CAS: 16526-68-4; Cis,Cis-Cyclohexane-1,3,5-Tricarboxylic Acid

该化合物是一种环形三色箱酸,其特征是附在环己环上的三色箱酸功能组,这种化合物具有独特的环形,影响其物理和化学特性,如溶解性和再活性.它通常是在室内温度下的一种白色晶状固体,由于存在多极地碳盒酸组,在水中可以溶解.该化合物可参与各种化学反应,包括酯化和除色,使其与有机合成和生物化学途径相关.其结构特征有助于其在制药,食品化学和生物化学中间的潜在应用.此外,多种碳盒酸组的存在还有助于形成强大的氢结,从而在不同条件下影响其熔点和稳定性.

结构式图片

相似化合物

3971-31-1 2305-31-9 2305-30-8

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号554-95-0 均苯三甲酸 | CAS号6998-83-0 顺式,顺式-1,3,5-环己烷... | CAS号28084-34-6 cis,cis-triethy... | CAS号4105-92-4 1,3,5-苯三羧酸三乙酯 | CAS号168280-46-4 (1α,3α,5α)-1,3,... | CAS号6998-83-0 顺式,顺式-1,3,5-环己烷... | CAS号99063-92-0 cyclohexane-1,3...

合成工艺路线路线简述

  • 合成目标产物 1,3,5-Cyclohexanetricarboxylic Acid 主要起始原料 Triethyl 1,3,5-Benzenetricarboxylate
  • (文献来源)合成步骤主要原料 Triethyl 1,3,5-Benzenetricarboxylate

海关参考信息

专利信息


专利号:US-4895922-A
优先权日:1988-05-05
标 题 :Low temperature synthesis of polyesteramides
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention disclosed a process for the synthesis of polyesteramides. By utilizing the phosphorus containing catalyst systems of the present invention, such polyesteramides can be synthesized at relatively low temperatures. The present invention specifically discloses a process for the synthesis of a polyesteramide which comprises polymerizing at least one diamine, at least one diol, and at least one dicarboxylic acid in the presence of (1) at least one acid acceptor; (2) at least one halogenated organic compound; and (3) at least one phosphorus containing compound selected from the group consisting of (a) triphenylphosphine, (b) triphenylphosphine oxide, (c) triphenylphosphine sulfide, (d) polymeric agents having pendant diphenylphosphine groups, (e) silicon-phosphorus compositions which contain at least one divalent oxygen atom which is bonded directly to a tetravalent silicon atom and a trivalent or pentavalent phosphorus atom; (f) compounds with the structural formula (C 6 H 5 ) 3 P=N-R, wherein R is a hydrogen atom or an alkyl group containing from 1 to 10 carbon atoms; and (g) compounds with the structural formula (C 6 H 5 )PR 1 R 2 wherein R 1 and R 2 can be the same or different, wherein R 1 is selected from the group consisting of alkyl groups containing from 1 to 10 carbon atoms and phenyl groups, and wherein R 2 is an alkyl group containing from 1 to 10 carbon atoms.

专利号:US-12146136-B2
优先权日:2020-03-26
标题:Synthesis of modified oligonucleotides with increased stability
发明人:KHVOROVA ANASTASIA; ROUX LOà C MAURICE RENÉ JEAN; YAMADA KEN
权利人:UNIV MASSACHUSETTS
摘要:This disclosure relates to the synthesis of novel modified oligonucleotides. The synthesis of novel phosphoramidites are also provided.

专利号:US-4923839-A
优先权日:1987-02-05
标题:Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-4843053-A
优先权日:1987-02-05
标 题 :Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-4996178-A
优先权日:1987-02-05
标题 :Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-9868752-B2
优先权日:2012-04-13
标题 :Modular assembly of metal-organic super-containers incorporating calixarenes
发明人:WANG ZHENQIANG; Dai feng-rong
权利人:UNIV OF SOUTH DAKOTA; SOUTH DAKOTA BOARD OF REGENTS
摘要:A new strategy to design container molecules is presented. Sulfonylcalix[4]arenes, which are synthetic macrocyclic containers, are used as building blocks that are combined with various metal ions and tricarboxylate ligands to construct metal-organic ‘super-containers’ (MOSCs). These MOSCs possess both endo and exo cavities and thus mimic the structure of viruses. The synthesis of MOSCs is highly modular, robust, and predictable.
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合成参考文献


参考文献:10.1007/s11696-023-02695-6
摘要:Thakur M, Baral M, Kanungo BK. Computational and experimental studies on spectra and bonding of cyclohexane linked tris-hydroxyquinoline flexible tripodal chelator and its complexes. Chem. Pap. 2023 Feb 06;77(6):3163–79. doi: 10.1007/s11696-023-02695-6.
参考文献:10.1007/978-3-662-66460-5_273
摘要:Pardasani RT, Pardasani P. Magnetic properties of mixed ligand nickel(II) complex with tetraaza-macrocycle and 1,3,5-cyclohexanetricarboxylic acid. 2023. In: Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 8.
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