五甲基二硅氧烷置于三(五氟苯基)硼烷,水体系中,化学反应生成十甲基四硅氧烷 参考文献:B(c6F5)3催化的氢硅烷基化二硫化物和硫醇 标题:B(c6F5)3催化的氢硅烷基化二硫化物和硫醇 摘要:在温和的条件下,在b(c 6 F 5)3存在下,氢硅烷或氢硅酮可将硫醇或二硫化物转化为甲硅烷基硫醚.在这些条件下,与硫醇或二硫化物相比,发现醇的反应更快,而烷氧基硅烷的反应更慢.使用温和的基于氧气的亲核试剂可实现硫醇的释放(甲硅烷基脱保护). Doi:10.1002/ejoc.202100349
专利信息
专利号:US-9751987-B2 优先权日:2013-08-23 标题:Catalyst for synthesis of siloxanes 发明人:SIVASUBRAMANIAN KARTHIKEYAN; ANDERSON PATRICIA PIKE; KHARE VIVEK 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a N-trialkylsilyl-bis(perfluoroalkylsulfonyl)imide compound.
专利号:US-5779904-A 优先权日:1992-03-31 标题:Synthesis of inorganic membranes on supports 发明人:RUDERMAN WARREN; FEHLNER JAMES R; ZHANG ZHENYU 权利人:INRAD 摘要:Inorganic membranes such as zeolite membranes or other molecular sieve membranes can be provided by using silicone polymer material as starting material. A thin film zeolite membrane or a thin film membrane formed of interlocking zeolite crystals can be provided. Water soluble or water insoluble silicones can be treated in a basic solution under conditions and with an appropriate structure directing template, suitable aluminum content and at a temperature that is appropriate for growing a desired inorganic crystal framework. The membranes can be formed across the perforation of a support, such as a steel screen.
专利号:US-5474681-A 优先权日:1992-03-31 标 题:Synthesis of inorganic membranes 发明人:FEHLNER JAMES R; RUDERMAN WARREN; ZHANG ZHENYU 权利人:INRAD 摘要:Inorganic membranes such as zeolite membranes or other molecular sieve membranes can be provided by using silicone polymer material as starting material. A thin film zeolite membrane or a thin film membrane formed of interlocking zeolite crystals can be provided. Water soluble or water insoluble silicones can be treated in a basic solution under conditions and with an appropriate structure directing template, suitable aluminum content and at a temperature that is appropriate for growing a desired inorganic crystal framework. The continuous thin film membranes or interlocking crystal membranes can be formed on the sides of a reaction vessel, on the surface of the solution or on the surfaces of substrates introduced into the vessel.
专利号:US-9683083-B2 优先权日:2013-08-30 标 题:Catalyst for synthesis of siloxanes 发明人:SIVASUBRAMANIAN KARTHIKEYAN; ANDERSON PATRICIA PIKE; KHARE VIVEK 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:The present technology provides compositions, methods, and processes to form polysiloxanes. In one aspect, the present technology provides a process for the ring opening polymerization of a cyclosiloxane comprising contacting a cyclosiloxane with a bicyclic guanidine compound. The guanidine-containing compounds useful in the ring opening reaction include a fused ring structure comprising a guanidine functional group as part of the fused ring.
专利号:US-5618435-A 优先权日:1992-03-31 标题:Synthesis of inorganic membranes including metals 发明人:FEHLNER JAMES R; ZHANG ZHENYU 权利人:INRAD 摘要:Inorganic membranes such as zeolite membranes or other molecular sieve membranes can be provided by using siliconee, polymer material as starting material. A thin film zeolite membrane or a thin film membrane formed of interlocking zeolite crystals can be provided. Water soluble or water insoluble silicones can be treated in a basic solution under conditions and with an appropriate structure directing template, suitable aluminum content and at a temperature that is appropriate for growing a desired inorganic crystal framework. Heteroatoms can be included in the crystalline framework.
专利号:US-4496705-A 优先权日:1984-01-04 标题 :Synthesis of zwitterionic siloxane polymers 发明人:FLORENCE ROBERT A; CAMPBELL JOHN R; WILLIAMS JR ROBERT E 权利人:GEN ELECTRIC 摘要:A method is provided for producing aminoalkyl-siloxane polymers of a high molecular weight by hydrolyzing a difunctional aminoalkyl-silane prior to incorporation into the siloxane polymer. The high molecular weight siloxane polymers obtained may be converted to zwitterionic siloxane rubbers with excellent engineering properties and integrity.
参考文献:10.1007/s11356-015-5574-4 摘要:Ratola N, Ramos S, Homem V, Silva JA, Jiménez-Guerrero P, Amigo JM, Santos L, Alves A. Using air, soil and vegetation to assess the environmental behaviour of siloxanes. Environmental Science and Pollution Research. 2015 Oct 21;23(4):3273–84. doi: 10.1007/s11356-015-5574-4. 摘要: 摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.