CAS: 10361-43-0; Bismuth Hydroxide

该化合物是一种无机化合物,通常用于分析化学,催化和制药,是一种白色或青柳固体,在水中溶解,但酸中溶解,形成二甲硫盐,该化合物具有极好的吸附特性,有助于重金属的清除和废水处理,其热稳定性和低毒性在需要安全处理和环境合规的应用中是有利的. 氢氧化乙二氧还作为在受控制条件下合成其他双硫化合物(如二甲二氧)的前体,因为它在受控条件下具有再活动性,在工业和实验室环境中的多用途强调了其在化学工艺中的重要性.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    Wismutnitrat 反应生成氢氧化铋
    参考文献:Mercuiro,J. P.;Lambachri,A.;Frit,B.,Sci. Ceram. 14: Proc. 14Th Int. Conf.,Canterbury,Sept. 7-9Th,1987,Sto+
    标题:Mercuiro,J. P.;Lambachri,A.;Frit,B.,Sci. Ceram. 14: Proc. 14Th Int. Conf.,Canterbury,Sept. 7-9Th,1987,Sto+

    专利信息


    专利号:WO-2006067109-A1
    优先权日:2004-12-22
    标 题 :Process for the mechanochemical synthesis of metal carboxylate
    发明人:ROBIN JEAN-JACQUES; TIFFES DOMINIQUE; HANNECART ETIENNE
    权利人:SOLVAY; ROBIN JEAN-JACQUES; TIFFES DOMINIQUE; HANNECART ETIENNE
    摘要:Process for the mechanochemical synthesis of metal carboxylate Process for the mechanochemical synthesis of metal carboxylate, according to which, in a first stage, a mixture (M) comprising at least one acidic substance (A) selected from carboxylic acids and carboxylic acid anhydrides, at least one basic inorganic metal compound (B), water (C) and at least one third solid body (D) which is chemically inert with regard to the components (A), (B) and (C) and the metal carboxylate is formed and, in a second stage, the abovesaid mixture (M) is subjected to a mechanical stress sufficient to bring about a mechanochemical reaction between the acidic substance (A) and the basic inorganic metal compound (B).

    专利号:US-5753726-A
    优先权日:1995-12-20
    标 题:Synthesis of modified epoxy resins for cathodic electrodeposition with catalyst deactivation and diol modification
    发明人:REUTER HARDY; JOUCK WALTER; OTT GUENTHER
    权利人:BASF LACKE & FARBEN
    摘要:Epoxy resins for preparing water-dispersible binders for cathodic electrodeposition coating materials, the epoxy resin being preparable by reacting a) polyepoxides having at least one glycidyl group per molecule b) and, optionally, up to 60% by weight, based on the overall epoxy resin reaction product, of aliphatic and/or alicyclic hydroxy compounds having preferably two or on average less than two hydroxyl groups per molecule and a molecular weight of less than 9000 g/mol, c) in the presence of a catalyst consisting of neutral metal salts, such as alkali metal salts and alkaline earth metal salts, zinc salts and nickel salts of tetrafluoroboric, tetrachloroboric, hexafluoro- antimonic,hexachloroantimonic,hexafluorophosphoric, perchlorate and periodic acid, and d) adding a deactivating agent which prevents the epoxy groups reacting further or effectively reduces the rate of such reaction as soon as the phenolic hydroxyl groups have already substantially reacted and at least 0.6% by weight of epoxy groups are still present, based on the overall weight of the epoxy resin reaction product.\\!

    专利号:US-11629137-B2
    优先权日:2017-04-24
    标 题:Methods of manufacturing of niraparib
    发明人:STEWART ALISTAIR; TOTO ANTHONY JOSEPH; CHEN FRANK XING; WU GEORGE
    权利人:TESARO INC
    摘要:Disclosed herein are methods and processes of preparing niraparib and pharmaceutically acceptable salts thereof, and intermediates and their salts useful for the synthesis of niraparib.

