CAS: 63697-96-1; 4-Ethynylbenzaldehyde

上下游产品

4-[(trimethylsilyl)ethynyl]bezaldehyde 4-bromo-1-ethynylbenzene N,N-dimethyl-formamide 1-Formyl-4-ethynyl-1,4-cyclohexadiene (4-ethynylphenyl)methanol ethyl 2-(4-formylphenylethynyl)cyclopentenecarboxylate 1-ethynyl-4-((4-nitrophenyl)ethynyl)benzene 4-((4-ethynylphenyl)ethynyl)benzonitrile

4-三甲基硅乙炔基苯甲醛置于potassium Carbonate体系中,用 甲醇 作为反应溶剂,化学反应 3.0H,以98%的收率获得产物4-乙炔基苯甲醛
参考文献:基于多面体低聚倍半硅氧烷(poss)的树枝状聚合物的可逆自组装.
标题:基于多面体低聚倍半硅氧烷(poss)的树枝状聚合物的可逆自组装.
摘要:通过自组装在二苯并24-24冠8封端的t(10)-Poss树状聚合物和基于t(8)-Poss的六氟磷酸二苄基铵盐之间构建自酸基可转换树状复合物.通过(1)1 H NMR和uv-可见吸收光谱表征其形成及其穿线-脱线性能.
DOI:10.1039/c0Cc03359F

专利信息

专利号:US-6916982-B2
优先权日:2000-07-21
标题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
发明人：LOEWE ROBERT S; TOMIZAKI KIN-YA; LINDSEY JONATHAN S
权利人:UNIV NORTH CAROLINA STATE
摘要:The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I:n nX 1 X m+1 ) m   (I)n nwherein m is at least 1; X 1 is a charge separation group, and X 2 through X m+1 are chromophores. At least one of X 2 through X m+1 has at least one perylene group coupled thereto.

专利号:US-8372986-B2
优先权日:2005-09-30
标 题 :Ruthenium-catalyzed cycloaddition of alkynes and organic azides
发明人：FOKIN VALERY; JIA GUOCHENG; SHARPLESS K BARRY
权利人:SCRIPPS RESEARCH INST; UNIV HONG KONG SCIENCE & TECHN; FOKIN VALERY; JIA GUOCHENG; SHARPLESS K BARRY
摘要:A convenient process for the regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles and 1,4,5-trisubstituted 1,2,3-triazoles from organic azides and alkynes employs catalytic ruthenium.

专利号:US-7022862-B2
优先权日:2003-08-15
标 题:Scalable synthesis of dipyrromethanes
发明人：LINDSEY JONATHAN S; DHANALEKSHMI SAVITHRI; LAHA JOYDEV K; TANIGUCHI MASAHIKO
权利人:UNIV NORTH CAROLINA STATE
摘要:A (preferably nonaqueous) method of making a dipyrromethane is described. The comprises the steps of: (a) providing a reaction system consisting essentially of an aldehyde or acetal, excess pyrrole and a catalyst; (b) reacting the aldehyde or acetal with the pyrrole in the reaction system to form the dipyrromethane therein; (c) quenching the reaction system by adding a base thereto (preferably without simultaneously or concurrently adding water and/or an organic solvent thereto); (d) separating the catalyst from the reaction system; and then (e) separating the pyrrole from the reaction system to produce the dipyrromethane as a residual

专利号:CN-105492891-A
优先权日:2013-08-05
标题:Synthesis of aggregation-induced luminescence material and its synthesis method

专利号:US-2003075216-A1
优先权日:2000-07-21
标题 :Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays

专利号:US-2006009638-A1
优先权日:2004-07-08
标 题:Synthesis of porphyrins designed for attachment to electroactive surfaces via one or more carbon tethers