CAS: 13731-82-3; 2,5-Dibromoterephtalic Acid

该化合物是芳香化合物,其特点是存在两个溴原子和两个附于苯环的碳酸团,其分子结构具有对称安排,溴替代体位于与1和4位置的碳酸团相对的2和5个位置,该化合物一般在室温下是固体,以其在有机合成和材料科学中的潜在应用为名,特别是在聚合物的开发方面,以及作为各种化学反应的前体.溴的存在增强了其再活性,使其在电子替代反应中有用.此外,碳酸团有助于其在极溶溶剂中的溶性及其形成氢结的能力,这可能影响其物理特性以及与其他物质的相互作用.在处理该化合物时,应当采取安全防范措施,因为溴化化合物可能会对环境和健康造成危害.

结构式图片

相似化合物

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CAS号1074-24-4 1,4-二溴-2,5-二甲基苯 | CAS号20871-01-6 2,5-二溴-4-甲基苯甲酸 | CAS号106-42-3 对二甲苯 | CAS号63525-48-4 2,5-二溴苯-1,4-二甲醛 | CAS号18870-11-6 2,5-二溴对苯二甲腈 | CAS号18013-97-3 2,5-二溴对苯二甲酸二乙酯 | CAS号18014-00-1 2,5-二溴对苯二甲酸二甲酯 | CAS号114537-99-4 2,5-dibromo-ter... | CAS号2550-73-4 均苯四甲酸二酰亚胺 | CAS号636-94-2 2-羟基对苯二甲酸 | CAS号610-92-4 2,5-二羟基对苯二甲酸 | CAS号124-38-9 二氧化碳 | CAS号106-37-6 对二溴苯 | CAS号13815-90-2 2,5-dibromobenz... | CAS号18870-11-6 2,5-二溴对苯二甲腈

合成工艺路线路线简述

    Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于硫酸体系中,化学反应生成2,5-二溴对苯二甲酸
    参考文献:Halogen-Terephthalic-Hexahalides And Process Of Preparing Same
    标题:Halogen-Terephthalic-Hexahalides And Process Of Preparing Same

    海关参考信息

    专利信息


    专利号:US-7943723-B2
    优先权日:2006-12-21
    标 题:Process for the synthesis of ethers of aromatic acids
    发明人:RITTER JOACHIM C
    权利人:DU PONT
    摘要:The inventions disclosed herein include processes for the preparation of an ether of an aromatic acid, processes for the preparation of products into which such an ether can be converted, the use of such processes, and the products obtained and obtainable by such processes. A key feature of the processes described is the use of a solvent comprising an alcohol ROH and an alcoholate RO − M + .

    专利号:US-8207374-B2
    优先权日:2006-12-21
    标 题:Process for the synthesis of ethers of aromatic acids
    发明人:RITTER JOACHIM C
    权利人:RITTER JOACHIM C; DU PONT
    摘要:Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper.

    专利号:US-2011060118-A1
    优先权日:2009-09-02
    标 题:Process for the synthesis of fluorinated ethers of aromatic acids
    发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; MAHAJAN DU SURBHI
    权利人:DU PONT
    摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a Schiff base ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.

    专利号:US-7985825-B2
    优先权日:2006-12-21
    标 题 :Process for the synthesis of ethers of aromatic acids
    发明人:RITTER JOACHIM C
    权利人:DU PONT
    摘要:Ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a halogenated aromatic acid such as is described by the structure of Formula II n nwherein each X is independently Cl, Br or I; the reaction mixture further comprising;n (i) a polar protic solvent, a polar aprotic solvent or an alcoholic solvent containing the alcoholate RO-M+ (wherein M is Na or K), wherein the polar protic solvent, polar aprotic solvent or alcoholic solvent is either ROH or is a solvent that is less acidic than ROH; (ii) a copper (I) or copper (II) source; and (iii) an amino acid ligand that coordinates to copper, wherein the ligand comprises an amino acid in which the amine nitrogen and the carboxyl carbon are separated by no more than two carbon atoms.

    专利号:US-2011060117-A1
    优先权日:2009-09-02
    标题:Process for the synthesis of fluorinated ethers of aromatic acids
    发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; MAHAJAN DU SURBHI
    权利人:DU PONT
    摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diamine ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.

    专利号:US-2011060161-A1
    优先权日:2009-09-02
    标题 :Process for the synthesis of fluorinated ethers of aromatic acids
    发明人:RITTER JOACHIM C; MOLOY KENNETH GENE; POLLINO JOEL M; DU SURBHI MAHAJAN
    权利人:DU PONT
    摘要:Fluorinated ethers of aromatic acids are produced from halogenated aromatic acids in a reaction mixture containing a copper (I) or copper (II) source and a diketone ligand that coordinates to copper. The fluorinated ethers of aromatic acids made using the process described herein can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.
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    合成参考文献


    参考文献:10.1021/ja0398823
    摘要:Jacob J, Sax S, Piok T, List EJ, Grimsdale AC, Müllen K. Ladder-type pentaphenylenes and their polymers: efficient blue-light emitters and electron-accepting materials via a common intermediate. J Am Chem Soc. 2004 Jun 09;126(22):6987–95. doi: 10.1021/ja0398823.
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