CAS: 20548-54-3; Calcium Sulfide

该化合物是一种无机化合物,其特点是由钙和硫形成,一般是白色至黄色的固体,以水中高熔点和溶解度闻名,可形成氢氧化钙和硫化氢溶液,硫化钙主要用于生产磷,制造某些种类的玻璃和作为各种化学过程的消毒剂,它显示出发光性,特别是与其他元素结合时的发光性,使其在照明应用中具有价值.此外,CaS可使用酸来释放硫化氢气体,这种气体具有腐烂的蛋味和毒性,在处理这种化合物时,由于它的潜在危害,必须采取安全防范措施.

结构式图片

欧盟法规

统一分类与标签ECHA物质ECHA物质工作场所安全标识要求C&L通报REACH预注册废弃物危险特性清单

合成工艺路线路线简述

    Calcium Sulfate 反应生成硫化钙
    参考文献:Rao,M. S. R.;Rao,D. R.,Bull. Electrochem.,5,(1989) N,C. 125-128
    标题:Rao,M. S. R.;Rao,D. R.,Bull. Electrochem.,5,(1989) N,C. 125-128

    专利信息


    专利号:US-8945494-B1
    优先权日:2013-05-24
    标题 :Synthesis of calcium sulfide (CaS) nanoparticles
    发明人:CASTRO MIGUEL E; RIVERA DANIEL
    权利人:CASTRO MIGUEL E; RIVERA DANIEL; UNIV PUERTO RICO
    摘要:The invention provides a simple an efficient method for the synthesis of CaS nanoparticles, where a solution of CaAc in DMSO is warmed in a microwave oven.

    专利号:US-7335320-B2
    优先权日:2001-03-06
    标题 :Method for the production of hydrogen-containing gaseous mixtures
    发明人:KINDIG JAMES KELLY; WEYAND THOMAS E
    权利人:ALCHEMIX CORP
    摘要:A method for the production of a hydrogen-containing gas composition, such as a synthesis gas including hydrogen and carbon monoxide. The molar ratio of hydrogen to carbon monoxide (H 2 :CO) in the synthesis gas can be well-controlled to yield a ratio that is adequate for the synthesis of useful products such as methane or methanol, without the need to remove carbon oxides from the gas stream to adjust the ratio.

    专利号:WO-9912939-A1
    优先权日:1997-09-12
    标题 :Lanthanide chalcogenolates and lanthanide doped chalcogenide matrices and their room temperature synthesis
    发明人:BRENNAN JOHN G
    权利人:UNIV RUTGERS; BRENNAN JOHN G
    摘要:New lanthanide chalcogenolates and lanthanide doped chalcogenide matrices are described for use as photon emitters and amplifiers for fiber optic materials. In particular, metal organic precursors for such compositions of the formula: (L)pM-(ER)n are provided. In addition, low temperature procedures for the synthesis of such compositions are also provided.

    专利号:US-2024010511-A1
    优先权日:2019-05-02
    标 题 :Methods and compositions for synthesis of phosphor and its incorporation in a polymer matrix for light conversion
    发明人:SAHI SUNIL
    权利人:SOLGO INC; SOLGRO INC
    摘要:The invention relates to methods and compositions for synthesizing a phosphor and preparing a surface-modified phosphor comprising a phosphor, a silica, and a silane, and articles comprising same. The invention also relates to a method of dispersion of the disclosed surface-modified phosphor with a blue emitting agent in a polymer matrix and uses thereof.

    专利号:US-7902383-B2
    优先权日:2006-05-29
    标 题 :Production method of heterocyclic mercapto compound
    发明人:YOROZUYA SHINICHI; AOKI HIDEMASA
    权利人:SHOWA DENKO KK
    摘要:A method of the invention industrially produces heterocyclic mercapto compounds useful as raw materials or intermediates in the synthesis of medicaments or pesticides, or as permanent wave agent, with a high yield and high productivity using easily available starting materials. A heterocyclic mercapto compound represented by Formula (1) (wherein X represents any structure of —O—, —S—, —NH—, and —NR 1 —; R 1 represents any of an alkyl group, alkoxy group and alkoxyalkyl group each having 1 to 6 carbon atoms; Y represents an oxygen atom, a sulfur atom or —NR 2 —; R 2 represents a hydrogen atom or alkyl group having 1 to 6 carbon atoms; and Z 1 represents a divalent organic residue having at least one mercapto group) is produced by reacting a metal sulfide or a metal hydrosulfide with a compound represented by Formula (2) (wherein X and Y are as defined in Formula (1); and Z 2 represents a divalent organic residue having at least one halogen group) in the presence of a solvent at a pH of 7.0 to 11.0.

    专利号:US-9163179-B2
    优先权日:2011-12-21
    标题 :System and method for production of Fischer-Tropsch synthesis products and power
    发明人:MCCOMISH BRUCE E; CARRYER BENJAMIN H; BORUM BRYAN C; JIANG WEIBIN; IBSEN MARK D; ROBERTSON MARK K; ELROD ERIC R; WEEKS SIM; WRIGHT HAROLD A
    权利人:MCCOMISH BRUCE E; CARRYER BENJAMIN H; BORUM BRYAN C; JIANG WEIBIN; IBSEN MARK D; ROBERTSON MARK K; ELROD ERIC R; WEEKS SIM; WRIGHT HAROLD A; RES USA LLC
    摘要:A method for generation of power and Fischer-Tropsch synthesis products by producing synthesis gas comprising hydrogen and carbon monoxide, producing Fischer-Tropsch synthesis products and Fischer-Tropsch tailgas from a first portion of the synthesis gas, and generating power from a second portion of the synthesis gas, from at least a portion of the Fischer-Tropsch tailgas, or from both. The method may also comprise conditioning at least a portion of the synthesis gas and/or upgrading at least a portion of the Fischer-Tropsch synthesis products. A system for carrying out the method is also provided.
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    主要参考文献

    [参考文献]: Alberto Soto, Et Al. Alternative Control Of Tetranychus Evansi Baker & Pritchard (Acari: Tetranychidae) On Tomato Plants Grown In Greenhouses. Neotrop Entomol. 2010 Jul-Aug;39(4):638-44.
    [参考文献]: Alison Diesel, Et Al. Efficacy Of Eight Commercial Formulations Of Lime Sulphur On In Vitro Growth Inhibition Of Microsporum Canis. Vet Dermatol. 2011 Apr;22(2):197-201.
    [参考文献]: Eleanor Bott, Et Al. Suicide By Hydrogen Sulfide Inhalation. Am J Forensic Med Pathol. 2013 Mar;34(1):23-5.
    [参考文献]: Elizabeth H Beers, Et Al. Lethal, Sublethal, And Behavioral Effects Of Sulfur-Containing Products In Bioassays Of Three Species Of Orchard Mites. J Econ Entomol. 2009 Feb;102(1):324-35.
    [参考文献]: J N Zvimba, Et Al. The Dissolution Characteristics Of Calcium Sulfide And Utilization As A Precipitation Agent In Acidic Wastewater Effluent Treatment. Water Sci Technol. 2011;63(12):2860-6.

    合成参考文献


    摘要:S13 | EUCOSMETICS | Combined Inventory of Ingredients Employed in Cosmetic Products (2000) and Revised Inventory (2006) | DOI:10.5281/zenodo.2624118
    摘要:Schafer, E. W., Jr., W. A. Bowles Jr., and J. Hurlbut. 1983. The acute oral toxicity and repellency and hazard potential of 998 chemicals to one or more species of wild and domestic birds. Archives of Environmental Contamination and Toxicology 12:355-382. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/Q_schafer832.pdf
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