专利号:US-4284582-A 优先权日:1978-04-28 标 题 :Process for the preparation of cyclopropane derivatives, intermediates in the synthesis of pyrethroid insecticides 发明人:KAYE ALBERT E; TUCKER ALAN C 权利人:ICI LTD 摘要:Compounds of formula: wherein both groups X are chlorine, bromine or trifluoromethyl, or one X is chlorine or bromine and the other is trifluoromethyl, and Y is -CN or -COOR in which R is an alkyl group, are obtained by (A) reacting a compound of the formula: wherein X1 is chlorine or bromine, with a compound of the formula: X2C=CH-CH=C(CH3)2 in the presence of metallic copper or at least one copper salt and a base, or (B) reacting a compound of the formula: Y-CH2-CN with a compound of the formula: X2C=CH-CH=C(CH3)2 and chlorine or bromine, in the presence of at least one reducible copper salt and a base, or (C) reacting a compound of formula: X-CH2-CN with a compound of the formula: wherein X1 is chlorine or bromine, in the presence of at least one copper salt. The compounds are intermediates in the synthesis of pyrethroid insecticides.
专利号:US-9272971-B2 优先权日:2012-02-28 标题 :Catalyst for C2 oxygenate synthesis, device for manufacturing C2 oxygenate, and method for manufacturing C2 oxygenate 发明人:NISHINO TOMOAKI; MIYAMA TOSHIHITO; MURATA KAZUHISA; LIU YANYONG 权利人:SEKISUI CHEMICAL CO LTD; NAT INST OF ADVANCED IND SCIEN 摘要:The present invention relates to a catalyst for C2 oxygenate synthesis in which a hydrogenated active metal is supported on a porous carrier to synthesize a C2 oxygenate from a mixed gas containing hydrogen and carbon monoxide, wherein the porous carrier has an average pore diameter of 0.1 to 20 nm.
专利号:US-2024097109-A1 优先权日:2021-02-11 标 题:Bottom-Up, Scalable Synthesis Of Oxide-Based Sub-Nano And Nanofilaments And Nanofilament-Based Two-Dimensional Flakes And Mesoporous Powders 发明人:BARSOUM MICHEL W; BADR HUSSEIN OSAMA 权利人:UNIV DREXEL 摘要:Provided are methods to convert—through a bottom-up approach—binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into lepidocrocitic nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can comprise nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances.
专利号:WO-2013129614-A1 优先权日:2012-02-28 标 题 :Catalyst for synthesis of c2 oxygenate, apparatus for producing c2 oxygenate, and method for producing c2 oxygenate
专利号:EP-2821136-A1 优先权日:2012-02-28 标 题 :Catalyst for synthesis of c2 oxygenate, apparatus for producing c2 oxygenate, and method for producing c2 oxygenate
专利号:EP-2821136-B1 优先权日:2012-02-28 标题 :Catalyst for synthesis of c2 oxygenate, apparatus for producing c2 oxygenate, and method for producing c2 oxygenate
参考文献:10.1007/978-981-15-2373-1_3 摘要:Kamali AR. Interaction of Molten Salts with Graphite. 2020. In: Green Production of Carbon Nanomaterials in Molten Salts and Applications. 参考文献:10.1007/s40831-023-00707-z 摘要:Tian Y, Xie J, Zhang F, Xu L, Zhao Z. Synthesis and Lithium Adsorption Performance of NiFe2O4@AlLi-LDH. J. Sustain. Metall. 2023 Jul 06;9(3):1075–83. doi: 10.1007/s40831-023-00707-z. 参考文献:10.1007/s40831-023-00729-7 摘要:Heo J, Jones PT, Blanpain B, Guo M. Chlorination Roasting of Li-Bearing Minerals and Slags: Combined Evaluation of Lithium Recovery Ratio and Lithium Chloride Product Purity. J. Sustain. Metall. 2023 Aug 24;9(3):1353–62. doi: 10.1007/s40831-023-00729-7. 参考文献:10.1007/s10570-024-05969-8 摘要:Du H, Cheng Z, Liu Y, Hu M, Xia M, Sun X, Lin Z, Liu H. Polydopamine-modified cellulose nanofiber composite hydrogel with strong toughness and high adhesion for human motion detection and wireless sensing. Cellulose. 2024 May 31;31(10):6421–33. doi: 10.1007/s10570-024-05969-8. 参考文献:10.1007/s10570-024-05970-1 摘要:Tsague FL, Chimeni DY, Assonfack HL, Abo MT, Cheumani AMY, Ndinteh DT, Ndikontar MK. Study of oxidation of cellulose by Fenton-type reactions using alkali metal salts as swelling agents. Cellulose. 2024 Jun 24;31(11):6643–61. doi: 10.1007/s10570-024-05970-1.