CAS: 3115-66-0; Tetrabutylphosphonium Iodide

该化合物是一种四磷盐,化学配方([(C_4H_9_9_4P]_I-\]),在有机合成中通常用作分阶段转移催化剂(PTC),因为其能够促进不同阶段之间的反应.TPI在极地溶剂和非极地溶剂中都表现出高度的热稳定性和溶性,使其适应诸如藻类,聚合物和核生殖替代反应等应用.其强健的营养结构提高了反应效率,特别是在双发系统中.此外,TPI因其与其他磷盐相比毒性相对较低而受到重视,有助于在工业和实验室环境中进行更安全的处理.

结构式图片

相似化合物

2304-30-5 3115-68-2 1813-60-1

上下游产品

1-iodo-butane tributylphosphine1-(4-chlorophenyl)pentan-1-one n-butyl p-tolyl ketone

合成工艺路线路线简述

  • 合成目标产物 Tetrabutylphosphonium Iodide 主要起始原料 1-Iodobutane And Tributylphosphine
  • (文献来源)合成步骤主要原料 1-Iodobutane 和 Tributylphosphine

海关参考信息

专利信息


专利号:US-6235910-B1
优先权日:1998-09-22
标题:Process for the preparation of imidazolidine-2, 4-diones
发明人:BELLER MATTHIAS; ECKERT MARKUS; MORADI WAHED
权利人:DEGUSSA
摘要:A process for the preparation of compounds of the general formula (I)by reacting an aldehyde compound of the general formula (II)with a urea compound of the general formula (III)in the presence of carbon monoxide and a catalytically active metal compound. Compounds of the general formula (I) are important intermediates for the synthesis of alpha-amino acids.

专利号:US-4629807-A
优先权日:1986-02-06
标 题 :Selective synthesis of aliphatic dicarboxylic acid esters using palladium-phosphine or palladium-arsine catalysts
发明人:KNIFTON JOHN F
权利人:TEXACO INC
摘要:A process for preparing aliphatic dicarboxylic acid esters from aliphatic, non-conjugated dienes via carbonylation in the presence of a homogeneous palladium-phosphine catalyst or a palladium-phosphine melt catalyst.

专利号:US-4270015-A
优先权日:1979-02-05
标题:Manufacture of ethylene from synthesis gas (D#75,673-C1)
发明人:KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention concerns a two-step process for the preparation of ethylene from mixture of carbon monoxide and hydrogen (commonly known as synthesis gas) by reaction of said carbon monoxide/hydrogen mixtures with a carboxylic acid in the presence of one or more ruthenium catalyst complexes to form an ethyl ester of said carboxylic acid coreactant, followed by pyrolysis of said ethyl ester intermediate to ethylene.

专利号:US-4451680-A
优先权日:1982-10-21
标题:Alcohols prepared from olefins and synthesis gas
发明人:KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention concerns a process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound coupled with one or more bidentate or multidentate, phosphine-containing promoters, dispersed in a low melting quaternary phosphonium salt, and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.

专利号:US-4451679-A
优先权日:1982-10-21
标题 :Alcohols and aldehydes prepared from olefins and synthesis gas
发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRIGSBY JR ROBERT A; BRADER JR WALTER H
权利人:TEXACO INC
摘要:This invention concerns a process of preparing alcohols and aldehydes which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols and aldehydes.

专利号:US-4469895-A
优先权日:1982-10-21
标题 :Process for preparing alcohols from olefins and synthesis gas
发明人:KNIFTON JOHN F; GRIGSBY JR ROBERT A
权利人:TEXACO INC
摘要:This invention concerns an improved process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound in conjunction with one or more tertiary amine promoters, dispersed in a low melting quaternary phosphonium salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.
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合成参考文献


摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#01513
摘要:Wood, M. E., Science of Synthesis, (2003) 5, 323.
摘要:Braverman, S.; Cherkinsky, M.; Birsa, M. L., Science of Synthesis, (2005) 18, 67.
摘要:Jung, K. W.; Nagle, A. S., Science of Synthesis, (2005) 18, 401.
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