrictions for industrial-scale producing, in a more simple manner and so that the obtained catalyst has a high activity. This method for manufacturing an ammonia synthesis catalyst includes: a first step for preparing 12CaO·7Al 2 O 3 having a specific surface area of 5 m 2 /g or above; a second step for supporting a ruthenium compound on the 12CaO·7Al 2 O 3 ; and a third step for performing a reduction process on the 12CaO·7Al 2 O 3 supporting the ruthenium compound, obtained in the second step. This invention is characterized in that the reduction process is performed until the average particle diameter of the ruthenium after the reduction process has increased by at least 15% in relation to the average particle diameter of the ruthenium before the reduction process.

    专利号:US-2017114004-A1
    优先权日:2015-10-21
    标 题 :Synthesis of (s)-2-acetamido-3-(4-hydroxy-3-(3-methylbut-2-enyl) phenyl) propanoic acid derivatives

    专利号:PL-236164-B1
    优先权日:2017-01-31
    标 题:Synthesis of 1-propenyl ethers
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    合成参考文献


    摘要:Tchabanenko, K., Science of Synthesis Knowledge Updates, (2013) 1, 57.
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