CAS: 4125-25-1; Tris(2-Methylpropyl)Phosphane

该化合物是一种有机磷的化合物,其特征是附于磷原子的三个异丁基组,对有独特气味的黄黄色液体来说,它是无色的,以其作为悬浮体的作用而著称,该化合物由于其性能和电子特性而能够稳定金属复合体.三丁基磷在有机溶剂中溶解,使其在各种有机合成应用中有用.其化学结构使其与其他磷相比的毒性相对较低,尽管由于潜在的刺激性能,仍应谨慎地处理.此外,该化合物可以参与核循环替代等反应,并可用于编写氧化磷.该化合物的稳定性和再活性使其在学术研究和工业应用中,特别是在催化和有机金属化合物合成方面都具有价值.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

Isobutyl iodide diisobutylphosphine isobutylmagnesium bromide isobuteneP(i-C4H9)3O Mo(η6-PhPPh2)(dppe)(N2)

合成工艺路线路线简述

    异丁烯置于偶氮二异丁腈,Phosphan体系中,用 正庚烷 作为反应溶剂,化学反应 4.0H,反应生成 三异丁基磷烷
    参考文献:The Free Radical Addition Of Phosphines To Unsaturated Compounds
    标题:The Free Radical Addition Of Phosphines To Unsaturated Compounds
    摘要:
    DOI:10.1021/jo01070A087

    专利信息


    专利号:US-11794179-B2
    优先权日:2016-08-24
    标 题 :Synthesis and characterization of metathesis catalysts
    发明人:JOHNS ADAM M
    权利人:UMICORE AG & CO KG
    摘要:This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.

    专利号:WO-2024061900-A1
    优先权日:2022-09-20
    标题 :Quantum dot shell synthesis
    发明人:WALRAVENS WILLEM; NAKONECHNYI IGOR; MACINTYRE BROWN ALASDAIR ANGUS; PRATO MODESTINO RAFAEL ALBERTO; GRIGEL VALERIIA
    权利人:QUSTOMDOT BV
    摘要:The invention relates to the synthesis of core/shell/shell quantum dots, particularly to a novel shell synthesis method.

    专利号:US-6518048-B2
    优先权日:2000-04-10
    标题:Stereo-specific synthesis of shimikic acid derivatives with improved efficiency
    发明人:IDING HANS; WIRZ BEAT; ZUTTER ULRICH
    权利人:HOFFMANN LA ROCHE
    摘要:The invention provides a multistep synthesis for the preparation of 4,5-diamino shikimic acid derivatives of formula n starting from an isophthalic acid derivative of formula n 4,5-Diamino shikimic acid derivatives are potent inhibitors of viral neuraminidase.

    专利号:US-9273410-B2
    优先权日:2009-01-16
    标 题 :Low-temperature synthesis of colloidal nanocrystals
    发明人:BARTL MICHAEL H; SIY JACQUELINE T
    权利人:BARTL MICHAEL H; SIY JACQUELINE T; UNIV UTAH RES FOUND
    摘要:Low-temperature organometallic nucleation and crystallization-based synthesis methods for the fabrication of semiconductor and metal colloidal nanocrystals with narrow size distributions and tunable, size- and shape-dependent electronic and optical properties. Methods include (1) forming a reaction mixture in a reaction vessel under an inert atmosphere that includes at least one solvent, a cationic precursor, an anionic precursor, and at least a first surface stabilizing ligand while stirring at a temperature in a range from about 50° C. to about 130° C. and (2) growing nanocrystals in the reaction mixture for a period of time while maintaining the temperature, the stirring, and the inert-gas atmosphere.

    专利号:US-4303593-A
    优先权日:1979-06-16
    标 题 :Process for the dimerization of hexafluoropropene oxide
    发明人:KUEHNE GERHARD
    权利人:HOECHST AG
    摘要:In the dimerization of hexafluoropropene oxide to give oligomeric acid fluorides of the formula the ratio of the oligomeric constituents formed is directed, in an improved manner, towards the formation of the dimer (n=0) if the reaction is carried out in the presence of a catalyst system which consists of a mixture of a copper (I) compound and a copper (II) compound mixed with a complex-forming agent from the group of the nitriles, isocyanides, tertiary phosphines and cyclic hydrocarbons with 6 to 12 ring atoms and 2 to 3 double bonds in the ring, and an aprotic organic solvent. The dimer is an intermediate product in the synthesis of perfluoropropyl perfluorovinyl ether, the latter being employed as a comonomer in fluorine-containing copolymers.

    专利号:US-8231848-B1
    优先权日:2012-04-10
    标题:One-pot synthesis of chalcopyrite-based semi-conductor nanoparticles
    发明人:REN YUHANG; SUN CHIVIN; SHUM KAI
    权利人:REN YUHANG; SUN CHIVIN; SHUM KAI; SUN HARMONICS LTD
    摘要:Ternary and quaternary Chalcopyrite CuInxGa1-xSySe2-y (CIGS, where 0≰x and y≰1) nanoparticles were synthesized from molecular single source precursors (SSPs) by a one-pot reaction in a high boiling solvent using salt(s) (i.e. NaCl as by-product) as heat transfer agent via conventional convective heating method. The nanoparticles sizes were 1.8 nm to 5.2 nm as reaction temperatures were varied from 150° C. to 190° C. with very high-yield. Tunable nanoparticle size is achieved through manipulation of reaction temperature, reaction time, and precursor concentrations. In addition, the method developed in this study was scalable to achieve ultra-large quantities production of tetragonal and quaternary Chalcopyrite CIGS nanoparticles.
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    合成参考文献


    摘要:Guram, A. S.; Milne, J. E.; Tedrow, J. S.; Walker, S. D., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 22.
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