2-乙基己醇,1,2,4-苯三甲酸置于triflic Acid On Silica-Encapsulated Superparamagnetic Iron Oxide Nanoparticles体系中,用 Neat (No Solvent) 作为反应溶剂,化学反应 0.42H,以95%的收率获得产物偏苯三酸三辛酯 参考文献:Micro-Flow Nanocatalysis: Synergic Effect Of Tfoh@spions And Micro-Flow Technology As An Efficient And Robust Catalytic System For The Synthesis Of Plasticizers 标题:Micro-Flow Nanocatalysis: Synergic Effect Of Tfoh@spions And Micro-Flow Technology As An Efficient And Robust Catalytic System For The Synthesis Of Plasticizers 摘要:将连续流技术与纳米催化剂相结合合成增塑剂. DOI:10.1039/c8Ra07838F
专利号:WO-2025133656-A1 优先权日:2023-12-21 标题 :Synthesis and use of tuned precatalyst for carbon-monoxide and carbon-dioxide based fischer-tropsch catalyst for controlled product distribution 发明人:SÃ?PI ANDRÃ?S; NAJARI SARA; KÓNYA ZOLTÃ?N; KUKOVECZ Ã?KOS; SAEIDE SAMRAND 权利人:UNIV SZEGEDI 摘要:The present invention belongs to the technical field of design and synthesis of carbon-monoxide and carbon-dioxide-based Fischer-Tropsch synthesis catalysts, and discloses a novel iron-based Fischer-Tropsch synthesis catalyst containing both iron and carbon and a synthesis method and use thereof. The present invention specifically relates to a catalyst mixture for use in hydrogenation of CO and/or CO2, which catalyst mixture comprises i) iron oxide promoted by alkali metal, alkaline earth metal or transition metal, and ii) iron carbide. The invention further relates to a method for production of iron carbide composite comprising different iron carbides, and the use of said carbide composite in combination with alkali metal, alkaline earth metal or transition metal promoted iron oxide for use in hydrogenation of CO and/or CO2.
专利号:US-9212113-B2 优先权日:2013-04-26 标题:Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source 发明人:CHAKRAVARTI SHRIKAR; DRNEVICH RAYMOND F; STUCKERT INES C; SHAH MINISH M 权利人:CHAKRAVARTI SHRIKAR; DRNEVICH RAYMOND F; STUCKERT INES C; SHAH MINISH M; PRAXAIR TECHNOLOGY INC 摘要:A method and system for producing a synthesis gas in an oxygen transport membrane based reforming system is disclosed that carries out a primary reforming process within a reforming reactor, and a secondary reforming process within an oxygen transport membrane reactor and in the presence of heat generated from a oxygen transport membrane reactor and an auxiliary source of heat. The auxiliary source of heat is disposed within the reactor housing proximate the reforming reactors and may include an auxiliary reactively driven oxygen transport membrane reactor or a ceramic burner.
专利号:US-5194469-A 优先权日:1991-02-28 标题:Latex for coatings having improved flexibility 发明人:SRAIL RICHARD E; BURROWAY GARY L 权利人:GOODYEAR TIRE & RUBBER 摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved flexibility and good water resistance. Coatings of this type are particularly useful in roof coating applications because they offer excellent flexibility, excellent ultra-violet light resistance, and good water resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: n (1) free radical aqueous emulsion polymerizing, at a pH of less than about 3.5, a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 30 to about 70 weight percent vinyl aromatic monomers, (b) from about 25 to about 65 weight percent of at least one alkyl acrylate monomer, (c) from about 1 to about 5 weight percent of acrylic acid, and (d) about 0.4 to about 3 weight percent methacrylic acid, in the presence of about 0.2 to 0.4 phm at least one sulfonate surfactant and in the presence of about 4 to 8 phm of at least one nonionic surface active agent having a hydrophile-lipophile balance number which is within the range of about 12 to about 20 to produce a latex; and n (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex.
专利号:US-5122566-A 优先权日:1989-10-06 标 题 :Latex for coatings having reduced blushing characteristics 发明人:BURROWAY GARY L; GESENHUES ALBERT M; BRADEN JENNIFER T 权利人:GOODYEAR TIRE & RUBBER 摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved water resistance for both moisture vapor transmission and water spotting. Coatings which are formulated with the latex of this invention are particularly useful for coating metal substrates because they provide excellent rust and corrosion resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: (1) free radical aqueous emulsion polymerizing at a pH of less than about 3.5 a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 45 to about 85 weight percent vinyl aromatic monomers, (b) from about 15 to about 50 weight percent of at least one alkyl acrylate monomer, and (c) from about 1 to about 6 weight percent of at least one unsaturated carbonyl compound; in the presence of about 0.5 to 4.0 phm at least one phosphate ester surfactant and in the presence of about 0.5 to 4.0 phm of at least one water insoluble nonionic surface active agent to produce a latex; and (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to a bout 10.5 to produce the neutralized latex.
专利号:CN-107428648-A 优先权日:2015-01-30 标题 :Process for the preparation of compounds such as 3-arylbutyraldehyde useful in the synthesis of medetomidine
专利号:US-4968741-A 优先权日:1989-10-06 标题:Latex for coatings having reduced blushing characteristics 发明人:BURROWAY GARY L; GESENHUES ALBERT M; BRADEN JENNIFER T 权利人:GOODYEAR TIRE & RUBBER 摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved water resistance for both moisture vapor transmission and water spotting. Coatings which are formulated with the latex of this invention are particularly useful for coating metal substrates because they provide excellent rust and corrosion resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: n (1) free radical aqueous emulsion polymerizing at a pH of less than about 3.5 a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 45 to about 85 weight percent vinyl aromatic monomers, (b) from about 15 to about 50 weight percent of at least one alkyl acrylate monomer, and (c) from about 1 to about 6 weight percent of at least one unsaturated carbonyl compound; in the presence of about 0.5 to 4.0 phm at least one phosphate ester surfactant and in the presence of about 0.5 to 4.0 phm of at least one water insoluble nonionic surface active agent to produce a latex; and n (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex.
[参考文献]: A B Champion, Et Al. Storage Of Platelets On Flatbed Agitators In Polyvinyl Chloride Blood Bags Plasticized With Tri(2-Ethylhexyl) Trimellitate. Transfusion. 1987 Sep-Oct;27(5):399-401. [参考文献]: Claude Vaccher, Et Al. Analysis Of Non-Phthalates Plasticizers On Porous Graphitic Carbon By Supercritical Fluid Chromatography Using Evaporative Light Scattering Detection. J Chromatogr A. 2014 Sep 12:1359:277-86. [参考文献]: David F Stroncek, Et Al. Increasing Hemoglobin Oxygen Saturation Levels In Sickle Trait Donor Whole Blood Prevents Hemoglobin S Polymerization And Allows Effective White Blood Cell Reduction By Filtration. Transfusion. 2004 Sep;44(9):1293-9. [参考文献]: M A Quinn, Et Al. Storage Of Platelet Concentrates--An In Vitro Study Of Four Types Of Plastic Packs. Pathology. 1986 Jul;18(3):331-5. [参考文献]: M Miyamoto, Et Al. Effects Of Plasticizers And Plastic Bags On Granulocyte Function During Storage. Vox Sang. 1987;53(1):19-22.
合成参考文献
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