专利号:US-8563763-B2 优先权日:2011-04-05 标 题 :Composition, synthesis and use of isonitriles 发明人:FLEMING FRASER FERGUSON; PITTA BHASKAR REDDY 权利人:FLEMING FRASER FERGUSON; PITTA BHASKAR REDDY; UNIV HOLY GHOST DUQUESNE 摘要:The present invention relates to isonitrile compounds, methods of synthesis, and uses in a variety of fields. In one aspect, the present invention includes sulfinyl methyl isonitriles and methods for their preparation. In another aspect, the present invention includes the use of sulfinyl methyl isonitriles to prepare various other isonitrile compounds and derivatives thereof. In yet another aspect, the present invention includes a relatively simple and routine synthesis of sulfinyl methyl isonitrile compounds, other isonitrile compounds and derivatives thereof.
专利号:US-9035058-B2 优先权日:2011-10-12 标题:Synthesis of MSE-framework type molecular sieves 发明人:WESTON SIMON C; STROHMAIER KARL G; VROMAN HILDA B 权利人:WESTON SIMON C; STROHMAIER KARL G; VROMAN HILDA B; EXXONMOBIL RES & ENG CO 摘要:A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1-yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1′-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1′-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1′-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).
专利号:US-2015158020-A1 优先权日:2013-12-11 标题:Synthesis of zeolites using an organoammonium compound 发明人:NICHOLAS CHRISTOPHER P; MILLER MARK A 权利人:UOP LLC 摘要:A method for synthesizing a zeolite includes the steps of: (a) preparing an aqueous mixture comprising water, a substituted hydrocarbon and an amine; (b) reacting the aqueous mixture; (c) obtaining a solution comprising an organoammonium product; (d) forming a reaction mixture including reactive sources of M, Al, Si, optionally seeds of a layered material L, and the solution, wherein M is a metal; and (e) heating the reaction mixture to form the zeolite. The substituted hydrocarbon can be an α,ω-dihalogen substituted alkane, and the amine is preferably essentially incapable of undergoing pyramidal inversion.
专利号:US-9522896-B2 优先权日:2014-12-04 标题 :Organo-1-oxa-4-azonium cyclohexane compounds 发明人:NICHOLAS CHRISTOPHER P; MILLER MARK A; GALEY MELISSA M; YUHAS BENJAMIN D; PRABHAKAR SESH 权利人:UOP LLC 摘要:Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.
专利号:US-10633355-B2 优先权日:2014-12-04 标题:Organo-1-oxa-4-azonium cyclohexane compounds 发明人:NICHOLAS CHRISTOPHER P; MILLER MARK A; GALEY MELISSA M; YUHAS BENJAMIN D; PRABHAKAR SESH 权利人:UOP LLC 摘要:Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.
专利号:US-10654817-B2 优先权日:2014-12-04 标题 :Organo-1-oxa-4-azonium cyclohexane compounds 发明人:NICHOLAS CHRISTOPHER P; MILLER MARK A; GALEY MELISSA M; YUHAS BENJAMIN D; PRABHAKAR SESH 权利人:UOP LLC 摘要:Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.
参考标题:An Efficient And Simple Aqueous N-Heterocyclization Of Aniline Derivatives: Microwave-Assisted Synthesis Of N-Aryl Azacycloalkanes 作者:Yuhong Ju,Rajender S. Varma |发布日期:2005.6.1 摘要:[reaction: See Text] An Efficient And Clean Synthesis Of N-Aryl Azacycloalkanes From Alkyl Dihalides And Aniline Derivatives Has Been Achieved Using Microwave Irradiation In An Aqueous Potassium Carbonate Medium. The Phase Separation Can Simplify The Product Isolation And Reduce Usage Of Volatile Organic Solvents.
合成参考文献
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