CAS: 4774-15-6; 2,6-Dimethoxypyrazine

相似化合物

3149-28-8 68468-30-4 38028-67-0

上下游产品

2,6-dibromopyrazine sodium methylate 2,6-dichloropyrazine (2,6-dimethoxy-3-pyrazinyl)phenylmethanone (2,6-dimethoxy-3-pyrazinyl)-2'-methoxyphenyl methanol 2,6-dimethoxy-3-pyrazinecarboxaldehyde (3R,4R,5R)-3,4-Bis-benzyloxy-5-benzyloxymethyl-2-(3,5-dimethoxy-pyrazin-2-yl)-tetrahydro-furan-2-ol

2,6-二氯吡嗪,Sodium Methylate 以 甲醇 作为反应溶剂,化学反应 3.0H,以97%的收率获得产物2,6-二甲氧基吡嗪
参考文献:H2O2 /过氧钨酸盐体系合成llm-105的绿色氧化过程及其理论研究
标题:H2O2 /过氧钨酸盐体系合成llm-105的绿色氧化过程及其理论研究
摘要:开发了一种新的催化体系,并应用于llm-105合成的氧化反应,其中质子化过硫钨酸盐结合壳聚糖用作催化剂.使用H2O 2作为氧化剂,可以合成吡嗪-1-氧化物,2,6-二甲氧基吡嗪-1-氧化物,2,6-二氯吡嗪-1-氧化物和2-氯吡咯.不添加三氟乙酸的6-甲氧基吡嗪-1-氧化物,为llm-105的新颖且对环境无害的合成路线提供了重要的探索.还使用高斯03进行了理论研究,以评估氧化过程.所有的计算数据与我们的实验结果非常吻合.
DOI:10.1002/jhet.2044

专利信息

专利号:US-2025034146-A1
优先权日:2023-07-13
标题:Electro-photochemical synthesis of 1,2,4-triazolo-[4,3-a]pyrazine
发明人：PIERCEY DAVIN GLENN; YOUNT JOSEPH ROBERT
权利人:PURDUE RESEARCH FOUNDATION
摘要:A method of preparing a 1,2,4-triazolo-[4,3-a]pyrazine backbone using an electro-photochemical process comprising coupling a compound comprising a 5-substituted tetrazole moiety to a compound comprising an optionally substituted pyrazine moiety electrochemically and subjecting the resulting compound to photochemical excitation with ultraviolet light.

专利号:US-9458115-B2
优先权日:2009-04-20
标 题 :Synthesis of substituted pyrazines
发明人：PAGORIA PHILIP F; ZHANG MAO XI
权利人:PAGORIA PHILIP F; ZHANG MAO XI; L LIVERMORE NAT SECURITY LLC
摘要:A method for synthesizing a pyrazine-containing material according to one embodiment includes contacting an iminodiacetonitrile derivative with a base and a reagent selected from a group consisting of hydroxylamine, a hydroxylamine salt, an aliphatic primary amine, a secondary amine, an aryl-substituted alkylamine a heteroaryl-substituted alkyl amine, an alcohol, an alkanolamine and an aryl alcoholamine. Additional methods and several reaction products are presented.

专利号:US-10836731-B2
优先权日:2017-02-28
标 题 :Precipitation method and synthesis method of 2,6-diamino-3,5-dinitropyrazine-1-oxide
发明人：PASQUINET ERIC; WUILLAUME ANNE; PIN NICOLAS; BEAUCAMP ARNAUD; BARTHET CHRISTELLE
权利人:COMMISSARIAT ENERGIE ATOMIQUE
摘要:A method for precipitating as particles 2,6-diamino-3,5-dinitropyrazine-1-oxide (or ANPZO) present in an acid medium, which comprises adding the acid medium to an aqueous solution and which is characterized in that the aqueous solution comprises a nitrate salt. Further disclosed is a method for synthesizing ANPZO implementing this precipitation method. The synthesis method comprises converting 2,6-diaminopyrazine-1-oxide (or DAPO) into ANPZO by nitration in an acid medium, and then precipitating as particles the ANPZO by adding the acid medium to an aqueous solution, and is characterized in that the aqueous solution comprises a nitrate salt.

专利号:WO-2010123806-A1
优先权日:2009-04-20
标 题:Synthesis of pyrazines including 2,6-diaminopyrazine-1-oxide (dapo) and 2,6-diamino-3,5-dinitropyrazine-1-oxide (llm-105)

专利号:FR-3063291-A1
优先权日:2017-02-28
标题 :PRECIPITATION METHOD AND PROCESS FOR THE SYNTHESIS OF 2,6-DIAMINO-3,5-DINITROPYRAZINE-1-OXIDE

专利号:US-2010267955-A1
优先权日:2009-04-20
标题 :Synthesis of pyrazines including 2,6-diaminopyrazine-1-oxide (dapo) and 2,6-diamino-3,5-dinitropyrazine-1-oxide (llm-105)