CAS: 2782-91-4; Tetramethylthiourea

该化合物是一种含有硫的有机化合物,配有分子式C5H12N2S.它通常用作橡胶制造中的硫化加速器,提供高效的交叉连接特性,以加强治愈过程.TMTU在温和温度下表现出极好的回动性,适合需要受控硫化率的应用.在加工条件下,它的低波动性和稳定性有助于弹性体制剂的一致性能.此外,TMTU是有机合成的前体,特别是在生产硫氨酸盐衍生物的过程中.该化合物的高度纯度和可靠性能使得它在精确的硫基反应至关重要的工业和研究环境中成为首选.

结构式图片

相似化合物

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CAS号75-15-0 二硫化碳 | CAS号74-88-4 碘甲烷 | CAS号632-22-4 四甲基脲 | CAS号534-13-4 N,N′-二甲基硫脲 | CAS号463-71-8 硫光气 | CAS号2083-91-2 N-(三甲基硅烷基)二甲胺 | CAS号128398-55-0 1-dimethylamino... | CAS号124-40-3 二甲胺 | CAS号19348-30-2 N,N,N,N,S-Penta... | CAS号463-58-1 羰基硫 | CAS号124-40-3 二甲胺 | CAS号632-22-4 四甲基脲 | CAS号791-50-4 2,2,4,4-Tetra(t... | CAS号26394-96-7 ethyl 3,3-bis(d... | CAS号97-74-5 一硫化四甲基秋兰姆 | CAS号50-00-0 甲醛 | CAS号7664-93-9 硫酸 | CAS号64-18-6 甲酸

合成工艺路线路线简述

    福美双 反应生成四甲基硫脲
    参考文献:V. Braun; Anton; Weissbach,Chemische Berichte,1930,Vol. 63,P. 2847,2861
    标题:V. Braun; Anton; Weissbach,Chemische Berichte,1930,Vol. 63,P. 2847,2861

    海关参考信息

    专利信息


    专利号:US-2024309024-A1
    优先权日:2023-03-14
    标题 :Direct synthesis of alkenylhalosilanes
    发明人:LEWIS KENRICK MARTIN; ZHU YANJUN; BYRNE CHRISTOPHER M
    权利人:MOMENTIVE PERFORMANCE MAT INC
    摘要:A process for the direct synthesis of alkenylhalosilane monomers. Forming a slurry of liquid and copper-activated silicon from fresh silicon, cyclone fines and/or fine dust from silicon grinding, ultrafines and/or spent contact mass from the Direct Synthesis of alkylhalosilanes and arylhalosilanes, in a thermally stable solvent. Reacting the silanes by agitating the slurry with at least one unsaturated aliphatic or cycloaliphatic organohalide of the formula R1X, and optionally an organohalosilane and/or hydrogen halide, in the presence of a polymerization inhibiting Lewis base additive, at a reaction time, temperature and pressure effective to produce alkenylhalosilanes having the formulae, R1SiHX2, R12SiHX, R13SiX, R1SiX3, and R12SiX2 or mixtures thereof.

    专利号:US-2021107859-A1
    优先权日:2018-04-06
    标题 :A process for the synthesis of carbon labeled organic compounds
    发明人:AUDISIO DAVIDE; CANTAT THIBAULT; DESTRO GIANLUCA
    权利人:COMMISSARIAT ENERGIE ATOMIQUE
    摘要:A process for the synthesis of a carbon labeled organic compound containing a carbon labeled carboxyl group is described. A method of using carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; a process for manufacturing labeled pharmaceuticals and agrochemicals comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; and a process for producing tracers comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure are also described.

    专利号:WO-2018191373-A1
    优先权日:2017-04-12
    标 题:Synthesis and characterization of metathesis catalysts
    发明人:JOHNS ADAM
    权利人:MATERIA INC
    摘要:This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.

