CAS: 86134-26-1; 2,5-Bis(Trimethylstannyl)Thiophene

• 英文名称2,5-Bis(Trimethylstannyl)Thiophene
• 中文名称2,5-双(三甲基甲锡烷基)噻吩
• IUPAC名称trimethyl-(5-trimethylstannylthiophen-2-yl)stannane
• 其它别名2,5-双(三甲基锡基)噻吩; Trimethyl-(5-Trimethylstannylthiophen-2-yl)Stannane
• CAS编号86134-26-1
• MFCD编号:MFCD01940352
• EINECS号:687-880-5
• 分子式:C10H20SSn2
• 分子量:409.75
• 产品CID: 1861978
• 产品分类有机原料→分子砌块→芳杂环类化合物→噻吩类化合物

• 相似结构搜索
• InChIKey: KKRPPVXJVZKJON-UHFFFAOYSA-N
• InChI=1S/C4H2S.6CH3.2Sn/c1-2-4-5-3-1;;;;;;;;/h1-2H;6*1H3;;…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数2.0

物理性质

• 熔点93-102 °C
• 沸点311.5±52.0 °C at 760 mmHg
• PSA:0.0
• LogP:2.8385
• 外观形态固体
• 储存条件在惰性气体(氮气或氩气)下 2–8 °C

MSDS等安全信息

• GHS象形图
• GHS符号GHS06 & GHS09;
  注释: Skull and crossbones & Environment
• 危险类别急性毒性 类别4(经皮)
  急性毒性 类别3(经口)
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  水生急性毒性 类别1
  急性毒性 类别2(吸入)
  急性毒性 类别1(经皮)
  急性毒性 类别2(经口)
  水生慢性毒性 类别1
• 警示词Danger(危险)
• 危险描述H312 |皮肤接触有害.
  H301 |吞咽会中毒.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H400 |对水生生物毒性极大.
  H330 |吸入致命.
  H310 |皮肤接触致命.
  H300 |吞咽致命.
  H410 |对水生生物毒性极大并具有长期持续影响.
• 防范说明P260-P262-P264-P270-P271-P273-P280-P284-P302+P352-P304+P340-P330-P361+P364-P391-P405-P501
• 危险等级6.1
• UN编号3146.0
• 危险品标志T,N
• 包装等级Ⅰ
• 安全声明35-36/37/39-45-60-61
• 危险类别码21-25-36/38-48/23/25-50/53
• WGK Germany3

欧盟法规

合成工艺路线路线简述

• 合成目标产物 2,5‐ Bis(Trimethylstannyl)Th Iophene 主要起始原料 Thiophene(Siv) (9CI) And Trimethyltin Chloride
• 1066-45-1 + 3141-27-3 = 86134-26-1
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 1 H,-78 °C1.2 Solvents: Tetrahydrofuran; -78 °C; -78 °C -> Rt; Overnight,Rt
  标题:Stille Type P-C Coupling Polycondensation Towards Phosphorus-Crosslinked Polythiophenes With P-Regulated Photocatalytic Hydrogen Evolution
  作者:Zhang,Zhikai; Et Al
  参考文献:Chemical Science 日期:2023 卷标:14(11) 页码:2990-2998]
  
  1066-45-1 = 86134-26-1
  反应条件:1.1 Reagents: Butyllithium,N,N,N′,N′-Tetramethylethylenediamine Solvents: Hexane; 10 Min,0 °C; Rt -> Reflux; 45 Min,Reflux; Reflux -> 0 °C1.2 Solvents: Tetrahydrofuran; 10 Min,0 °C; 15 H,24 °C1.3 Reagents: Ammonium Chloride Solvents: Water
  标题:Chemoselective Cross-Coupling Reactions With Differentiation Between Two Nucleophilic Sites On A Single Aromatic Substrate
  作者:Linshoeft,Julian; Et Al
  参考文献:Organic Letters 日期:2012 卷标:14(22) 页码:5644-5647]
  
