CAS: 24596-19-8; 4-Bromo-2,6-Dimethylaniline

上下游产品

CAS号87-62-7 2,6-二甲基苯胺 | CAS号882642-83-3 2-(4-bromo-2,6-... | CAS号3096-63-7 N-(2,6-dimethyl... | CAS号7647-01-0 盐酸 | CAS号7726-95-6 溴素 | CAS号64-19-7 冰醋酸 | CAS号54827-17-7 3,3′,5,5′-四甲基联苯... | CAS号87-62-7 2,6-二甲基苯胺 | CAS号500287-72-9 利匹韦林 | CAS号50638-54-5 4-溴-N,N,2,6-四甲基苯胺 | CAS号374067-85-3 4-[[4-[(4-溴-2,6... | CAS号454476-59-6 3-(4-amino-3,5-... | CAS号206559-40-2 5-溴-2-氯间二甲苯 | CAS号255850-24-9 4-乙炔-2,6-二甲基-苯胺 | CAS号99725-44-7 5-溴-2-氟-1,3-二甲苯 | CAS号74346-19-3 4-溴-2,6-二甲基苯甲酸

2,6-二甲基苯胺置于氢溴酸,二甲基亚砜体系中,用 水,乙酸乙酯 用作溶剂,化学反应 1.0H,以86%的收率获得4-溴-2,6-二甲基苯胺
参考文献:Dmso和卤化氢对芳烃和杂芳烃的高效实用氧化溴化和碘化:后期功能化的温和方案
标题:Dmso和卤化氢对芳烃和杂芳烃的高效实用氧化溴化和碘化:后期功能化的温和方案
摘要:据报道,通过使用容易获得的二甲基亚砜(dmso)和hx(x = Br,I)试剂,可对芳烃和杂芳烃进行廉价的溴化和碘化的高效实用系统.这种温和的氧化系统显示了用于合成芳基卤化物的通用协议.当与dmso结合使用时,Hx(x = Br,I)被用作卤化试剂,Dmso作为一种温和且廉价的氧化剂参与了本发明的化学反应.该氧化系统适合于天然产物的后期溴化.公斤级实验(> 95%的收率)显示出工业应用的巨大潜力.
Doi:10.1021/acs.Orglett.5B00932

专利信息

专利号:US-2003075216-A1
优先权日:2000-07-21
标题 :Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays

专利号:US-7687635-B2
优先权日:2002-01-22
标 题:Metal complexes useful in metathesis and other reactions
发明人：VERPOORT FRANCIS WALTER CORNELIUS; DE CLERCQ BOB
权利人:TELENE S A S
摘要:This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.

专利号:JP-2014522385-A
优先权日:2011-04-15
标 题:Method for the synthesis of rilpivirine intermediate

专利号:CN-1280315-C
优先权日:2003-12-24
标 题 :Late transition metal catalyst system for the synthesis of branched polyethylene and its application

专利号:JP-5870183-B2
优先权日:2011-04-15
标题:Method for the synthesis of rilpivirine intermediate

专利号:US-2025026766-A1
优先权日:2022-01-12
标题 :Thiazolopyridyl Amide Derivatives as DNA Polymerase Theta Inhibitors
发明人：LI JING; XU WENQING; WANG ZHIWEI
权利人:BEIGENE LTD
摘要:The present invention relates to compounds containing thiazolopyridyl amide structure, the process for their synthesis, as well as the use of such compounds for inhibiting DNA Polymerase Theta (Pol Theta), and in the treatment of various diseases including cancers.