CAS: 16323-43-6; 1,4-Benzenediacrylic Acid

该化合物其结构特征为该化合物其结构特征为附于p-苯二二氮基骨的两个丙烯酸组,该化合物一般是白色至光黄色固体,以其在聚合化学中的潜在用途而著称,特别是各种共聚物合成和交叉剂中的潜在用途而著称.该化合物具有良好的热稳定性和进行聚合的能力等特性,使其在生产具有强化机械特性的材料时有用.此外,p-苯二烯基酸可参与各种化学反应,包括激进聚合,从而能够形成多种聚合结构.其溶解性因溶剂不同而不同,而且一般在有机溶剂中是可溶的.应当参考安全数据,以便处理和接触准则,如任何化学物质一样.

结构式图片

相似化合物

63405-68-5 1866-39-3 940-61-4

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

piperidine pyridine malonic acid terephthalaldehyde, 1,4-Divinylbenzene p-phenylene-di-propionic acid2,3,2',3'-tetrabromo-3,3'-p-phenylene-di-propionic acid 1,4-Bis-(1,2,2-tribromo-ethyl)-benzene (E,E)-1,4-bis(β-bromovinyl)benzene

合成工艺路线路线简述

  • 合成目标产物 4-Phenylenediacrylic Acid 主要起始原料 Sodium Acetate And Terephthalaldehyde
  • (文献来源)合成步骤主要原料 Sodium Acetate 和 Terephthalaldehyde
(E,E)-Ethyl Hydrogen P-Phenylenediacrylate置于sodium Hydroxide体系中,化学反应生成对苯二丙烯酸
参考文献:Loew,Justus Liebigs Annalen Der Chemie,1885,Vol. 231,P. 363
标题:Loew,Justus Liebigs Annalen Der Chemie,1885,Vol. 231,P. 363

海关参考信息

专利信息


专利号:US-9716239-B2
优先权日:2015-09-25
标题 :Phototunable metal-organic framework compositions, and methods of synthesis thereof
发明人:MU BIN; SHAN BOHAN
权利人:UNIV ARIZONA STATE; ARIZONA BOARD OF REGENTS ON BEHALF OF ARI
摘要:Some embodiments include a method of preparing a phototuned metal-organic framework by forming a first solution by dissolving ZrOCl 2 .8H 2 O in dimethylformamide (DMF) and formic acid, mixing and dissolving 1,4-phenylenediacrylic acid in a second solution of dimethylformamide (DMF) and trimethylamine, and at least partially mixing the first and second solutions to form a mixture. The method further includes sealing the mixture in an autoclave and heating the mixture to above ambient temperature for a specified period of time to prepare ZrPDA metal-organic framework, and extracting the ZrPDA metal-organic framework and at least partially reacting to a specified degree at least some of ZrPDA metal-organic framework through [2+2] cycloaddition reactions. The specified degree can be tunable based at least in part on at least one of the intensity of UV radiation, the exposure time, and the UV wavelength.

专利号:WO-2004050654-A1
优先权日:2002-11-29
标 题 :Synthesis of pyrrolidine compound and salt thereof
发明人:KAWANISHI YASUYUKI; UENAKA MASAAKI; IDE YUTAKA; SHINOMOTO SHOJI; OKUNO TAKAYUKI
权利人:SHIONOGI & CO; KAWANISHI YASUYUKI; UENAKA MASAAKI; IDE YUTAKA; SHINOMOTO SHOJI; OKUNO TAKAYUKI
摘要:A p-toluenesulfonate, sulfate, or hydrochloride of the compound represented by the formula (I): (I) a solvate of any of these, or crystals of any of these; and processes for producing these.

专利号:US-2014120075-A1
优先权日:2011-05-24
标 题 :Nanozyme Compositions and Methods of Synthesis and Use Thereof
发明人:KABANOV ALEXANDER V; MANICKAM DAVIKA SOUNDARA; BRYNSKIKH ANNA M
权利人:UNIV NEBRASKA
摘要:Nanozymes and methods of use and synthesis thereof are provided.

专利号:US-2017092879-A1
优先权日:2015-09-25
标题:Phototunable metal-organic framework compositions, and methods of synthesis thereof

专利号:WO-2012162490-A1
优先权日:2011-05-24
标 题 :Nanozyme compositions and methods of synthesis and use thereof

专利号:US-5019379-A
优先权日:1987-07-31
标题 :Unsaturated polyanhydrides
发明人:DOMB ABRAHAM J; LANGER ROBERT S
权利人:MASSACHUSETTS INST TECHNOLOGY
摘要:A class of unsaturated polyanhydrides having double bonds available for secondary polymerization is disclosed. A crosslinked material having improved or different physical and mechanical properties can be prepared from these polyanhydrides, via secondary polymerization. The synthesis and characteristics of one unsaturated polyanhydride based on fumaric acid and its copolymers with aliphatic and aromatic diacids, prepared by either the melt-polycondensation method or by solution polymerization, is described in detail. These polymers are well suited for use in controlled release drug delivery devices. The polymers can also be used as a bioerodible bone cement where the polymer is first cast as a solution onto a bone fracture and then crosslinked by radiation or radical polymerization to yield a strong, adhesive material.
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合成参考文献


摘要:National Toxicology Program, Institute of Environmental Health Sciences, National Institutes of Health (NTP). 1992. National Toxicology Program Chemical Repository Database. Research Triangle Park, North Carolina.
摘要:Kellogg, R. M., Science of Synthesis, (2006) 8, 1511.
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