    专利号:US-3641082-A
    优先权日:1969-02-17
    标题 :Process for the alkylation alkenylation or arylation of heavy-metla salts by means of organo-triptychsiloxazolidines
    发明人:MULLER RICHARD; FREY HANS; DATHE CHRISTIAN
    权利人:INST SILIKON & FLUORKARBONCHEM
    摘要:PROCESS FOR THE ALKYLATOR, XXXVLATION OR ARYLATION OF SALTS OR HYDROXIDES OF HEAVY METALS, SUCH AS MERCURY, BXXOUTH, ANTIMONY AND XXX COMPRISING REACTING THEM WITH ORGANO-TRIPTYCH-SILEXXOLIDINES IN THE PRESENCE OF FLUORINE. THE PRODUCTS ACCORDING TO THIS INVENTION ARE USEFUL AS PHARMACEUTICALS AND PESTICIDES, AND MAY ALSO SERVE IN THE SYNTHESIS OF OTHER USEFUL PRODUCTS.

    专利号:RU-2186055-C2
    优先权日:1995-05-24
    标 题 :Method of synthesis of derivatives 3-carboxy-4-hydroxybenzaldehyde, method of synthesis of 4-hydroxybenzaldehyde, methods of synthesis of vanillin and ethylvanillin

    专利号:US-2011198530-A1
    优先权日:2010-02-18
    标题:Method of Producing a Bismuth Vanadium Oxide Derivative of Bi4V2O11 Using Molten Salt Synthesis, and Product Produced
    发明人:ROY BANASRI
    权利人:NEW MEXICO TECHNICAL FOUNDATION
    摘要:A method comprising mixing a bismuth precursor, a vanadium precursor, and at least one metal dopant precursor together with a salt or salt mixture having a eutectic melting temperature of no greater than 680° C. to form a homogeneous mixture, which is heated to a temperature of from 550° C. to 700° C. to produce a molten state of the salt or salt mixture and to obtain a metal doped bismuth vanadium oxide product that is a derivative of Bi 4 V 2 O 11 , which is then cooled. The thus-produced metal doped bismuth vanadium oxide product is present in loose platelet form, with the platelets capable of being aligned such that their planes are substantially parallel to one another.
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    主要参考文献

    参考标题:Investigation Of The Formation Process Of Zeolite-Like 3D Frameworks Constructed With ε-Keggin-Type Polyoxovanadomolybdates With Binding Bismuth Ions And Preparation Of A Nano-Crystal
    作者:Zhenxin Zhang,Masahiro Sadakane,Toru Murayama,Wataru Ueda
    摘要:Reaction Conditions For The Synthesis Of An îµ-Keggin-Type Polyoxometalate-Based 3D Framework, (Nh4)2.8H0.9[îµ-Vmo9.4V2.6O40Bi2]A.7.2H2O (Denoted As Mo–v–bi Oxide), Are Studied. It Is Found That The Reaction Time, Temperature, Ph Of The Solution, And Starting Compounds Affect The Production Of Mo–v–bi Oxide. The Crystal Size Of Mo–v–bi Oxide Is Controllable By Changing Bismuth Compounds. Nanometer-Sized Mo–v–bi Oxide Is Produced Using A Water-Soluble Bismuth Compound, Bi(No3)3A.5H2O, Whereas Micrometer To Submicrometer-Sized Mo–v–bi Oxide Is Produced Using Bi(Oh)3, Which Is Less Soluble In Water. The Particle Size Of The Material Affects The Properties Of The Material, Such As Surface Area And Catalysis. The Investigation Of The Formation Process Of The Material Is Carried Out With Raman Spectroscopy, Which Indicates That Mixing (Nh4)6Mo7O24A.4H2O, Voso4A.5H2O, And Bismuth Ions In Water Produces The îµ-Keggin Polyoxovanadomolybdate Together With A Ball-Shaped Polyoxovanadomolybdate, [mo72V30O282(H2O)56(So4)12]36Aˆ’ (Denoted As Mo72V30}). By Heating The Reaction Mixture, The îµ-Keggin Polyoxovanadomolybdate Assembles With Bismuth Ions To Form Mo–v–bi Oxide, Whereas Mo72V30} Assembles With Other Vanadium And Molybdenum Ions To Form Orthorhombic Mo–v Oxide.

    合成参考文献


    摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.
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