    专利号:US-7651968-B2
    优先权日:2005-12-12
    标 题:Shaped body comprising a microporous material and at least one silicon-containing binding agent method for production and use thereof as catalyst in particular in a method for continuous synthesis of methylamines
    发明人:BOSCH MARCO; EBERHARDT JAN; ROETTGER RODERICH
    权利人:BASF SE
    摘要:A process for producing a shaped body comprising a microporous material and at least one silicon-comprising binder, which comprises the stepsn (I) preparation of a mixture comprising the microporous material, the binder and a lubricant, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body and (IV) calcination of the shaped body,n nwherein a silicone resin having a softening point of ≧30° C. is used as binder,n nshaped bodies which can be produced by this process, their use as catalyst, in particular in organic synthesis and very particularly preferably in a process for preparing methylamines.

    专利号:US-9809565-B2
    优先权日:2013-07-05
    标 题 :Formation of chiral 4-chromanones using chiral pyrrolidines in the presence of ureas or thioureas
    发明人:LETINOIS ULLA; NETSCHER THOMAS; ACKERMANN STEPHAN
    权利人:DSM IP ASSETS BV
    摘要:The present invention relates to a synthesis of chromanones or chromanes in a stereospecific matter in view of the 2-position in the chromanone or chromane ring. It has been found that this synthesis is particularly possible in the presence of a chiral compound of formula of a specific type and of at least one urea or thiourea.

    专利号:US-6696586-B1
    优先权日:2002-08-07
    标题 :Bis AU(I) sensitizers and their synthesis
    发明人:CLEARY BRIAN P; LOK ROGER; WHITE WEIMAR W
    权利人:EASTMAN KODAK CO
    摘要:This invention relates to an organothiosulfonato Au(I) complex having the formula n n n [A—SO 2 S—Au—SSO 2 —A] n − M +n n n n wherein n M is a cationic counter ion; n A is a substituted or unsubstituted organic group; n and n is 1 to 4; and wherein the compound is symmetrical. It further relates to the synthesis of said compounds.
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    主要参考文献

    [参考文献]: Alexius Freyberger, Et Al. Studies On The Goitrogenic Mechanism Of Action Of N,N,N',N'-Tetramethylthiourea. Toxicology. 2006 Jan 16;217(2-3):169-75.
    [参考文献]: Daniel J Hochman, Et Al. Acrolein Induction Of Oxidative Stress And Degranulation In Mast Cells. Environ Toxicol. 2014 Aug;29(8):908-15.
    [参考文献]: J Bouvet, Et Al. Morphometric Analysis Of The Cerebellar Purkinje Cell In The Developing Normal And Hypothyroid Chick. Int J Dev Neurosci. 1987;5(4):345-55.
    [参考文献]: J Palassis, Et Al. Sampling And Analytical Determination Of Airborne Tetramethyl And Ethylene Thiourea. Am Ind Hyg Assoc J. 1980 Feb;41(2):91-7.
    [参考文献]: Jiqin Liu, Et Al. Dna-Binding Activity Of Nf-Kappab And Phosphorylation Of P65 Are Induced By N-Acetylcysteine Through Phosphatidylinositol (Pi) 3-Kinase. Mol Immunol. 2008 Sep;45(15):3984-9.

    合成参考文献


    摘要:Baird, M. S., Science of Synthesis, (2010) 47, 1111.
    摘要:Koutentis, P. A.; Ioannidou, H. A., Science of Synthesis Knowledge Updates, (2010) 1, 270.
    摘要:Shi, L.; Yang, Z., Science of Synthesis: Applications of Domino Transformations in Organic Synthesis, (2015) 1, 612.
    摘要:Shi, L.; Yang, Z., Science of Synthesis: Applications of Domino Transformations in Organic Synthesis, (2015) 1, 610.
    摘要:Beccalli, E. M.; Bonetti, A.; Mazza, A., Science of Synthesis: Metal-Catalyzed Cyclization Reactions, (2016) 1, 417.
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