CAS: 10563-26-5; N1,N1'-(Ethane-1,2-Diyl)Bis(Propane-1,3-Diamine)

该化合物是多元胺化合物,其特征为两大主要矿类和灵活的脂体链,其特点是一种中央乙二胺主干柱,代之以两个3-氨丙基基组,增强溶剂的活性性和溶性,其典型的颜色无色可粉黄液体或固态,取决于温度和纯度;多种矿物质的存在使其能够参与各种化学反应,包括交叉联系和电热,使其在粘合剂,涂层等应用中有用,并成为环氧制剂的固化剂;此外,其形成氢联结的能力有助于其作为表面活性剂和生物应用(如药物运载系统)的潜力,但由于其矿性,它可能具有基本性,并且可能具有湿味,吸收环境的湿气;由于潜在的刺激性,适当的处理和安全措施是必不可少的.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号3217-00-3 Propanenitrile,... | CAS号56576-72-8 3-[2-[bis(2-cya... | CAS号22584-31-2 3-[(2-氨乙基)氨]基]丙烯腈 | CAS号106-93-4 1,2-二溴乙烷 | CAS号109-76-2 1,3-丙二胺 | CAS号36394-60-2 3,8-dioxo-4,7-d... | CAS号295-37-4 1,4,8,11-四氮杂环十四烷 | CAS号78303-77-2 2,2'-bi-(1,4,8,... | CAS号7209-38-3 1,4-双(3-氨丙基)哌嗪 | CAS号15439-16-4 1,4,8,12-四氮杂环十五烷 | CAS号135439-75-7 1-(pyridin-2-yl... | CAS号71089-74-2 1,4,8,11-四[(4-甲...

合成工艺路线路线简述

    3,3'-(乙烯二亚胺)二丙腈置于5% Active Carbon-Supported Ruthenium,氢气体系中,用 甲醇 用作溶剂,65.0~70.0 °C,2.2 Mpa 条件下,反应生成N,N-二(3-氨丙基)乙基乙胺
    参考文献:一种环己胺衍生物及其制备和用途
    标题:一种环己胺衍生物及其制备和用途
    摘要:本发明公开了一种环己胺衍生物及其制备和用途,丙烯腈与脂肪二胺发生迈克尔加成,之后将氰基还原为氨基,与环己酮缩合后再还原得到一系列环己胺衍生物.本发明脂肪二胺与丙烯腈加成条件可控,可通过脂肪二胺碳的个数调控环己胺衍生物的链长.环己胺衍生物的水溶性好,固化速度快,固化产物硬度高,耐热氧老化性能好,本发明操作简单,反应条件可控,收率高,产品利于工业化生产;该有机胺可作为助剂应用于高分子材料,复合材料等工程材料领域,适用于高档环保美缝剂,接缝王,水性环氧彩砂,透水砖中.

    专利信息


    专利号:US-2009318592-A1
    优先权日:2005-10-11
    标 题 :Process for the Synthesis of Amine Ethers
    发明人:FREY MARKUS; BROENNIMANN VALERIE
    权利人:CIBA GEIGY CORP
    摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.

    专利号:US-2007191516-A1
    优先权日:2004-03-15
    标题 :Process for the synthesis of amine ethers
    发明人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
    权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
    摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

    专利号:US-8877977-B2
    优先权日:2011-11-25
    标题 :Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
    发明人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
    权利人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO; BASF SE
    摘要:Process for the preparation of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, in which aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst and in the presence of hydrogen gas. Polyalkylenepolyamines obtainable by such processes and polyalkylenepolyamines comprising hydroxy groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.

    专利号:US-12303865-B2
    优先权日:2022-10-10
    标 题 :Aqueous manufacture of aminated MOF complexes
    发明人:GOSSELIN AERI; GAMORAS JOEL H; HERM ZOEY ROSE; MCDONALD THOMAS M; WENZ GRAHAM B; ZHU LINA
    权利人:MOSAIC MAT INC
    摘要:This disclosure relates to a select class of porous adsorbent, metal-organic frameworks (MOFs) capable of adsorbing carbon dioxide, their manufacturing, applications, and methods of use. Specifically, this disclosure relates to the solvo(hydro)thermal synthesis of a family of metal-organic frameworks, and their subsequent processing and transformation into material forms suitable for use in acid gas separations. More specifically, this disclosure relates to the preparation and recovery of MOFs at multiple scales of production, demonstrating the suitability and robustness of the materials thus obtained by the disclosed synthetic route and post-synthetic manipulation employed to tailor the materials for use in a variety of commercial acid gas separation systems, with improved performances, recyclability, and reuse characteristics.

    专利号:WO-2013076053-A1
    优先权日:2011-11-25
    标题:Synthesis of polyalkylene polyamines with low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
    发明人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
    权利人:BASF SE; STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
    摘要:The invention relates to a method for the production of polyalkylene polyamines by homogeneously catalyzed alcohol amination, wherein aliphatic alkanolamines are reacted with each other or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols in the presence of a homogeneous catalyst while eliminating water and in the presence of hydrogen gas. The invention further relates to polyalkylene polyamines, which can be obtained by said methods, and to polyalkylene polyamines which contain hydroxyl groups, secondary amines or tertiary amines. The invention finally relates to uses of said polyalkylene polyamines as adhesion promoters in inks, adhesion promoters in composite films, cohesion promoters in adhesives, cross-linkers/hardeners for resins, primers for paints, wet adhesion promoters for dispersion paints, complexing agents and flocculants, penetration auxiliaries for use in wood preservation, corrosion inhibitors, and immobilization agents of proteins and enzymes.

    专利号:US-7402675-B2
    优先权日:2000-05-26
    标题 :Process for the synthesis of amine ethers from secondary amino oxides
    发明人:HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER
    权利人:CIBA SC HOLDING AG
    摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.
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    合成参考文献


    摘要:National Technical Information Service., OTS0539630
    参考文献:10.1021/jm701583b
    摘要:Goode DR, Totten RK, Heeres JT, Hergenrother PJ. Identification of promiscuous small molecule activators in high-throughput enzyme activation screens. J Med Chem. 2008 Apr 24;51(8):2346–9. doi: 10.1021/jm701583b.
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