专利号:US-5877330-A 优先权日:1995-06-08 标 题:Vanadium-containing catalysts, process for manufacturing and use of the same 发明人:KISHIMOTO NOBUJI; MATSUNAMI ETSUSHIGE 权利人:NIPPON CATALYTIC CHEM IND 摘要:PCT No. PCT/JP96/01547 Sec. 371 Date Jan. 29, 1997 Sec. 102(e) Date Jan. 29, 1997 PCT Filed Jun. 7, 1996 PCT Pub. No. WO96/41678 PCT Pub. Date Dec. 27, 1996Vanadium-containing catalysts are obtained by using polyvanadic acid as a source of vanadium. Vanadium-containing catalysts are obtained by mixing catalyst components other than vanadium, or their precursors, with a polyvanadic acid sol which is formed by ion-exchanging a metavanadic acid aqueous solution with a proton-type cation-exchange resin and performing polycondensation, and by drying and/or calcining the mixture. Such vanadium-containing catalysts can fully exhibit their catalytic activity under mild reaction conditions, and can be suitably used for various reactions, such as synthesis of phthalic anhydride by the partial oxidation of o-xylene, synthesis of benzaldehyde by the partial oxidation of toluene, synthesis of benzoic acid by the partial oxidation of toluene, synthesis of anisaldehyde by the partial oxidation of p-methoxy toluene, synthesis of propylene by the oxidative dehydrogenation of propane, synthesis of isobutene by the oxidative dehydrogenation of isobutane, synthesis of methyl formate by the oxidative dehydrogenation of methanol, and synthesis of acrylonitrile by the ammoxidation of propane.
专利号:US-6281378-B1 优先权日:1995-06-08 标 题 :Vanadium-containing catalysts, process for manufacturing and use of the same 发明人:KISHIMOTO NOBUJI; MATSUNAMI ETSUSHIGE 权利人:NIPPON CATALYTIC CHEM IND 摘要:Vanadium-containing catalysts are obtained by using polyvanadic acid as a source of vanadium. Vanadium-containing catalysts are obtained by mixing catalyst components other than vanadium, or their precursors, with a polyvanadic acid sol which is formed by ion-exchanging a metavanadic acid aqueous solution with a proton-type cation-exchange resin and performing polycondensation, and by drying and/or calcining the mixture. Such vanadium-containing catalysts can fully exhibit their catalytic activity under mild reaction conditions, and can be suitably used for various reactions, such as synthesis of phthalic anhydride by the partial oxidation of o-xylene, synthesis of benzaldehyde by the partial oxidation of toluene, synthesis of benzoic acid by the partial oxidation of toluene, synthesis of anisaldehyde by the partial oxidation of p-methoxy toluene, synthesis of propylene by the oxidative dehydrogenation of propane, synthesis of isobutene by the oxidative dehydrogenation of isobutane, synthesis of methyl formate by the oxidative dehydrogenation of methanol, and synthesis of acrylonitrile by the ammoxidation of propane.
专利号:US-4517371-A 优先权日:1981-12-02 标题:Process for the synthesis of carboxylic anhydrides using a vanadium, phosphorus oxygen containing catalyst composition 发明人:YANG TAI-CHENG; RAO KRISHNA K; HUANG I-DER 权利人:EXXON RESEARCH ENGINEERING CO 摘要:A vanadium, phosphorus oxygen containing catalyst composition capable of partially oxidizing hydrocarbons (e.g., n-butane) to form a carboxylic anhydride (e.g., maleic anhydride), a process for preparing this catalyst, and a process for using this catalyst to form such anhydrides is disclosed. The catalyst composition is prepared by an organic heterogenous technique followed by a water treatment step and activation.
专利号:US-4801573-A 优先权日:1987-10-23 标 题:Catalyst for production of hydrocarbons 发明人:GOODWIN JAMES G JR; ERI SIGRID; MARCELIN GEORGE; RIIS TRYGVE 权利人:NORSKE STATS OLJESELSKAP 摘要:A catalyst and process for converting synthesis gas composed of hydrogen and carbon monoxide to hydrocarbons. The catalyst includes cobalt in catalytically active amounts up to about 60wt% of the catalyst and rhenium in catalystically active amounts of about 0.5 to 50wt% of the cobalt content of the catalyst supported on alumina. A metal oxide promoter may be added. A preferred process includes the step of contact the synthesis gas feed with the catalyst at reaction conditions.
专利号:US-4857559-A 优先权日:1987-10-23 标题 :Process for production of hydrocarbons 发明人:GOODWIN JAMES G JR; ERI SIGRID; MARCELIN GEORGE; RIIS TRYGVE 权利人:GAS TO OIL INC 摘要:A process for converting synthesis gas composed of hydrogen and carbon monoxide to hydrocarbons. The process includes the step of contacting at reaction conditions a synthesis gas feed to a catalyst which includes cobalt in catalytically active amounts up to about 60 wt % of the catalyst and rhenium in catalytically active amounts of about 0.5 to 50 wt % of the cobalt content of the catalyst supported on alumina. A metal oxide promoter may be added.
专利号:US-4880763-A 优先权日:1987-10-23 标 题:Catalyst for production of hydrocarbons 发明人:GOODWIN JAMES G JR; ERI SIGRID; MARCELIN GEORGE; RIIS TRYGVE 权利人:NORSKE STATS OLJESELSKAP 摘要:A catalyst for converting synthesis gas composed of hydrogen and carbon monoxide to hydrocarbons. The catalyst includes cobalt in catalytically active amounts up to about 60 wt % of the catalyst, rhenium in amounts of about 0.5 to 50 wt % of the cobalt content of the catalyst and an alkali in amounts ranging from about 0.5 to 5 atom percent of the cobalt content of the catalyst, supported on alumina. A metal oxide promoter may be added.
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