  = 86134-26-1
  反应条件:1.1 Reagents: Bromine Solvents: Chloroform; Rt; Overnight,Rt1.2 Reagents: Sodium Bisulfite Solvents: Water2.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 1.5 H,-78 °C2.2 Solvents: Hexane; 1 H,-78 °C; -78 °C -> Rt; Overnight,Rt
  标题:Difluoroterthiophene As Promising Block To Build Highly Planar Conjugated Polymer For Polymer Photovoltaic Cells
  作者:Jhang,Rong-Xian; Et Al
  参考文献:Dyes And Pigments 日期:2021 卷标:188]
  
  2246560-20-1 + 1160823-78-8 = 86134-26-1
  反应条件:1.1 Catalysts: Tri-O-Tolylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 10 Min,80 °C; 10 Min,100 °C; 30 Min,120 °C; 50 Min,140 °C1.2 Reagents: 2-(Tributylstannyl)Thiophene; 10 Min,100 °C; 20 Min,140 °C1.3 Reagents: 2-Bromothiophene; 10 Min,100 °C; 20 Min,140 °C2.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C; 2 H,-78 °C2.2 -78 °C -> Rt; Overnight,Rt
  标题:Dicyanodistyrylbenzene-Based Copolymers For Ambipolar Organic Field-Effect Transistors With Well-Balanced Hole And Electron Mobilities
  作者:Ryu,Hwa Sook; Et Al
  参考文献:Macromolecules (Washington 日期:2018 卷标:51(20) 页码:8258-8267]
  
  1066-45-1 + 1160823-77-7 = 86134-26-1
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C; 2 H,-78 °C1.2 -78 °C -> Rt; Overnight,Rt2.1 Catalysts: Tri-O-Tolylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 10 Min,80 °C; 10 Min,100 °C; 30 Min,120 °C; 50 Min,140 °C2.2 Reagents: 2-(Tributylstannyl)Thiophene; 10 Min,100 °C; 20 Min,140 °C2.3 Reagents: 2-Bromothiophene; 10 Min,100 °C; 20 Min,140 °C3.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C; 2 H,-78 °C3.2 -78 °C -> Rt; Overnight,Rt
  标题:Dicyanodistyrylbenzene-Based Copolymers For Ambipolar Organic Field-Effect Transistors With Well-Balanced Hole And Electron Mobilities
  作者:Ryu,Hwa Sook; Et Al
  参考文献:Macromolecules (Washington 日期:2018 卷标:51(20) 页码:8258-8267]
  
  1296725-01-3 = 86134-26-1
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -73 °C2.1 Reagents: Potassium Tert-Butoxide Solvents: Tert-Butanol; Rt; 1 H,50 °C3.1 Catalysts: Tri-O-Tolylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 10 Min,80 °C; 10 Min,100 °C; 30 Min,120 °C; 50 Min,140 °C3.2 Reagents: 2-(Tributylstannyl)Thiophene; 10 Min,100 °C; 20 Min,140 °C3.3 Reagents: 2-Bromothiophene; 10 Min,100 °C; 20 Min,140 °C4.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C; 2 H,-78 °C4.2 -78 °C -> Rt; Overnight,Rt
  标题:Dicyanodistyrylbenzene-Based Copolymers For Ambipolar Organic Field-Effect Transistors With Well-Balanced Hole And Electron Mobilities
  作者:Ryu,Hwa Sook; Et Al
  参考文献:Macromolecules (Washington 日期:2018 卷标:51(20) 页码:8258-8267]
  
  886746-58-3 + 86134-26-1 = 86134-26-1 + 886746-58-3
  反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium
  标题:Low Band Gap Polymers For Organic Solar Cells
  作者:Bundgaard,Eva; Et Al
  参考文献:Proceedings Of Spie-The International Society For Optical Engineering 日期:2006 卷标:6334]
  
  1066-45-1 + 3141-27-3 = 86134-26-1
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 100 Min,-78 °C1.2 Solvents: Tetrahydrofuran; -78 °C; -78 °C -> Rt; Overnight,Rt
  标题:Conjugated Boron Porous Polymers Having Strong P-π* Conjugation For Amine Sensing And Absorption
  作者:Xue,Cece; Et Al
  参考文献:Macromolecules (Washington 日期:2022 卷标:55(10) 页码:3850-3859]
  
