CAS: 2380-91-8; 4-(1-Hydroxyethyl)Phenol

上下游产品

4-Hydroxyacetophenone methyl magnesium iodide 4-hydroxy-benzaldehyde ethanol 1-acetoxy-4-(1-acetoxy-ethyl)-benzene 4-Ethyliden-2,5-cyclohexadienon (S)-(-)-1-(4'-hydroxyphenyl)ethanol (R)-(-)-1-(4'-hydroxyphenyl)ethanol

对羟基苯乙酮置于[rh(1-Cyclooctene)Cl(η2-(2-(Diphenylphosphino)Pyridine))],Potassium Hydroxide体系中,用 异丙醇 用作溶剂,化学反应 4.0H,以91%的收率获得1-(4-羟基苯)乙醇
参考文献:含p-n供体配体的铑(i)配合物的合成,表征及其在羰基转移加氢中的催化应用
标题:含p-n供体配体的铑(i)配合物的合成,表征及其在羰基转移加氢中的催化应用
摘要:类型的三氯化铑(i)配合物的[rh(coe)氯(η 2-L)](1A,1B)和[的rhcl(η 2-L)(η 1-L)](1C),其中l = P〜n供体配体2-[2-(二苯基膦基)乙基]吡啶,(pph 2 Etpy)(a),2-(二苯基膦基)吡啶(pph 2 Py)(b)和3-(二苯基膦基)-1-丙胺(pph 2(ch 2)3 Nh 2)(c)是通过[rh(coe)2 Cl] 2与各自的配体以1:2摩尔比反应1A,1B合成的回流条件下,Dcm中1C的摩尔比为1:4 .使用不同的分析技术(例如ft-Ir,Esi(+)质谱,1 H和31 P { 1 H} NMR光谱,电导率测量和熔点测定)对复合物进行表征.发现合成的配合物显示出非常好的催化活性,以高转化率将羰基化合物转移氢化成相应的醇.
Doi:10.1002/bkcs.10237

专利信息

专利号:US-2023151394-A1
优先权日:2020-03-31
标题 :Biologic synthesis of diols from amino acids
发明人：ZENG AN-PING; LIU YONGFEI
权利人:TAIZHOU SIMPLU TECH CO LTD
摘要:A method for the enzymatically catalyzed synthesis of a diol from an amino acid includes enzymatically hydroxylating the amino acid, enzymatically deaminating the amino acid, the deamination resulting in the formation of an oxo group at the position of the amino group, enzymatically decarboxylating the amino acid, and enzymatically hydrogenating the oxo group resulting from the deamination reaction.

专利号:WO-2025031833-A1
优先权日:2023-08-04
标 题:Recombinant strain and use thereof in production of scoulerine
发明人：CHEN YUN; JIAO XIANG
权利人:CHRYSEA LTD; CHEN YUN
摘要:Disclosed are recombinant yeast strains and a use thereof in the production of a benzylisoquinoline alkaloid. The recombinant yeast strains comprise berberine bridge enzyme. De novo synthesis of scoulerine and a benzylisoquinoline alkaloid is achieved through multiple strategies, and the yield thereof is significantly increased. The recombinant yeast strains provided by the present invention can produce scoulerine and other benzylisoquinoline alkaloids at high efficiency, and has important value in applications.

专利号:US-6114489-A
优先权日:1997-03-27
标 题 :Reactive hyperbranched polymers for powder coatings
发明人：VICARI RICHARD; FRUCHEY OLAN STANLEY; JUNEAU KATHLEEN NELSON; THAMES SHELBY FRELAND; RAWLINS JAMES WAYNE
权利人:HERBERTS GMBH
摘要:Novel powder coating compositions containing reactive hyperbranched polymers are disclosed and claimed. Preferred embodiments include powder coating compositions formed from hyperbranched polyesters having terminal hydroxy, carboxy, epoxy, and isocyanate groups. Preferred hyperbranched polyesters are formed from alpha , alpha -bis-(hydroxymethyl)-propionic acid, which act either as crosslinkers, adhesion promotors, or flow and leveling agents. A process for the synthesis of powder coating compositions is also disclosed which involves (a) self condensation of one or more of the multifunctional monomers to form the hyperbranched polymer, optionally, in the presence of suitable reactive end-capping moieties which are described herein; (b) melt blending of the hyperbranched polymer with suitable amounts of one or more of polyesters, epoxy resins, blocked urethane resins, or acrylic resins, a crosslinker, and one or more of suitable additional ingredients including degassers or flow and leveling agents, to form a flake; and (c) grinding and sieving of the flake to form the powder coating composition. These compositions exhibit improved flow and curing properties. These compositions can therefore be formed into thin films and can be cured at low temperatures to form smooth surfaces. Additionally, these films are hard and exhibit enhanced impact resistance properties than the conventional polyester resins. Thus, these powder coating compositions find utilities in automotive, packaging, and appliances.

专利号:CN-109674039-B
优先权日:2018-11-23
标题:Method and Application of Biotransformation Synthesis of Salidroside and Icariside D2

专利号:CN-1651379-A
优先权日:2004-12-03
标 题 :A new process for the synthesis of 4-[2-(cyclopropylmethoxy)ethyl]phenol

专利号:CN-109422783-A
优先权日:2017-08-28
标 题:A kind of method for chemical synthesis of salidroside