CAS: 2039-82-9; 1-Bromo-4-Vinylbenzene

上下游产品

Vinyl bromide (4-bromophenyl)magnesium bromide 2-phenylethanol 1-(4-bromophenyl)ethanol 5-(4-bromophenyl)-3-phenyl-4,5-dihydroisoxazole [5-(4-bromo-phenyl)-2-phenyl-isoxazolidin-3-yl]-phenyl-methanone 1-p-Bromphenyl-1,2-dimethoxyethan 2-(4-bromophenyl)-1,1-dichlor°Cyclopropane

4-溴苯乙酮置于水,Potassium Carbonate体系中,用 甲醇,N,N-二甲基甲酰胺 用作溶剂,120.0 °C,4.0 Mpa 条件下,反应 26.0H,反应生成对溴苯乙烯
参考文献:碱促进的二氧化碳,胺类和n-甲苯磺酰hydr的偶联:一种新颖且通用的氨基甲酸酯方法
标题:碱促进的二氧化碳,胺类和n-甲苯磺酰hydr的偶联:一种新颖且通用的氨基甲酸酯方法
摘要:已开发出碱促进的二氧化碳,胺和n-甲苯磺酰hydr的三组分偶联剂.建议该反应通过碳正离子中间体进行,并且构成用于合成多种有机氨基甲酸酯的有效且通用的方法.该方法的优点包括使用易于获得的底物,出色的官能团耐受性,广泛的底物范围以及简便的后处理程序.
Doi:10.1002/anie.201410605

专利信息

专利号:WO-2024181781-A1
优先权日:2023-02-27
标 题:Substrate for synthesis of biological polymers having anti-aggregation function and biological polymer synthesis method using same
发明人：JANG MYOUNG HOON; CHOI JAE SUN
权利人:SP2 TX INC
摘要:The present invention relates to a substrate for the synthesis of biological polymers having an anti-aggregation function, and a biological polymer synthesis method using the substrate. The substrate according to an aspect may have anti-aggregation functionality to enable high-yield and high-purity processes in the synthesis of biological polymers.

专利号:US-7956011-B2
优先权日:2005-05-04
标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays
发明人：SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN
权利人:CANCER RES INST ROYAL
摘要:Materials and methods for photodirected synthesis of oligonucleotide arrays on a solid substrate by photodirected synthesis are disclosed which employ a film formed from (i) a photoacid generator that on photolysis generates acid that is capable of directly removing the protecting group of the linker molecules or oligonucleotides and (ii) a polymer substantially lacking electronegative heteroatoms that are capable of hydrogen bonding with photogenerated acid. Methods of synthesizing an oligomer arrays are also described that use a film that restricts diffusion of reactants and products on the substrate during synthesis of the array and which includes a precursor of a deprotecting reagent. The method involves removing one or more of the non-required products of the deprotection reaction from the reactive array elements at which they are produced during the reaction, in order to displace the deprotection reaction towards completion.

专利号:US-11719709-B2
优先权日:2020-02-14
标题 :Water soluble polymer surfactant for synthesis of functionalized polystyrene nanobeads towards detection of bilirubin in human serum
发明人：MAKKAD SARABJOT KAUR; SYAMAKUMARI ASHA
权利人:COUNCIL SCIENT IND RES
摘要:The present invention provides a water soluble polymer surfactant (PS-DGlu) of formula I which is utilized for synthesis of functionalized polystyrene nanobead covalently incorporating (oligo) p-phenylenevinylene (OPV) nanosensor (PSG-OPV-n) which in turn is useful for the detection of bilirubin in human serum. The present invention further provides a process for the preparation of the water soluble polymer surfactant (PS-DGlu) of formula (I) and a mini emulsion polymerization process for the synthesis of PSG-OPV-n.wherein, n is 30-50.The PSG-OPV-n nanosensor beads show selectivity towards detection of bilirubin in presence of interferences such as glucose, sucrose, metal ions, cholesterol, and biliverdin with limit of detection of 20 nM. Ultimately, the invention also provides a kit for visual detection of bilirubin in human serum.

专利号:US-4581416-A
优先权日:1981-01-19
标题 :Process for the synthesis of tertiary phosphine oxides and sulfides, and new tertiary phosphine oxides and sulfides
发明人：BERGERET WILFRID; BOILEAU SYLVIE; GAUTIER JEAN-CLAUDE; RAYNAL SERGE
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The invention relates to processes for the synthesis of tertiary phosphine oxides and sulfides. The process according to the invention consists, in a first step, of reacting a secondary phosphine oxide or sulfide with an optionally activated alkali metal amide, and, in a second step, of reacting the mixture obtained in the first step with an organic halide containing at least one halogenophenyl radical or one halogenomethyl group. Tertiary phosphine oxides and sulfides are complexing agents of high stability.

专利号:US-9834570-B2
优先权日:2013-06-03
标 题 :One step process for regioselective synthesis of α-acyloxy carbonyls
发明人：SUDALAI ARUMUGAM; REDDI RAMBABU; MALEKAR PUSHPA
权利人:COUNCIL SCIENT IND RES
摘要:A regioselective N-Heterocyclic Carbene (NHC) catalyzed one step process for high yield synthesis of α-acyloxy carbonyl compounds is disclosed.

专利号:US-6737504-B2
优先权日:2001-07-30
标 题 :Synthesis of substituted poly(aniline)s
发明人：FREUND MICHAEL S; SHOJI EIICHI
权利人:CALIFORNIA INST OF TECHN
摘要:A method for preparing a wide range of substituted poly(aniline)s from a single precursor is described. The method uses a variety of reactions, including a boron activation/electrophilic displacement reaction resulting in ipso-substitution. The ability to tune the properties of poly(aniline) through the generation of new structures is useful in numerous fields ranging from polymer-based electronics to sensors.