CAS: 298-07-7; Bis(2-Ethylhexyl) Phosphate

上下游产品

CAS号78-42-2 磷酸三辛酯 | CAS号104-76-7 2-乙基己醇 | CAS号3658-48-8 双(2-乙基己基)磷酸 | CAS号63449-80-9 3-[[chloro(2-et... | CAS号685498-13-9 di-2-ethylhexyl... | CAS号1369964-84-0 (1,1-dioxido-4-... | CAS号141-65-1 磷酸双(2-乙基己基)酯钠盐 | CAS号13340-46-0 triethoxy(2-phe...

2-乙基己醇置于oxone||potassium Monopersulfate Triple Salt,Phosphorus,水,Silica Gel,Potassium Bromide体系中,用 二氯甲烷,甲苯 用作溶剂,化学反应 48.0H,以73%的收率获得二(2-乙基己基)磷酸酯
参考文献:白磷直接合成亚磷酸二烷基酯
标题:白磷直接合成亚磷酸二烷基酯
摘要:亚磷酸二烷基酯 (Dapi) 传统上由危险和腐蚀性 Pcl 3制备,是有机磷化学中使用的基本反应性起始材料.在这里,介绍了 Kbr 介导的 Dapi 合成,涉及 P 4,醇和水.以硅胶为催化剂,过氧化氢作为安全氧化剂,工业上重要的(Eto) 2 P(O)H,(I-Pro) 2 P(O)H和(Meo) 2 P(O)H是以 70-90% 的收率制备.此外,稀有金属萃取剂双(2-乙基己基)磷酸酯(d2Ehpa)的收率为73%.该反应的特点是白磷完全转化.此外,这种方法可以很容易地适应大规模制备.
Doi:10.1002/adsc.202200560

专利信息

专利号:US-6184168-B1
优先权日:1997-09-22
标题:Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
发明人：LYNCH THOMAS J
权利人:BRIDGESTONE CORP
摘要:The invention provides a catalyst composition, comprising: (a) an organolithium compound; and, (b) an organic acid salt of lanthanide series element; wherein: (1) only components (a) and (b) are required to promote the synthesis of 1,4-trans-polybutadiene; (2) the ratio of component (a) to component (b) is selected to maximize formation of the trans structure of said 1,4-trans-polybutadiene; and, (3) components (a) and (b) are selected for enabling further diblock synthesis. The invention further contemplates a process for using the catalyst to synthesize 1,4-trans-polybutadiene and other polymers and copolymers having trans configuration in the conjugated diene monomer contributed units.

专利号:US-9809661-B2
优先权日:2012-07-02
标 题 :Process for continuous synthesis of a diene elastomer
发明人：DUSSILLOLS JEROME; KIENER PIERRE; PAROLA HELENE
权利人:MICHELIN & CIE; MICHELIN RECH TECH; MICHELIN RECH TECH
摘要:A process for the continuous synthesis of diene elastomers with a high degree of conversion is provided. The process includes simultaneously:n a) introducing continuously into a polymerization reactor containing a gas phase and equipped with at least one stirring rotor and a discharge device, at least i. one or more monomers, including at least one conjugated diene monomer, and ii. from 0% to 70% by mass of an organic solvent, calculated relative to the total mass of monomers and of solvent b) continuously polymerizing the monomer(s), c) stirring the polymerization medium via the continuous movement of at least one stirring rotor about a rotary axle, d) continuously discharging the elastomer paste, e) continuously conveying the discharged elastomer paste to a chopping device and chopping it into particles, f) removing solvent from the particles of the elastomer paste, and g) recovering diene elastomer.

专利号:US-8519184-B2
优先权日:2010-07-05
标 题:Synthesis of rare earth metal extractant
发明人：SAKAKI KAZUAKI; SUGAHARA HIROTO; OHASHI TETSUYA; KUME TETSUYA; IKKA MASAHIKO; NAGANAWA HIROCHIKA; SHIMOJO KOJIRO
权利人:SAKAKI KAZUAKI; SUGAHARA HIROTO; OHASHI TETSUYA; KUME TETSUYA; IKKA MASAHIKO; NAGANAWA HIROCHIKA; SHIMOJO KOJIRO; SHINETSU CHEMICAL CO; NISSIN CHEMICAL IND
摘要:A rare earth metal extractant in the form of a dialkyl diglycol amic acid is synthesized by reacting diglycolic anhydride with a dialkylamine in a synthesis medium. A molar ratio (B/A) of dialkylamine (B) to diglycolic anhydride (A) is at least 1.0. A non-polar or low-polar solvent in which the dialkyl diglycol amic acid is dissolvable is used as the synthesis medium.

专利号:US-8933181-B2
优先权日:2006-10-06
标题:Branched polymers and methods for their synthesis and use
发明人：MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

专利号:US-7312251-B2
优先权日:1999-04-26
标题 :Synthesis of stable solutions of rare earth tris (organophosphate) in hydrocarbon solvents
发明人：YUNLU KENAN; HE MIN
权利人:RHODIA RARE EARTHS INC
摘要:Stable rare earth tris (organophosphate) solutions comprise a rare earth tris (organophosphate) and a hydrocarbon solvent. From about 2% to about 10% rare earth element, preferably from about 3% to about 8%, is present in the solutions. The rare earth tris (organophosphate) solutions are stable from precipitation of the rare earth tris (organophosphate) for at least about fifteen (15) days, preferably for at least about twenty (20) days and most preferably at least about thirty (30) days. A process for preparing these solutions is described herein. A stabilizing additive, acid, glycol or mixtures thereof, is utilized to inhibit precipitation. The molar ratios of free acid, glycol and/or water to the rare earth element are controlled to inhibit precipitation.

专利号:US-8410254-B2
优先权日:2007-12-20
标 题:Method for the synthesis of a rare-earth organophosphate and use thereof for preparing a preformed catalytic system
发明人：THUILLIEZ JULIEN
权利人:THUILLIEZ JULIEN; MICHELIN RECH TECH; MICHELIN & CIE
摘要:A process for preparing a rare-earth organophosphate in the form of a gel that can be used as is for the preparation of a “preformedâ€? catalyst system intended, in particular, for the cis-1,4 stereospecific polymerization of conjugated dienes.