CAS: 2698-41-1; Chlorobenzylidene Malononitrile

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CAS号89-98-5 邻氯苯甲醛 | CAS号109-77-3 丙二腈 | CAS号98-86-2 苯乙酮 | CAS号118-91-2 邻氯苯甲酸 | CAS号17849-38-6 2-氯苄醇 | CAS号111861-47-3 3-amino-1-(2-ch... | CAS号141996-40-9 2-[(2-chlorophe... | CAS号28989-25-5 3-氯-5-(2-氯苯基)异噻... | CAS号23773-23-1 1,1,2,2-Cyclopr... | CAS号3533-10-6 3-(2-chlorophen... | CAS号3513-09-5 3-(2-chlorophen... | CAS号3513-08-4 3-(2-chlorophen... | CAS号347890-46-4 tert-butyl n-(5... | CAS号40915-55-7 2-[(2-chlorophe...

邻氯苄醇置于碘苯二乙酸体系中,用 乙腈 用作溶剂,化学反应 4.17H,反应生成2-氯苯亚甲基丙二腈
参考文献:一锅顺序反应在中孔碳中金属有机笼的约束自组装
标题:一锅顺序反应在中孔碳中金属有机笼的约束自组装
摘要:在超分子催化领域中已经广泛探索了定义明确的离散金属有机笼.但是,这些金属有机笼子很少被用作一锅反应的多相催化剂.在这里,我们介绍了氨基官能化介孔碳内含(2,2,6,6-四甲基哌啶-1-基)氧基(tempo)的金属有机笼的首次成功的封闭自组装,以实现一个新的双官能团非均相催化剂(cage @ Fdu-Ed)进行一锅反应.所获得的双功能催化剂中分离的催化活性位点的正交特征导致增强的催化活性,选择性和可回收性,总转化率可达到96%.这些结果表明,通过精心设计分离的金属有机笼和中孔基质中的催化位点,可以实现连续高效的化学转化.这项研究为金属有机笼子铺平了道路,将其作为异质顺序反应的有前途的平台.
Doi:10.1016/j.Chempr.2020.06.038

专利信息

专利号:US-3963770-A
优先权日:1972-09-27
标 题:Synthesis of ortho-chlorobenzalmalononitrile
发明人：KNAPP JOHN S
权利人:FEDERAL LAB INC
摘要:Disclosed herein is a synthesis of ortho chlorobenzalmalononitrile by reacting malononitrile with ortho-chloro benzaldehyde in methanol in the presence of a basic catalyst; separating the product crystals from the methanol; washing the crystals with fresh methanol; combining the wash methanol with the methanol filtrate and using the combined methanol in another similar synthesis run and repeating a series of such runs; drying the crystals with a current of turbulent dry air and scrubbing the air with base solution thereby substantially reducing associated problems of effluent treatment and ambient air pollution.

专利号:CN-102924202-A
优先权日:2012-11-15
标题:Solvent-free and heat-free synthesis of benzylidene malononitrile and its derivatives

专利号:US-4223031-A
优先权日:1978-05-05
标题 :Azolopyrimidinones
发明人：COVINGTON ROBERT R; TEMPLE JR DAVIS L; YEVICH JOSEPH P
权利人:MEAD JOHNSON & CO
摘要:6-(1H-Tetrazol-5-yl)thiozolo[3,2-a]pyrimidin-5-ones, 3-(1H-tetrazol-5-yl)-4H-pyrimido[2,1-b]benzothiazol-4-ones, and the corresponding imidazo- and triazolo-pyrimidines, thiones, and imines are useful as antiallergy and antiasthmatic compounds by virtue of their inhibitory action on the immediate hypersensitivity reaction in mammals and relaxant action on the tracheal muscle. Intermediates in the synthesis of these substances from 2-aminoazoles and ethoxy-methylene malononitrile also have smooth muscle relaxant and immediate hypersensitivity reaction inhibitory activity.

专利号:CN-105061385-A
优先权日:2015-08-11
标 题 :A method for the catalytic synthesis of 4H-benzo[b]pyran derivatives by alkaline ionic liquid

专利号:CN-103880708-B
优先权日:2014-04-10
标 题 :A kind of improvement process for catalytic synthesis of propane dinitrile

专利号:CN-101130506-A
优先权日:2006-08-23
标题:Synthesis method of image agent used for diagnosis of progeria dementia