  1066-45-1 = 86134-26-1
  反应条件:1.1 Reagents: Butyllithium,N,N,N′,N′-Tetramethylethylenediamine Solvents: Hexane; 0 °C; 45 Min,Rt -> Reflux; Reflux -> 0 °C1.2 Solvents: Tetrahydrofuran; 10 Min,0 °C; 15 H,24 °C1.3 Reagents: Ammonium Chloride
  标题:Dual Selectivity: Electrophile And Nucleophile Selective Cross-Coupling Reactions On A Single Aromatic Substrate
  作者:Heinrich,Annika C. J.; Et Al
  参考文献:Organic Letters 日期:2013 卷标:15(18) 页码:4666-4669]
  
  1066-45-1 + 2246560-20-1 + 1160823-78-8 = 86134-26-1
  反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C; 2 H,-78 °C1.2 -78 °C -> Rt; Overnight,Rt
  标题:Dicyanodistyrylbenzene-Based Copolymers For Ambipolar Organic Field-Effect Transistors With Well-Balanced Hole And Electron Mobilities
  作者:Ryu,Hwa Sook; Et Al
  参考文献:Macromolecules (Washington 日期:2018 卷标:51(20) 页码:8258-8267]
  
  = 86134-26-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Acetic Acid; 8 H,Reflux2.1 Reagents: Butyllithium,N,N,N′,N′-Tetramethylethylenediamine Solvents: Tetrahydrofuran,Hexane; 1 H,Rt -> -78 °C; 2 H,-78 °C -> 0 °C; -78 °C2.2 Solvents: Tetrahydrofuran; 4 H,Rt
  标题:Electrochromic Properties Of Pyrene Conductive Polymers Modified By Chemical Polymerization
  作者:Li,Rui; Et Al
  参考文献:Rsc Advances 日期:2021 卷标:11(62) 页码:39291-39305]
  
  = 86134-26-1
  反应条件:1.1 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide; 20 H,Rt2.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 20 Min,-78 °C; 1 H,-78 °C2.2 Overnight,-78 °C -> Rt2.3 Solvents: Water; Rt
  标题:Solution-Processable Bodipy-Based Small Molecules For Semiconducting Microfibers In Organic Thin-Film Transistors
  作者:Ozdemir,Mehmet; Et Al
  参考文献:Acs Applied Materials & Interfaces 日期:2016 卷标:8(22) 页码:14077-14087]
  
  71637-37-1 + 2136615-87-5 = 86134-26-1
  反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Tert-Butanol; Rt; 1 H,50 °C2.1 Catalysts: Tri-O-Tolylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 10 Min,80 °C; 10 Min,100 °C; 30 Min,120 °C; 50 Min,140 °C2.2 Reagents: 2-(Tributylstannyl)Thiophene; 10 Min,100 °C; 20 Min,140 °C2.3 Reagents: 2-Bromothiophene; 10 Min,100 °C; 20 Min,140 °C3.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; -78 °C; 2 H,-78 °C3.2 -78 °C -> Rt; Overnight,Rt
  标题:Dicyanodistyrylbenzene-Based Copolymers For Ambipolar Organic Field-Effect Transistors With Well-Balanced Hole And Electron Mobilities
  作者:Ryu,Hwa Sook; Et Al
  参考文献:Macromolecules (Washington 日期:2018 卷标:51(20) 页码:8258-8267]
  
  86134-26-1 + 15155-41-6 = 86134-26-1 + 15155-41-6
  反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium
  标题:Low Band Gap Polymers For Organic Solar Cells
  作者:Bundgaard,Eva; Et Al
  参考文献:Proceedings Of Spie-The International Society For Optical Engineering 日期:2006 卷标:6334]
  
  86134-26-1 + 288071-87-4 = 86134-26-1 + 288071-87-4
  反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium
  标题:Low Band Gap Polymers For Organic Solar Cells
  作者:Bundgaard,Eva; Et Al
  参考文献:Proceedings Of Spie-The International Society For Optical Engineering 日期:2006 卷标:6334

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管